Electrochemical electrolyte spreading studies of the protective properties of ultra-thin films on zinc galvanized steel
Reactive electrolyte spreading along the surfaces of different conversion films on zinc galvanized steel in humid air was monitored visually and with a height-regulated scanning Kelvin Probe. Electrochemical impedance spectroscopy and current density-potential curves revealed that decelerated spread...
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| Published in | Surface & coatings technology Vol. 228; pp. 286 - 295 |
|---|---|
| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
| Published |
Amsterdam
Elsevier B.V
15.08.2013
Elsevier |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Reactive electrolyte spreading along the surfaces of different conversion films on zinc galvanized steel in humid air was monitored visually and with a height-regulated scanning Kelvin Probe. Electrochemical impedance spectroscopy and current density-potential curves revealed that decelerated spreading kinetics are connected with increasing pore resistances of the pre-treatment layers and decreasing oxygen reduction current densities in the electron transfer controlled potential region. After a few days the progress ranking of electrolyte spreading along uncoated conversion films reflected the progress tendencies of cathodic delamination observed on epoxy coated conversion layers after long-time exposure to the same corrosive environment. Such correlation was not discovered for pre-treatment films that do not provide relevant electrochemical barrier properties. The results suggest that oxygen reduction driven electrolyte wetting is an option for accelerated performance testing of anticorrosive ultra-thin films on metal substrates that can be subject to cathodic delamination.
•Electrolyte spreading and cathodic delamination are similar on conversion coatings.•Interrelation of electrolyte spreading, barrier properties and oxygen reduction.•Electrolyte spreading kinetics can anticipate the progress of cathodic delamination.•Options for cost-efficient and accelerated corrosion testing are shown. |
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| AbstractList | Reactive electrolyte spreading along the surfaces of different conversion films on zinc galvanized steel in humid air was monitored visually and with a height-regulated scanning Kelvin Probe. Electrochemical impedance spectroscopy and current density-potential curves revealed that decelerated spreading kinetics are connected with increasing pore resistances of the pre-treatment layers and decreasing oxygen reduction current densities in the electron transfer controlled potential region. After a few days the progress ranking of electrolyte spreading along uncoated conversion films reflected the progress tendencies of cathodic delamination observed on epoxy coated conversion layers after long-time exposure to the same corrosive environment. Such correlation was not discovered for pre-treatment films that do not provide relevant electrochemical barrier properties. The results suggest that oxygen reduction driven electrolyte wetting is an option for accelerated performance testing of anticorrosive ultra-thin films on metal substrates that can be subject to cathodic delamination. Reactive electrolyte spreading along the surfaces of different conversion films on zinc galvanized steel in humid air was monitored visually and with a height-regulated scanning Kelvin Probe. Electrochemical impedance spectroscopy and current density-potential curves revealed that decelerated spreading kinetics