Effective Organochlorine Pesticides Removal from Aqueous Systems by Magnetic Nanospheres Coated with Polystyrene
In this paper, magnetic nanospheres coated with polystyrene （Fe3O4@PS） were prepared for the removal of organochlorine pesticides from aqueous solutions. The obtained Fe3O4@PS was round shape with diameter of 55±11 nm. The VSM results illustrated that its higher saturated magnetization was 36.76 emu...
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| Published in | Journal of Wuhan University of Technology. Materials science edition Vol. 29; no. 1; pp. 168 - 173 |
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| Main Authors | , , |
| Format | Journal Article |
| Language | English |
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Heidelberg
Wuhan University of Technology
01.02.2014
Springer Nature B.V |
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| Abstract | In this paper, magnetic nanospheres coated with polystyrene （Fe3O4@PS） were prepared for the removal of organochlorine pesticides from aqueous solutions. The obtained Fe3O4@PS was round shape with diameter of 55±11 nm. The VSM results illustrated that its higher saturated magnetization was 36.76 emu g^-1 and it could be easily separated from aqueous solutions with a permanent magnet. The adsorption results showed that pesticides could be effectively adsorbed and the adsorption equilibrium time was less than 20 mins. The pseudo-second-order model was suitable to describe the adsorption kinetics. Compared with the Freundlich adsorption model, the adsorption data fitted well with Langmuir model. The effect of salinity and humic acid was also studied and the results illustrated that they could be neglected under optimized conditions. The asobtained sorbent showed a good performance with more than 93.3% pesticides removal in treating actual water samples. |
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| AbstractList | In this paper, magnetic nanospheres coated with polystyrene （Fe3O4@PS） were prepared for the removal of organochlorine pesticides from aqueous solutions. The obtained Fe3O4@PS was round shape with diameter of 55±11 nm. The VSM results illustrated that its higher saturated magnetization was 36.76 emu g^-1 and it could be easily separated from aqueous solutions with a permanent magnet. The adsorption results showed that pesticides could be effectively adsorbed and the adsorption equilibrium time was less than 20 mins. The pseudo-second-order model was suitable to describe the adsorption kinetics. Compared with the Freundlich adsorption model, the adsorption data fitted well with Langmuir model. The effect of salinity and humic acid was also studied and the results illustrated that they could be neglected under optimized conditions. The asobtained sorbent showed a good performance with more than 93.3% pesticides removal in treating actual water samples. In this paper, magnetic nanospheres coated with polystyrene (Fe 3 O 4 @PS) were prepared for the removal of organochlorine pesticides from aqueous solutions. The obtained Fe 3 O 4 @PS was round shape with diameter of 55±11 nm. The VSM results illustrated that its higher saturated magnetization was 36.76 emu g −1 and it could be easily separated from aqueous solutions with a permanent magnet. The adsorption results showed that pesticides could be effectively adsorbed and the adsorption equilibrium time was less than 20 mins. The pseudo-second-order model was suitable to describe the adsorption kinetics. Compared with the Freundlich adsorption model, the adsorption data fitted well with Langmuir model. The effect of salinity and humic acid was also studied and the results illustrated that they could be neglected under optimized conditions. The asobtained sorbent showed a good performance with more than 93.3% pesticides removal in treating actual water samples. In this paper, magnetic nanospheres coated with polystyrene (Fe^sub 3^O^sub 4^@PS) were prepared for the removal of organochlorine pesticides from aqueous solutions. The obtained Fe^sub 3^O^sub 4^@PS was round shape with diameter of 55±11 nm. The VSM results illustrated that its higher saturated magnetization was 36.76 emu g^sup -1^ and it could be easily separated from aqueous solutions with a permanent magnet. The adsorption results showed that pesticides could be effectively adsorbed and the adsorption equilibrium time was less than 20 mins. The pseudo-second-order model was suitable to describe the adsorption kinetics. Compared with the Freundlich adsorption model, the adsorption data fitted well with Langmuir model. The effect of salinity and humic acid was also studied and the results illustrated that they could be neglected under optimized conditions. The asobtained sorbent showed a good performance with more than 93.3% pesticides removal in treating actual water samples.