Improvement of the oxidation stability and the mechanical properties of flexible graphite foil by boron oxide impregnation
Flexible graphite foil produced by rolling expanded graphite impregnated with boron oxide was analyzed by laser mass spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy and thermogravimetry. It was shown that the modification of the graphite foil by boron oxide increases the...
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| Published in | New carbon materials Vol. 27; no. 1; pp. 12 - 18 |
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| Main Authors | , , , , |
| Format | Journal Article |
| Language | English |
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Elsevier B.V
01.02.2012
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| Abstract | Flexible graphite foil produced by rolling expanded graphite impregnated with boron oxide was analyzed by laser mass spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy and thermogravimetry. It was shown that the modification of the graphite foil by boron oxide increases the onset temperature of oxidation by ∼ 150 °C. Impregnation of less than 2 mass% boron oxide also increased the tensile strength of the materials. The observed improvement was attributed to the blocking of active sites by boron oxide, which is probably chemically bonded to the edges of graphene sheets in expanded graphite particles. |
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| AbstractList | Flexible graphite foil produced by rolling expanded graphite impregnated with boron oxide was analyzed by laser mass spectroscopy, X-ray photoelectron spectroscopy, scanning electron microscopy and thermogravimetry. It was shown that the modification of the graphite foil by boron oxide increases the onset temperature of oxidation by ∼ 150 °C. Impregnation of less than 2 mass% boron oxide also increased the tensile strength of the materials. The observed improvement was attributed to the blocking of active sites by boron oxide, which is probably chemically bonded to the edges of graphene sheets in expanded graphite particles. |
| Author | Ionov, S.G. Van Tendeloo, G. Morozov, V.A. Savchenko, D.V. Serdan, A.A. |
| Author_xml | – sequence: 1 givenname: D.V. surname: Savchenko fullname: Savchenko, D.V. email: Savchenko_D@rambler.ru organization: Department of Chemistry, Moscow State University, Moscow, 119991, Russia – sequence: 2 givenname: A.A. surname: Serdan fullname: Serdan, A.A. organization: Department of Chemistry, Moscow State University, Moscow, 119991, Russia – sequence: 3 givenname: V.A. surname: Morozov fullname: Morozov, V.A. organization: Department of Chemistry, Moscow State University, Moscow, 119991, Russia – sequence: 4 givenname: G. surname: Van Tendeloo fullname: Van Tendeloo, G. organization: EMAT, University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium – sequence: 5 givenname: S.G. surname: Ionov fullname: Ionov, S.G. organization: Department of Chemistry, Moscow State University, Moscow, 119991, Russia |
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| Keywords | Expanded graphite Graphite foil Boron oxide Oxidation protection Tensile strength |
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| SubjectTerms | Boron oxide Expanded graphite Graphite foil Oxidation protection Tensile strength |
| Title | Improvement of the oxidation stability and the mechanical properties of flexible graphite foil by boron oxide impregnation |
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