are connected with increasing pore resistances of the pre-treatment layers and decreasing oxygen reduction current densities in the electron transfer controlled potential region. After a few days the progress ranking of electrolyte spreading along uncoated conversion films reflected the progress tendencies of cathodic delamination observed on epoxy coated conversion layers after long-time exposure to the same corrosive environment. Such correlation was not discovered for pre-treatment films that do not provide relevant electrochemical barrier properties. The results suggest that oxygen reduction driven electrolyte wetting is an option for accelerated performance testing of anticorrosive ultra-thin films on metal substrates that can be subject to cathodic delamination. •Electrolyte spreading and cathodic delamination are similar on conversion coatings.•Interrelation of electrolyte spreading, barrier properties and oxygen reduction.•Electrolyte spreading kinetics can anticipate the progress of cathodic delamination.•Options for cost-efficient and accelerated corrosion testing are shown. |
| Author | Fink, N. Wolpers, M. Grundmeier, G. Posner, R. |
| Author_xml | – sequence: 1 givenname: R. surname: Posner fullname: Posner, R. email: ralf.posner@web.de organization: Max-Planck-Institut für Eisenforschung GmbH, Department of Interface Chemistry and Surface Engineering, Max-Planck-Str. 1, 40237 Düsseldorf, Germany – sequence: 2 givenname: N. surname: Fink fullname: Fink, N. organization: Max-Planck-Institut für Eisenforschung GmbH, Department of Interface Chemistry and Surface Engineering, Max-Planck-Str. 1, 40237 Düsseldorf, Germany – sequence: 3 givenname: M. surname: Wolpers fullname: Wolpers, M. organization: Henkel AG & Co. KGaA, Henkelstr. 67, 40589 Düsseldorf, Germany – sequence: 4 givenname: G. surname: Grundmeier fullname: Grundmeier, G. organization: University of Paderborn, Department of Technical and Macromolecular Chemistry, Warburger Str. 100, 33098 Paderborn, Germany |
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| Cites_doi | 10.1088/0022-3727/24/2/019 10.1016/j.electacta.2010.07.037 10.1149/1.1984448 10.1016/j.corsci.2012.04.026 10.1016/j.corsci.2009.08.038 10.1016/j.electacta.2008.11.059 10.1016/j.electacta.2007.05.045 10.1016/j.corsci.2009.04.014 10.1016/S0010-938X(01)00056-7 10.1016/j.electacta.2008.06.074 10.1002/sia.3710 10.1016/S0010-938X(00)00047-0 10.1016/S0010-938X(00)00048-2 10.1016/S0010-938X(98)00168-1 10.1016/j.corsci.2007.06.005 10.1016/j.electacta.2009.10.059 10.1016/S0010-938X(00)00049-4 10.1016/j.electacta.2008.07.011 10.1016/j.corsci.2010.01.034 10.1016/j.electacta.2008.04.022 10.1149/1.2946429 10.1016/S0010-938X(98)00167-X 10.1016/j.electacta.2009.03.089 10.1016/S0010-938X(98)00166-8 |
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| Keywords | Zinc galvanized steel Cathodic delamination Conversion coating Accelerated corrosion testing Reactive electrolyte spreading Galvanized steel Surface treatments Coatings Thin films Corrosion Protective layer Corrosion testing Delamination |
