Structure-property interplay of asymmetric membranes comprising of soft polydimethylsiloxane chains and hard silica nanomaterials
Silica nanomaterials modified with monomolecular C18-alkyl silane or oligomeric dimethylsiloxane units were loaded in-situ during the formation of PDMS membrane. The small-angle neutron scattering (SANS) study was performed to probe structural compatibility between the modified silica and PDMS. The...
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| Published in | Polymer (Guilford) Vol. 160; pp. 30 - 42 |
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| Main Authors | , , , |
| Format | Journal Article |
| Language | English |
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Elsevier Ltd
03.01.2019
Elsevier BV |
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| Abstract | Silica nanomaterials modified with monomolecular C18-alkyl silane or oligomeric dimethylsiloxane units were loaded in-situ during the formation of PDMS membrane. The small-angle neutron scattering (SANS) study was performed to probe structural compatibility between the modified silica and PDMS. The Ornstein-Zernike (OZ) and Debye-Anderson-Brumberger (DAB) models were excellently fit to the SANS data describing nanoscale structure morphology in terms of correlation length scales of the soft and hard segmental units. The polymeric chain was stretched or contracted depending upon the type and amount of silica incorporation. This indicated limiting amount of silica incorporation in the PDMS membrane structure depending upon structural compatibility between the silica and PDMS. The C18-alkyl silylated silica was found to be the best compatible with the membrane structure. The membrane with 30% (w/w) C18-alkyl silylated -silica loading exhibited the best performance in pervaporation separation of alcohol/water.
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•Structural compatibility between silica nanomaterials and PDMS as probed by SANS.•Polymerisation of PDMS affected by incorporation of excess silica.•Polymeric chain stretched or contracted depending upon silica type or amount.•PDMS with optimal C18-alkylsilylated-silica exhibited excellent performance. |
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| AbstractList | Silica nanomaterials modified with monomolecular C18-alkyl silane or oligomeric dimethylsiloxane units were loaded in-situ during the formation of PDMS membrane. The small-angle neutron scattering (SANS) study was performed to probe structural compatibility between the modified silica and PDMS. The Ornstein-Zernike (OZ) and Debye-Anderson-Brumberger (DAB) models were excellently fit to the SANS data describing nanoscale structure morphology in terms of correlation length scales of the soft and hard segmental units. The polymeric chain was stretched or contracted depending upon the type and amount of silica incorporation. This indicated limiting amount of silica incorporation in the PDMS membrane structure depending upon structural compatibility between the silica and PDMS. The C18-alkyl silylated silica was found to be the best compatible with the membrane structure. The membrane with 30% (w/w) C18-alkyl silylated -silica loading exhibited the best performance in pervaporation separation of alcohol/water. Silica nanomaterials modified with monomolecular C18-alkyl silane or oligomeric dimethylsiloxane units were loaded in-situ during the formation of PDMS membrane. The small-angle neutron scattering (SANS) study was performed to probe structural compatibility between the modified silica and PDMS. The Ornstein-Zernike (OZ) and Debye-Anderson-Brumberger (DAB) models were