Synthetic effect of supports in Cu-Mn–doped oxide catalysts for promoting ozone decomposition under humid environment

The escalating levels of surface ozone concentration pose detrimental effects on public health and the environment. Catalytic decomposition presents an optimal solution for surface ozone removal. Nevertheless, catalyst still encounters challenges such as poisoning and deactivation in the high humidi...

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Published inEnvironmental science and pollution research international Vol. 30; no. 46; pp. 102880 - 102893
Main Authors Li, Yunhe, Li, Hao, Zhao, Baogang, Ma, Yanming, Liang, Peiyuan, Sun, Tianjun
Format Journal Article
LanguageEnglish
Published Berlin/Heidelberg Springer Berlin Heidelberg 01.10.2023
Springer Nature B.V
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Abstract The escalating levels of surface ozone concentration pose detrimental effects on public health and the environment. Catalytic decomposition presents an optimal solution for surface ozone removal. Nevertheless, catalyst still encounters challenges such as poisoning and deactivation in the high humidity environment. The influence of support on catalytic ozone decomposition was examined at a gas hourly space velocity of 300 L·g −1 ·h −1 and 85% relative humidity under ambient temperature using Cu-Mn–doped oxide catalysts synthesized via a straightforward coprecipitation method. Notably, the Cu-Mn/SiO 2 catalyst exhibited remarkable performance on ozone decomposition, achieving 98% ozone conversion and stability for 10 h. Further characterization analysis indicated that the catalyst’s enhanced water resistance and activity could be attributed to factors such as an increased number of active sites, a large surface area, abundant active oxygen species, and a lower Mn oxidation state. The catalytic environment created by mixed oxides can offer a clearer understanding of their synergistic effects on catalytic ozone decomposition, providing significant insights into the development of water-resistant catalysts with superior performance. Graphical Abstract
AbstractList The escalating levels of surface ozone concentration pose detrimental effects on public health and the environment. Catalytic decomposition presents an optimal solution for surface ozone removal. Nevertheless, catalyst still encounters challenges such as poisoning and deactivation in the high humidity environment. The influence of support on catalytic ozone decomposition was examined at a gas hourly space velocity of 300 L·g ·h and 85% relative humidity under ambient temperature using Cu-Mn-doped oxide catalysts synthesized via a straightforward coprecipitation method. Notably, the Cu-Mn/SiO catalyst exhibited remarkable performance on ozone decomposition, achieving 98% ozone conversion and stability for 10 h. Further characterization analysis indicated that the catalyst's enhanced water resistance and activity could be attributed to factors such as an increased number of active sites, a large surface area, abundant active oxygen species, and a lower Mn oxidation state. The catalytic environment created by mixed oxides can offer a clearer understanding of their synergistic effects on catalytic ozone decomposition, providing significant insights into the development of water-resistant catalysts with superior performance.
The escalating levels of surface ozone concentration pose detrimental effects on public health and the environment. Catalytic decomposition presents an optimal solution for surface ozone removal. Nevertheless, catalyst still encounters challenges such as poisoning and deactivation in the high humidity environment. The influence of support on catalytic ozone decomposition was examined at a gas hourly space velocity of 300 L·g−1·h−1 and 85% relative humidity under ambient temperature using Cu-Mn–doped oxide catalysts synthesized via a straightforward coprecipitation method. Notably, the Cu-Mn/SiO2 catalyst exhibited remarkable performance on ozone decomposition, achieving 98% ozone conversion and stability for 10 h. Further characterization analysis indicated that the catalyst’s enhanced water resistance and activity could be attributed to factors such as an increased number of active sites, a large surface area, abundant active oxygen species, and a lower Mn oxidation state. The catalytic environment created by mixed oxides can offer a clearer understanding of their synergistic effects on catalytic ozone decomposition, providing significant insights into the development of water-resistant catalysts with superior performance.
The escalating levels of surface ozone concentration pose detrimental effects on public health and the environment. Catalytic decomposition presents an optimal solution for surface ozone removal. Nevertheless, catalyst still encounters challenges such as poisoning and deactivation in the high humidity environment. The influence of support on catalytic ozone decomposition was examined at a gas hourly space velocity of 300 L·g −1 ·h −1 and 85% relative humidity under ambient temperature using Cu-Mn–doped oxide catalysts synthesized via a straightforward coprecipitation method. Notably, the Cu-Mn/SiO 2 catalyst exhibited remarkable performance on ozone decomposition, achieving 98% ozone conversion and stability for 10 h. Further characterization analysis indicated that the catalyst’s enhanced water resistance and activity could be attributed to factors such as an increased number of active sites, a large surface area, abundant active oxygen species, and a lower Mn oxidation state. The catalytic environment created by mixed oxides can offer a clearer understanding of their synergistic effects on catalytic ozone decomposition, providing significant insights into the development of water-resistant catalysts with superior performance. Graphical Abstract
Author Li, Yunhe
Sun, Tianjun
Zhao, Baogang
Ma, Yanming
Li, Hao
Liang, Peiyuan
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Keywords spinel
CuMn
Oxidation states
Support modified
Water resistance
Catalytic decomposition
O
Oxygen vacancy
CuMn2O4 spinel
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Snippet The escalating levels of surface ozone concentration pose detrimental effects on public health and the environment. Catalytic decomposition presents an optimal...
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SubjectTerms Ambient temperature
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Catalysis
Catalysts
Chemical synthesis
Copper
Copper - chemistry
Decomposition
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Humidity
Manganese
Manganese - chemistry
Mixed oxides
Oxidation
Oxidation-Reduction
Oxides - chemistry
Ozone
Ozone - chemistry
Public health
Relative humidity
Research Article
Silicon dioxide
Stability analysis
Synergistic effect
Valence
Waste Water Technology
Water Management
Water Pollution Control
Water resistance
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Title Synthetic effect of supports in Cu-Mn–doped oxide catalysts for promoting ozone decomposition under humid environment
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