[PUBLICATION ABSTRACT] In this paper, magnetic nanospheres coated with polystyrene (Fe sub(3)O sub(4)S) were prepared for the removal of organochlorine pesticides from aqueous solutions. The obtained Fe sub(3)O sub(4)S was round shape with diameter of 55 plus or minus 11 nm. The VSM results illustrated that its higher saturated magnetization was 36.76 emu g super(-1) and it could be easily separated from aqueous solutions with a permanent magnet. The adsorption results showed that pesticides could be effectively adsorbed and the adsorption equilibrium time was less than 20 mins. The pseudo-second-order model was suitable to describe the adsorption kinetics. Compared with the Freundlich adsorption model, the adsorption data fitted well with Langmuir model. The effect of salinity and humic acid was also studied and the results illustrated that they could be neglected under optimized conditions. The asobtained sorbent showed a good performance with more than 93.3% pesticides removal in treating actual water samples. |
| Author | LAN Jing CHENG Yang ZHAO Zongshan |
| AuthorAffiliation | Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education of the People＇s Republic of China, Ocean University of China, Qingdao 266100, China College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University, Qingdao 266109, China College of Chemical Engineering and Technology, Wuhan University of Science and Technology, Wuhan 430081, China |
| Author_xml | – sequence: 1 givenname: Jing surname: Lan fullname: Lan, Jing organization: Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education of the People’s Republic of China, Ocean University of China, College of Chemistry and Pharmaceutical Sciences, Qingdao Agricultural University – sequence: 2 givenname: Yang surname: Cheng fullname: Cheng, Yang organization: College of Chemical Engineering and Technology, Wuhan University of Science and Technology – sequence: 3 givenname: Zongshan surname: Zhao fullname: Zhao, Zongshan email: zhaozongshan@ouc.edu.cn organization: Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education of the People’s Republic of China, Ocean University of China |
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| CitedBy_id | crossref_primary_10_1007_s13593_014_0274_x crossref_primary_10_1016_j_arabjc_2020_06_027 crossref_primary_10_5004_dwt_2018_21839 crossref_primary_10_3390_su15097336 crossref_primary_10_1016_j_envpol_2023_122940 crossref_primary_10_1155_2022_2055024 crossref_primary_10_1007_s11771_019_3989_7 crossref_primary_10_53623_sein_v1i1_379 crossref_primary_10_1007_s13201_021_01566_3 crossref_primary_10_1016_j_enmm_2018_07_008 crossref_primary_10_1080_02757540_2020_1787391 crossref_primary_10_1088_2053_1591_ad86a4 crossref_primary_10_14233_ajchem_2022_23579 |
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| Keywords | magnetic nanospheres adsorption organochlorine polystyrene |
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| Notes | magnetic nanospheres; polystyrene; adsorption; organochlorine. 42-1680/TB In this paper, magnetic nanospheres coated with polystyrene （Fe3O4@PS） were prepared for the removal of organochlorine pesticides from aqueous solutions. The obtained Fe3O4@PS was round shape with diameter of 55±11 nm. The VSM results illustrated that its higher saturated magnetization was 36.76 emu g^-1 and it could be easily separated from aqueous solutions with a permanent magnet. The adsorption results showed that pesticides could be effectively adsorbed and the adsorption equilibrium time was less than 20 mins. The pseudo-second-order model was suitable to describe the adsorption kinetics. Compared with the Freundlich adsorption model, the adsorption data fitted well with Langmuir model. The effect of salinity and humic acid was also studied and the results illustrated that they could be neglected under optimized conditions. The asobtained sorbent showed a good performance with more than 93.3% pesticides removal in treating actual water samples. SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 14 ObjectType-Article-2 content type line 23 |
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| Snippet | In this paper, magnetic nanospheres coated with polystyrene （Fe3O4@PS） were prepared for the removal of organochlorine pesticides from aqueous solutions. The... In this paper, magnetic nanospheres coated with polystyrene (Fe 3 O 4 @PS) were prepared for the removal of organochlorine pesticides from aqueous solutions.... In this paper, magnetic nanospheres coated with polystyrene (Fe^sub 3^O^sub 4^@PS) were prepared for the removal of organochlorine pesticides from aqueous... In this paper, magnetic nanospheres coated with polystyrene (Fe sub(3)O sub(4)S) were prepared for the removal of organochlorine pesticides from aqueous... |
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| SubjectTerms | Adsorption Aqueous solutions Biomaterials Chemistry and Materials Science Fe3O4 Langmuir模型 Magnetization Materials Science Mathematical models Nanospheres Pesticides Polystyrene resins Salinity 包覆 吸附平衡时间 有机氯农药 水系统 磁性纳米微球 聚苯乙烯微球 |
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| Title | Effective Organochlorine Pesticides Removal from Aqueous Systems by Magnetic Nanospheres Coated with Polystyrene |
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