excellently fit to the SANS data describing nanoscale structure morphology in terms of correlation length scales of the soft and hard segmental units. The polymeric chain was stretched or contracted depending upon the type and amount of silica incorporation. This indicated limiting amount of silica incorporation in the PDMS membrane structure depending upon structural compatibility between the silica and PDMS. The C18-alkyl silylated silica was found to be the best compatible with the membrane structure. The membrane with 30% (w/w) C18-alkyl silylated -silica loading exhibited the best performance in pervaporation separation of alcohol/water. [Display omitted] •Structural compatibility between silica nanomaterials and PDMS as probed by SANS.•Polymerisation of PDMS affected by incorporation of excess silica.•Polymeric chain stretched or contracted depending upon silica type or amount.•PDMS with optimal C18-alkylsilylated-silica exhibited excellent performance. |
| Author | Singh, Puyam S. Kansara, Ankit M. Prajapati, Pradeep K. Aswal, Vinod K. |
| Author_xml | – sequence: 1 givenname: Ankit M. surname: Kansara fullname: Kansara, Ankit M. organization: Membrane Science & Separation Technology Division, CSIR-Central Salt & Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G.B. Marg, Bhavnagar, 364021, India – sequence: 2 givenname: Pradeep K. surname: Prajapati fullname: Prajapati, Pradeep K. organization: Membrane Science & Separation Technology Division, CSIR-Central Salt & Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G.B. Marg, Bhavnagar, 364021, India – sequence: 3 givenname: Vinod K. surname: Aswal fullname: Aswal, Vinod K. organization: Solid State Physics Division, BARC, Trombay, Mumbai, 400085, India – sequence: 4 givenname: Puyam S. surname: Singh fullname: Singh, Puyam S. email: puyam@csmcri.res.in organization: Membrane Science & Separation Technology Division, CSIR-Central Salt & Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G.B. Marg, Bhavnagar, 364021, India |
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| Cites_doi | 10.1016/j.memsci.2015.01.047 10.1016/j.cis.2012.03.003 10.1080/01496395.2010.527896 10.1039/C5RA06433C 10.1016/j.desal.2014.05.004 10.1016/j.memsci.2015.05.070 10.1016/j.micromeso.2014.09.010 10.1016/j.seppur.2015.09.004 10.1021/ie50320a024 10.1038/srep05925 10.1016/j.desal.2013.05.008 10.1016/j.memsci.2016.11.029 10.1016/j.seppur.2014.02.032 10.1002/jctb.4090 10.1016/j.seppur.2017.07.072 10.1016/j.memsci.2017.02.006 10.1063/1.1722830 10.1021/la00051a020 10.1016/j.seppur.2016.02.040 10.1002/pen.24283 10.1002/app.35313 10.1016/j.memsci.2015.06.043 10.1002/jctb.1265 10.1016/j.memsci.2011.05.006 10.1006/jcis.2000.7106 10.1016/j.memsci.2011.05.031 10.1021/ma00010a026 10.1002/app.26471 10.1016/j.memsci.2015.10.018 10.1016/j.memsci.2008.12.014 10.1039/c3ta10358g 10.1080/01496395.2014.944619 |
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| References | Zhang, Li, Wang, Fan, Zhang, Zhang, Ji (bib2) 2015; 492 Wang, Chen, Fang, Wang, Yu, Li (bib11) 2016; 163 Zhou, Zhang, Wan, Jin (bib8) 2017; 524 Dozier, Huang, Fetters (bib30) 1991; 24 Yin, Lau, Rozowski, Howard, Xu, Lai, Dose, Lively, Lind (bib10) 2017; 529 García-Payo, Izquierdo-Gil, Fernández-Pineda (bib32) 2000; 230 Sun, Li, Xu (bib19) 2013; 322 Aswal, Goyal (bib23) 2000; 79 Noble (bib20) 2011; 378 Debye, Anderson, Brumberger (bib27) 1957; 28 Hammouda (bib29) 1995 Devi, Ray, Singh, Singh (bib21) 2014; 346 Han, Zhang, Ma, Li (bib9) 2016 Vane (bib4) 2005; 80 Zhuang, Chen, Su, Luo, Feng, Zhou, Wan (bib3) 2016; 499 Shirazi, Ghadimi, Mohammadi (bib17) 2012; 124 Tang, Wang, Xiao, Shi, Yang (bib16) 2007; 105 