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| References | Kanani (bb0040) 2007 Posner, Giza, Marazita, Grundmeier (bb0120) 2010; 52 Fürbeth, Stratmann (bb0105) 2001; 43 Leng, Streckel, Hofmann, Stratmann (bb0100) 1999; 41 Posner, Marazita, Amthor, Roschmann (bb0070) 2010; 52 Posner, Wapner, Amthor, Roschmann, Grundmeier (bb0065) 2010; 52 Chen, Persson, Leygraf (bb0080) 2008; 50 Williams, McMurray, Loveridge (bb0025) 2010; 55 Leng, Streckel, Stratmann (bb0095) 1999; 41 Chen, Persson, Nazarov, Zakipour, Thierry, Leygraf (bb0085) 2005; 152 Nazarov, Thierry, Volovitch, Ogle (bb0010) 2011; 43 Kinloch (bb0015) 1987 (bb0045) 2003 Vasilakopoulos, Bouroushian, Spyrdlis (bb0140) 2009; 54 S.E. Dolan, “Composition and process for treating metals“, US patent no. US5427632. Walsh (bb0135) 1991; 24 Adhikari, Unocic, Zhai, Frankel, Zimmerman, Fristad (bb0130) 2011; 56 K. Hackbarth, M. Wolpers, W. Lorenz, P. Kuhm, K. Meagher, C. Rosenkranz, M. Roth, R. Wark, G. Sanchis Otero, E. Wilke, “Metallisierende Vorbehandlung von Zinkoberflächen“, European patent no. EP 2 292 808 A1. Wielant, Posner, Hausbrand, Grundmeier, Terryn (bb0060) 2009; 51 Posner, Titz, Wapner, Stratmann, Grundmeier (bb0055) 2009; 54 Fürbeth, Stratmann (bb0110) 2001; 43 Neufeld, Cole, Bond, Furman (bb0145) 2002; 44 Allahar, Hinderliter, Tallman, Bierwagen (bb0030) 2008; 155 Rubina, Oltra, Vuillemin, Ogle (bb0020) 2008; 53 Leng, Streckel, Stratmann (bb0090) 1999; 41 Klimow, Fink, Grundmeier (bb0150) 2007; 53 Posner, Giza, Vlasak, Grundmeier (bb0075) 2009; 54 Posner, Wapner, Stratmann, Grundmeier (bb0050) 2009; 54 Fürbeth, Stratmann (bb0115) 2001; 43 Prosek, Nazarov, Stoulil, Thierry (bb0005) 2012; 61 Posner (10.1016/j.surfcoat.2013.04.042_bb0065) 2010; 52 Prosek (10.1016/j.surfcoat.2013.04.042_bb0005) 2012; 61 Nazarov (10.1016/j.surfcoat.2013.04.042_bb0010) 2011; 43 Kanani (10.1016/j.surfcoat.2013.04.042_bb0040) 2007 Fürbeth (10.1016/j.surfcoat.2013.04.042_bb0105) 2001; 43 Williams (10.1016/j.surfcoat.2013.04.042_bb0025) 2010; 55 Klimow (10.1016/j.surfcoat.2013.04.042_bb0150) 2007; 53 Wielant (10.1016/j.surfcoat.2013.04.042_bb0060) 2009; 51 Posner (10.1016/j.surfcoat.2013.04.042_bb0120) 2010; 52 10.1016/j.surfcoat.2013.04.042_bb0035 Posner (10.1016/j.surfcoat.2013.04.042_bb0075) 2009; 54 Leng (10.1016/j.surfcoat.2013.04.042_bb0100) 1999; 41 Posner (10.1016/j.surfcoat.2013.04.042_bb0050) 2009; 54 Rubina (10.1016/j.surfcoat.2013.04.042_bb0020) 2008; 53 (10.1016/j.surfcoat.2013.04.042_bb0045) 2003 Chen (10.1016/j.surfcoat.2013.04.042_bb0085) 2005; 152 Neufeld (10.1016/j.surfcoat.2013.04.042_bb0145) 2002; 44 Fürbeth (10.1016/j.surfcoat.2013.04.042_bb0115) 2001; 43 Leng (10.1016/j.surfcoat.2013.04.042_bb0090) 1999; 41 Vasilakopoulos (10.1016/j.surfcoat.2013.04.042_bb0140) 2009; 54 Leng (10.1016/j.surfcoat.2013.04.042_bb0095) 1999; 41 Adhikari (10.1016/j.surfcoat.2013.04.042_bb0130) 2011; 56 Walsh (10.1016/j.surfcoat.2013.04.042_bb0135) 1991; 24 Kinloch (10.1016/j.surfcoat.2013.04.042_bb0015) 1987 Posner (10.1016/j.surfcoat.2013.04.042_bb0070) 2010; 52 Chen (10.1016/j.surfcoat.2013.04.042_bb0080) 2008; 50 Fürbeth (10.1016/j.surfcoat.2013.04.042_bb0110) 2001; 43 10.1016/j.surfcoat.2013.04.042_bb0125 Allahar (10.1016/j.surfcoat.2013.04.042_bb0030) 2008; 155 Posner (10.1016/j.surfcoat.2013.04.042_bb0055) 2009; 54 |
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| SubjectTerms | Accelerated corrosion testing Applied sciences Cathodic delamination Conversion coating Corrosion Corrosion environments Cross-disciplinary physics: materials science; rheology Delaminating Delamination Electrochemical impedance spectroscopy Electrolytes Exact sciences and technology Galvanized steels Materials science Metals. Metallurgy Methods of deposition of films and coatings; film growth and epitaxy Physics Production techniques Reactive electrolyte spreading Reduction (electrolytic) Spreading Surface treatment Surface treatments Thin films Zinc Zinc galvanized steel |
| Title | Electrochemical electrolyte spreading studies of the protective properties of ultra-thin films on zinc galvanized steel |
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