Studies on monitoring the composition of the copolymer by cyclic voltammetry and in situ spectroelectrochemical analysis

Electrochemical copolymerization of diphenylamine (DPA) with ortho-toluidine (OT) was carried out in 4 M sulphuric acid medium by cyclic voltammetry. Cyclic voltammograms (CVs) of the copolymer films were recorded to deduce the electrochemical characteristics. In situ UV–visible spectroelectrochemic...

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Published inEuropean polymer journal Vol. 41; no. 1; pp. 97 - 105
Main Authors Santhosh, P., Gopalan, A., Vasudevan, T., Wen, T.-C.
Format Journal Article
LanguageEnglish
Published Oxford Elsevier Ltd 2005
Elsevier
Subjects
Applied sciences
Copolymer composition
Cyclic voltammetry
Electrocopolymerization
Exact sciences and technology
In situ spectroelectro studies
Physicochemistry of polymers
Polymerization
Polymers and radiations
Reactivity ratios
UV–visible spectroscopy
Cyclic voltammetry
Copolymer composition
In situ spectroelectro studies
Electrocopolymerization
UV–visible spectroscopy
Reactivity ratios
Aniline derivative polymer
UV-visible spectroscopy
Electrolytical copolymerization
In situ
Experimental study
Reactivity ratio
Conducting polymers
Aromatic copolymer
Reaction mechanism
Chemical composition
Aniline derivative copolymer
Spectroelectrochemistry
Monitoring
Ultraviolet visible spectrometry
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Abstract Electrochemical copolymerization of diphenylamine (DPA) with ortho-toluidine (OT) was carried out in 4 M sulphuric acid medium by cyclic voltammetry. Cyclic voltammograms (CVs) of the copolymer films were recorded to deduce the electrochemical characteristics. In situ UV–visible spectroelectrochemical studies on copolymerization were carried out using indium tin oxide (ITO) coated glass plate as working electrode for different feed ratios of DPA and OT. UV-visible spectral characteristics show clear dependencies on the molar feed composition of DPA or OT used in electropolymerization. Derivative cyclic voltabsorptogram (DCVA) was deduced at the wavelength corresponding to the absorption by the intermediate species and used to identify the intermediates generated during the electropolymerization. The molar composition of DPA and OT units in the copolymer for the copolymers synthesized with different molar feed ratios of DPA and OT was determined by UV–visible spectroscopy. Reactivity ratios of DPA and OT were deduced by using Fineman–Ross and Kelen–Tudos methods and the observed differences in the composition of DPA/OT in the copolymers were correlated with CV characteristics and results obtained from in situ spectroelectrochemical studies.
AbstractList Electrochemical copolymerization of diphenylamine (DPA) with ortho-toluidine (OT) was carried out in 4M sulphuric acid medium by cyclic voltammetry. Cyclic voltammograms (CVs) of the copolymer films were recorded to deduce the electrochemical characteristics. In situ UVvisible spectroelectrochemical studies on copolymerization were carried out using indium tin oxide (ITO) coated glass plate as working electrode for different feed ratios of DPA and OT. U V-visible spectral characteristics show clear dependencies on the molar feed composition of DPA or OT used in electropolymerization. Derivative cyclic voltabsorptogram (DCVA) was deduced at the wavelength corresponding to the absorption by the intermediate species and used to identify the intermediates generated during the electropolymerization. The molar composition of DPA and OT units in the copolymer for the copolymers synthesized with different molar feed ratios of DPA and OT was determined by UVvisible spectroscopy. Reactivity ratios of DPA and OT were deduced by using FinemanRoss and KelenTudos methods and the observed differences in the composition of DPA/ OT in the copolymers were correlated with CV characteristics and results obtained from in situ spectroelectrochemical studies.
Electrochemical copolymerization of diphenylamine (DPA) with ortho-toluidine (OT) was carried out in 4 M sulphuric acid medium by cyclic voltammetry. Cyclic voltammograms (CVs) of the copolymer films were recorded to deduce the electrochemical characteristics. In situ UV–visible spectroelectrochemical studies on copolymerization were carried out using indium tin oxide (ITO) coated glass plate as working electrode for different feed ratios of DPA and OT. UV-visible spectral characteristics show clear dependencies on the molar feed composition of DPA or OT used in electropolymerization. Derivative cyclic voltabsorptogram (DCVA) was deduced at the wavelength corresponding to the absorption by the intermediate species and used to identify the intermediates generated during the electropolymerization. The molar composition of DPA and OT units in the copolymer for the copolymers synthesized with different molar feed ratios of DPA and OT was determined by UV–visible spectroscopy. Reactivity ratios of DPA and OT were deduced by using Fineman–Ross and Kelen–Tudos methods and the observed differences in the composition of DPA/OT in the copolymers were correlated with CV characteristics and results obtained from in situ spectroelectrochemical studies.
Author Gopalan, A.
Santhosh, P.
Vasudevan, T.
Wen, T.-C.
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  surname: Wen
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  organization: Department of Chemical Engineering, National Cheng Kung University, Tainan 701, Taiwan
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Issue 1
Keywords Cyclic voltammetry
Copolymer composition
In situ spectroelectro studies
Electrocopolymerization
UV–visible spectroscopy
Reactivity ratios
Aniline derivative polymer
UV-visible spectroscopy
Electrolytical copolymerization
In situ
Experimental study
Reactivity ratio
Conducting polymers
Aromatic copolymer
Reaction mechanism
Chemical composition
Aniline derivative copolymer
Spectroelectrochemistry
Monitoring
Ultraviolet visible spectrometry
Language English
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Snippet Electrochemical copolymerization of diphenylamine (DPA) with ortho-toluidine (OT) was carried out in 4 M sulphuric acid medium by cyclic voltammetry. Cyclic...
Electrochemical copolymerization of diphenylamine (DPA) with ortho-toluidine (OT) was carried out in 4M sulphuric acid medium by cyclic voltammetry. Cyclic...
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SubjectTerms Applied sciences
Copolymer composition
Cyclic voltammetry
Electrocopolymerization
Exact sciences and technology
In situ spectroelectro studies
Physicochemistry of polymers
Polymerization
Polymers and radiations
Reactivity ratios
UV–visible spectroscopy
Title Studies on monitoring the composition of the copolymer by cyclic voltammetry and in situ spectroelectrochemical analysis
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