Wang, Liu, Li, Gao, Ji, Li (bib7) 2015; 201 Jadav, Aswal, Singh (bib24) 2011; 378 Zhou, Shi, Jin (bib15) 2014; 127 Jadav, Aswal, Singh (bib26) 2013; 1 Wenzel (bib31) 1936; 28 Beltran, Nisola, Choi, Kim, Chung (bib33) 2013; 88 Rioboo, Delattre, Duvivier, Vaillant, De Coninck (bib14) 2012; 175 Wang, Shi, Gao, Li, Wang, Guo, Zhang, Ji (bib12) 2015; 153 Knozowska, Kujawska, Kujawa, Kujawski, Bryjak, Chrzanowska, Kujawski (bib1) 2017; 188 Xue, Du, Chen, Ren, Sun, Bai, Yang (bib13) 2014; 4 Kansara, Aswal, Singh (bib25) 2015; 5 Kessel, Granick (bib28) 1991; 7 Kansara, Jadav, Chaudhri, Singh (bib22) 2014; 49 Jadav, Singh (bib5) 2009; 328 Yan, Li, Fan, Ji, Zhang, Zhang (bib34) 2015; 481 Zhuang, Chen, Su, luo, Cao, Wan (bib6) 2015; 493 Peng, Shi, Lan (bib18) 2011; 46 Beltran (10.1016/j.polymer.2018.11.039_bib33) 2013; 88 Zhou (10.1016/j.polymer.2018.11.039_bib15) 2014; 127 Hammouda (10.1016/j.polymer.2018.11.039_bib29) 1995 Rioboo (10.1016/j.polymer.2018.11.039_bib14) 2012; 175 Yin (10.1016/j.polymer.2018.11.039_bib10) 2017; 529 Debye (10.1016/j.polymer.2018.11.039_bib27) 1957; 28 Tang (10.1016/j.polymer.2018.11.039_bib16) 2007; 105 Zhuang (10.1016/j.polymer.2018.11.039_bib3) 2016; 499 Wang (10.1016/j.polymer.2018.11.039_bib12) 2015; 153 Shirazi (10.1016/j.polymer.2018.11.039_bib17) 2012; 124 Zhou (10.1016/j.polymer.2018.11.039_bib8) 2017; 524 Devi (10.1016/j.polymer.2018.11.039_bib21) 2014; 346 García-Payo (10.1016/j.polymer.2018.11.039_bib32) 2000; 230 Han (10.1016/j.polymer.2018.11.039_bib9) 2016 Knozowska (10.1016/j.polymer.2018.11.039_bib1) 2017; 188 Zhang (10.1016/j.polymer.2018.11.039_bib2) 2015; 492 Wang (10.1016/j.polymer.2018.11.039_bib7) 2015; 201 Jadav (10.1016/j.polymer.2018.11.039_bib26) 2013; 1 Vane (10.1016/j.polymer.2018.11.039_bib4) 2005; 80 Zhuang (10.1016/j.polymer.2018.11.039_bib6) 2015; 493 Sun (10.1016/j.polymer.2018.11.039_bib19) 2013; 322 Noble (10.1016/j.polymer.2018.11.039_bib20) 2011; 378 Peng (10.1016/j.polymer.2018.11.039_bib18) 2011; 46 Wang (10.1016/j.polymer.2018.11.039_bib11) 2016; 163 Kessel (10.1016/j.polymer.2018.11.039_bib28) 1991; 7 Xue (10.1016/j.polymer.2018.11.039_bib13) 2014; 4 Kansara (10.1016/j.polymer.2018.11.039_bib25) 2015; 5 Jadav (10.1016/j.polymer.2018.11.039_bib5) 2009; 328 Dozier (10.1016/j.polymer.2018.11.039_bib30) 1991; 24 Jadav (10.1016/j.polymer.2018.11.039_bib24) 2011; 378 Yan (10.1016/j.polymer.2018.11.039_bib34) 2015; 481 Wenzel (10.1016/j.polymer.2018.11.039_bib31) 1936; 28 Aswal (10.1016/j.polymer.2018.11.039_bib23) 2000; 79 Kansara (10.1016/j.polymer.2018.11.039_bib22) 2014; 49 |
| References_xml | – volume: 529 start-page: 286 year: 2017 end-page: 292 ident: bib10 article-title: Free-standing ZIF-71/PDMS nanocomposite membranes for the recovery of ethanol and 1-butanol from water through pervaporation publication-title: J. Membr. Sci. contributor: fullname: Lind – year: 1995 ident: bib29 article-title: A Tutorial on Small-angle Neutron Scattering from Polymers contributor: fullname: Hammouda – volume: 124 start-page: 2871 year: 2012 end-page: 2882 ident: bib17 article-title: Recovery of alcohols from water using polydimethylsiloxane–silica nanocomposite membranes: characterization and pervaporation performance publication-title: J. Appl. Polym. Sci. contributor: fullname: Mohammadi – year: 2016 ident: bib9 article-title: TS-1 molecular sieves filled polydimethylsiloxane membranes for ethanol/water separation via pervaporation publication-title: Polym. Eng. Sci contributor: fullname: Li – volume: 79 start-page: 947 year: 2000 end-page: 953 ident: bib23 article-title: Small-angle neutron scattering diffractometer at Dhruva reactor publication-title: Curr. Sci. contributor: fullname: Goyal – volume: 5 start-page: 51608 year: 2015 end-page: 51620 ident: bib25 article-title: Preparation and characterization of new poly (dimethylsiloxane) membrane series via a ‘cross-linking’reaction using monomolecular trichloro (alkyl) silane of different alkyl chain and type publication-title: RSC Adv. contributor: fullname: Singh – volume: 493 start-page: 37 year: 2015 end-page: 45 ident: bib6 article-title: Improved performance of PDMS/silicalite-1 pervaporation membranes via designing new silicalite-1 particles publication-title: J. Membr. Sci. contributor: fullname: Wan – volume: 188 start-page: 512 year: 2017 end-page: 522 ident: bib1 article-title: Performance of commercial composite hydrophobic membranes applied for pervaporative reclamation of acetone, butanol, and ethanol from aqueous solutions: binary mixtures publication-title: Separ. Purif. Technol. contributor: fullname: Kujawski – volume: 378 start-page: 393 year: 2011 end-page: 397 ident: bib20 article-title: Perspectives on mixed matrix membranes publication-title: J. Membr. Sci. contributor: fullname: Noble – volume: 1 start-page: 4893 year: 2013 end-page: 4903 ident: bib26 article-title: Preparation of bifunctional poly (dimethylsiloxane) membrane by dual X-linking publication-title: J. Mater. Chem. contributor: fullname: Singh – volume: 4 year: 2014 ident: bib13 article-title: A carbon nanotube filled polydimethylsiloxane hybrid membrane for enhanced butanol recovery publication-title: Sci. Rep. contributor: fullname: Yang – volume: 481 start-page: 94 year: 2015 end-page: 105 ident: bib34 article-title: Sonication-enhanced in situ assembly of organic/inorganic hybrid membranes: evolution of nanoparticle distribution and pervaporation performance publication-title: J. Membr. Sci. contributor: fullname: Zhang – volume: 175 start-page: 1 year: 2012 end-page: 10 ident: bib14 article-title: Superhydrophobicity and liquid repellency of solutions on polypropylene publication-title: Adv. Colloid Interface Sci. contributor: fullname: De Coninck – volume: 499 start-page: 386 year: 2016 end-page: 395 ident: bib3 article-title: Surface modification of silicalite-1 with alkoxysilanes to improve the performance of PDMS/silicalite-1 pervaporation membranes: preparation, characterization and modeling publication-title: J. Membr. Sci. contributor: fullname: Wan – volume: 7 start-page: 532 year: 1991 end-page: 538 ident: bib28 article-title: Formation and characterization of a highly ordered and well-anchored alkylsilane monolayer on mica by self-assembly publication-title: Langmuir contributor: fullname: Granick – volume: 378 start-page: 194 year: 2011 end-page: 202 ident: bib24 article-title: Characterization of polydimethylsiloxane pervaporation membranes using small-angle neutron scattering publication-title: J. Membr. Sci. contributor: fullname: Singh – volume: 127 start-page: 61 year: 2014 end-page: 69 ident: bib15 article-title: Novel organic–inorganic pervaporation membrane with a superhydrophobic surface for the separation of ethanol from an aqueous solution publication-title: Separ. Purif. Technol. contributor: fullname: Jin – volume: 105 start-page: 3132 year: 2007 end-page: 3137 ident: bib16 article-title: Preparation and pervaporation performances of fumed-silica-filled polydimethylsiloxane–polyamide (PA) composite membranes publication-title: J. Appl. Polym. Sci. contributor: fullname: Yang – volume: 346 start-page: 9 year: 2014 end-page: 18 ident: bib21 article-title: Preparation and characterization of highly micro-porous PVDF membranes for desalination of saline water through vacuum membrane distillation publication-title: Desalination contributor: fullname: Singh – volume: 28 start-page: 679 year: 1957 end-page: 683 ident: bib27 article-title: Scattering by an inhomogeneous solid. II. The correlation function and its application publication-title: J. Appl. Phys. contributor: fullname: Brumberger – volume: 24 start-page: 2810 year: 1991 end-page: 2814 ident: bib30 article-title: Colloidal nature of star polymer dilute and semidilute solutions publication-title: Macromolecules contributor: fullname: Fetters – volume: 201 start-page: 35 year: 2015 end-page: 42 ident: bib7 article-title: Tuning properties of silicalite-1 for enhanced ethanol/water pervaporation separation in its PDMS hybrid membrane publication-title: Microporous Mesoporous Mater. contributor: fullname: Li – volume: 328 start-page: 257 year: 2009 end-page: 267 ident: bib5 article-title: Synthesis of novel silica-polyamide nanocomposite membrane with enhanced properties publication-title: J. Membr. Sci. contributor: fullname: Singh – volume: 153 start-page: 146 year: 2015 end-page: 155 ident: bib12 article-title: MCM-41@ZIF-8/PDMS hybrid membranes with micro- and nanoscaled hierarchical structure for alcohol permselective pervaporation publication-title: Separ. Purif. Technol. contributor: fullname: Ji – volume: 46 start-page: 420 year: 2011 end-page: 427 ident: bib18 article-title: Preparation of PDMS—silica nanocomposite membranes with silane coupling for recovering ethanol by pervaporation publication-title: Separ. Sci. Technol. contributor: fullname: Lan – volume: 163 start-page: 39 year: 2016 end-page: 47 ident: bib11 article-title: ZIF-7/PDMS mixed matrix membranes for pervaporation recovery of butanol from aqueous solution publication-title: Separ. Purif. Technol. contributor: fullname: Li – volume: 230 start-page: 420 year: 2000 end-page: 431 ident: bib32 article-title: Wetting study of hydrophobic membranes via liquid entry pressure measurements with aqueous alcohol solutions publication-title: J. Colloid Interface Sci. contributor: fullname: Fernández-Pineda – volume: 88 start-page: 2216 year: 2013 end-page: 2226 ident: bib33 article-title: Surface-functionalized silica nanoparticles as fillers in polydimethylsiloxane membrane for the pervaporative recovery of 1-butanol from aqueous solution publication-title: J. Chem. Technol. Biotechnol. contributor: fullname: Chung – volume: 28 start-page: 988 year: 1936 end-page: 994 ident: bib31 article-title: Resistance of solid surfaces to wetting by water publication-title: Ind. Eng. Chem. contributor: fullname: Wenzel – volume: 80 start-page: 603 year: 2005 end-page: 629 ident: bib4 article-title: A review of pervaporation for product recovery from biomass fermentation processes publication-title: J. Chem. Technol. Biotechnol. contributor: fullname: Vane – volume: 49 start-page: 2834 year: 2014 end-page: 2846 ident: bib22 article-title: Preparation of poly(dimethylsiloxane)-polysulfone composite membrane by sequential absorption-reaction-evaporation process and its application in Tteatment of aqueous solution containing volatile organics publication-title: Separ. Sci. Technol. contributor: fullname: Singh – volume: 492 start-page: 322 year: 2015 end-page: 330 ident: bib2 article-title: Enhanced flux of polydimethylsiloxane membrane for ethanol permselective pervaporation via incorporation of MIL-53 particles publication-title: J. Membr. Sci. contributor: fullname: Ji – volume: 524 start-page: 1 year: 2017 end-page: 11 ident: bib8 article-title: Fabrication of high silicalite-1 content filled PDMS thin composite pervaporation membrane for the separation of ethanol from aqueous solutions publication-title: J. Membr. Sci. contributor: fullname: Jin – volume: 322 start-page: 159 year: 2013 end-page: 166 ident: bib19 article-title: Pervaporation of ethanol/water mixture by organophilic nano-silica filled PDMS composite membranes publication-title: Desalination contributor: fullname: Xu – volume: 481 start-page: 94 year: 2015 ident: 10.1016/j.polymer.2018.11.039_bib34 article-title: Sonication-enhanced in situ assembly of organic/inorganic hybrid membranes: evolution of nanoparticle distribution and pervaporation performance publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2015.01.047 contributor: fullname: Yan – volume: 175 start-page: 1 year: 2012 ident: 10.1016/j.polymer.2018.11.039_bib14 article-title: Superhydrophobicity and liquid repellency of solutions on polypropylene publication-title: Adv. Colloid Interface Sci. doi: 10.1016/j.cis.2012.03.003 contributor: fullname: Rioboo – volume: 46 start-page: 420 year: 2011 ident: 10.1016/j.polymer.2018.11.039_bib18 article-title: Preparation of PDMS—silica nanocomposite membranes with silane coupling for recovering ethanol by pervaporation publication-title: Separ. Sci. Technol. doi: 10.1080/01496395.2010.527896 contributor: fullname: Peng – volume: 5 start-page: 51608 issue: 64 year: 2015 ident: 10.1016/j.polymer.2018.11.039_bib25 article-title: Preparation and characterization of new poly (dimethylsiloxane) membrane series via a ‘cross-linking’reaction using monomolecular trichloro (alkyl) silane of different alkyl chain and type publication-title: RSC Adv. doi: 10.1039/C5RA06433C contributor: fullname: Kansara – volume: 346 start-page: 9 year: 2014 ident: 10.1016/j.polymer.2018.11.039_bib21 article-title: Preparation and characterization of highly micro-porous PVDF membranes for desalination of saline water through vacuum membrane distillation publication-title: Desalination doi: 10.1016/j.desal.2014.05.004 contributor: fullname: Devi – volume: 492 start-page: 322 year: 2015 ident: 10.1016/j.polymer.2018.11.039_bib2 article-title: Enhanced flux of polydimethylsiloxane membrane for ethanol permselective pervaporation via incorporation of MIL-53 particles publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2015.05.070 contributor: fullname: Zhang – volume: 201 start-page: 35 year: 2015 ident: 10.1016/j.polymer.2018.11.039_bib7 article-title: Tuning properties of silicalite-1 for enhanced ethanol/water pervaporation separation in its PDMS hybrid membrane publication-title: Microporous Mesoporous Mater. doi: 10.1016/j.micromeso.2014.09.010 contributor: fullname: Wang – volume: 153 start-page: 146 year: 2015 ident: 10.1016/j.polymer.2018.11.039_bib12 article-title: MCM-41@ZIF-8/PDMS hybrid membranes with micro- and nanoscaled hierarchical structure for alcohol permselective pervaporation publication-title: Separ. Purif. Technol. doi: 10.1016/j.seppur.2015.09.004 contributor: fullname: Wang – volume: 28 start-page: 988 year: 1936 ident: 10.1016/j.polymer.2018.11.039_bib31 article-title: Resistance of solid surfaces to wetting by water publication-title: Ind. Eng. Chem. doi: 10.1021/ie50320a024 contributor: fullname: Wenzel – volume: 4 year: 2014 ident: 10.1016/j.polymer.2018.11.039_bib13 article-title: A carbon nanotube filled polydimethylsiloxane hybrid membrane for enhanced butanol recovery publication-title: Sci. Rep. doi: 10.1038/srep05925 contributor: fullname: Xue – volume: 322 start-page: 159 year: 2013 ident: 10.1016/j.polymer.2018.11.039_bib19 article-title: Pervaporation of ethanol/water mixture by organophilic nano-silica filled PDMS composite membranes publication-title: Desalination doi: 10.1016/j.desal.2013.05.008 contributor: fullname: Sun – volume: 524 start-page: 1 year: 2017 ident: 10.1016/j.polymer.2018.11.039_bib8 article-title: Fabrication of high silicalite-1 content filled PDMS thin composite pervaporation membrane for the separation of ethanol from aqueous solutions publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2016.11.029 contributor: fullname: Zhou – volume: 127 start-page: 61 year: 2014 ident: 10.1016/j.polymer.2018.11.039_bib15 article-title: Novel organic–inorganic pervaporation membrane with a superhydrophobic surface for the separation of ethanol from an aqueous solution publication-title: Separ. Purif. Technol. doi: 10.1016/j.seppur.2014.02.032 contributor: fullname: Zhou – volume: 88 start-page: 2216 year: 2013 ident: 10.1016/j.polymer.2018.11.039_bib33 article-title: Surface-functionalized silica nanoparticles as fillers in polydimethylsiloxane membrane for the pervaporative recovery of 1-butanol from aqueous solution publication-title: J. Chem. Technol. Biotechnol. doi: 10.1002/jctb.4090 contributor: fullname: Beltran – year: 1995 ident: 10.1016/j.polymer.2018.11.039_bib29 contributor: fullname: Hammouda – volume: 188 start-page: 512 year: 2017 ident: 10.1016/j.polymer.2018.11.039_bib1 article-title: Performance of commercial composite hydrophobic membranes applied for pervaporative reclamation of acetone, butanol, and ethanol from aqueous solutions: binary mixtures publication-title: Separ. Purif. Technol. doi: 10.1016/j.seppur.2017.07.072 contributor: fullname: Knozowska – volume: 529 start-page: 286 year: 2017 ident: 10.1016/j.polymer.2018.11.039_bib10 article-title: Free-standing ZIF-71/PDMS nanocomposite membranes for the recovery of ethanol and 1-butanol from water through pervaporation publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2017.02.006 contributor: fullname: Yin – volume: 79 start-page: 947 year: 2000 ident: 10.1016/j.polymer.2018.11.039_bib23 article-title: Small-angle neutron scattering diffractometer at Dhruva reactor publication-title: Curr. Sci. contributor: fullname: Aswal – volume: 28 start-page: 679 year: 1957 ident: 10.1016/j.polymer.2018.11.039_bib27 article-title: Scattering by an inhomogeneous solid. II. The correlation function and its application publication-title: J. Appl. Phys. doi: 10.1063/1.1722830 contributor: fullname: Debye – volume: 7 start-page: 532 year: 1991 ident: 10.1016/j.polymer.2018.11.039_bib28 article-title: Formation and characterization of a highly ordered and well-anchored alkylsilane monolayer on mica by self-assembly publication-title: Langmuir doi: 10.1021/la00051a020 contributor: fullname: Kessel – volume: 163 start-page: 39 year: 2016 ident: 10.1016/j.polymer.2018.11.039_bib11 article-title: ZIF-7/PDMS mixed matrix membranes for pervaporation recovery of butanol from aqueous solution publication-title: Separ. Purif. Technol. doi: 10.1016/j.seppur.2016.02.040 contributor: fullname: Wang – year: 2016 ident: 10.1016/j.polymer.2018.11.039_bib9 article-title: TS-1 molecular sieves filled polydimethylsiloxane membranes for ethanol/water separation via pervaporation publication-title: Polym. Eng. Sci doi: 10.1002/pen.24283 contributor: fullname: Han – volume: 124 start-page: 2871 year: 2012 ident: 10.1016/j.polymer.2018.11.039_bib17 article-title: Recovery of alcohols from water using polydimethylsiloxane–silica nanocomposite membranes: characterization and pervaporation performance publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.35313 contributor: fullname: Shirazi – volume: 493 start-page: 37 year: 2015 ident: 10.1016/j.polymer.2018.11.039_bib6 article-title: Improved performance of PDMS/silicalite-1 pervaporation membranes via designing new silicalite-1 particles publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2015.06.043 contributor: fullname: Zhuang – volume: 80 start-page: 603 year: 2005 ident: 10.1016/j.polymer.2018.11.039_bib4 article-title: A review of pervaporation for product recovery from biomass fermentation processes publication-title: J. Chem. Technol. Biotechnol. doi: 10.1002/jctb.1265 contributor: fullname: Vane – volume: 378 start-page: 194 year: 2011 ident: 10.1016/j.polymer.2018.11.039_bib24 article-title: Characterization of polydimethylsiloxane pervaporation membranes using small-angle neutron scattering publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2011.05.006 contributor: fullname: Jadav – volume: 230 start-page: 420 year: 2000 ident: 10.1016/j.polymer.2018.11.039_bib32 article-title: Wetting study of hydrophobic membranes via liquid entry pressure measurements with aqueous alcohol solutions publication-title: J. Colloid Interface Sci. doi: 10.1006/jcis.2000.7106 contributor: fullname: García-Payo – volume: 378 start-page: 393 year: 2011 ident: 10.1016/j.polymer.2018.11.039_bib20 article-title: Perspectives on mixed matrix membranes publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2011.05.031 contributor: fullname: Noble – volume: 24 start-page: 2810 year: 1991 ident: 10.1016/j.polymer.2018.11.039_bib30 article-title: Colloidal nature of star polymer dilute and semidilute solutions publication-title: Macromolecules doi: 10.1021/ma00010a026 contributor: fullname: Dozier – volume: 105 start-page: 3132 year: 2007 ident: 10.1016/j.polymer.2018.11.039_bib16 article-title: Preparation and pervaporation performances of fumed-silica-filled polydimethylsiloxane–polyamide (PA) composite membranes publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.26471 contributor: fullname: Tang – volume: 499 start-page: 386 year: 2016 ident: 10.1016/j.polymer.2018.11.039_bib3 article-title: Surface modification of silicalite-1 with alkoxysilanes to improve the performance of PDMS/silicalite-1 pervaporation membranes: preparation, characterization and modeling publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2015.10.018 contributor: fullname: Zhuang – volume: 328 start-page: 257 year: 2009 ident: 10.1016/j.polymer.2018.11.039_bib5 article-title: Synthesis of novel silica-polyamide nanocomposite membrane with enhanced properties publication-title: J. Membr. Sci. doi: 10.1016/j.memsci.2008.12.014 contributor: fullname: Jadav – volume: 1 start-page: 4893 year: 2013 ident: 10.1016/j.polymer.2018.11.039_bib26 article-title: Preparation of bifunctional poly (dimethylsiloxane) membrane by dual X-linking publication-title: J. Mater. Chem. doi: 10.1039/c3ta10358g contributor: fullname: Jadav – volume: 49 start-page: 2834 year: 2014 ident: 10.1016/j.polymer.2018.11.039_bib22 article-title: Preparation of poly(dimethylsiloxane)-polysulfone composite membrane by sequential absorption-reaction-evaporation process and its application in Tteatment of aqueous solution containing volatile organics publication-title: Separ. Sci. Technol. doi: 10.1080/01496395.2014.944619 contributor: fullname: Kansara |
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| SubjectTerms | Alcohols Asymmetric nanostructure Compatibility Membrane structure Membrane structures Membranes Morphology Nanomaterials Nanotechnology Neutron scattering Organophilic silica nanomaterial PDMS Pervaporation Polydimethylsiloxane Scattering Silica Silicon dioxide Silicone resins |
| Title | Structure-property interplay of asymmetric membranes comprising of soft polydimethylsiloxane chains and hard silica nanomaterials |
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