Solvatochromic effect studies on the absorption spectra of 4-((2-ethylphenyl)diazenyl)benzene-1,3-diol and 2-((2-ethylphenyl)diazenyl)benzene-1,3,5-triol molecules
The electronic absorption spectra of 4-((2-ethylphenyl)diazenyl)benzene-1,3-diol and 2-((2-ethylphenyl)diazenyl)benzene-1,3,5-triol molecules in the nine different solvent variable electronic characters have been recorded. The solvent dependent maximum absorption band (π–π* transitions) shifts, ν ma...
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Published in | International journal of hydrogen energy Vol. 34; no. 12; pp. 5255 - 5259 |
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Abstract | The electronic absorption spectra of 4-((2-ethylphenyl)diazenyl)benzene-1,3-diol and 2-((2-ethylphenyl)diazenyl)benzene-1,3,5-triol molecules in the nine different solvent variable electronic characters have been recorded. The solvent dependent maximum absorption band (π–π* transitions) shifts,
ν
max, were analyzed using a wide range of parameters such as refractive index, dielectric constant and Kamlet–Taft parameters [hydrogen bond donating ability (
α) and hydrogen bond accepting ability (
β)]. The electronic transitions are assigned and the solvent-induced spectral shifts have been analyzed in relation to the different solute–solvent interaction mechanism using computational chemistry. The intermolecular interaction types in the azobenzene derivatives solutions have been established on the basis of a multiple linear regression analysis. The fitting coefficients obtained from this analysis allowed us to estimate the contribution of each type of interactions to the total spectral shifts in the studied solutions. |
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AbstractList | The electronic absorption spectra of 4-((2-ethylphenyl)diazenyl)benzene-1,3-diol and 2-((2-ethylphenyl)diazenyl)benzene-1,3,5-triol molecules in the nine different solvent variable electronic characters have been recorded. The solvent dependent maximum absorption band ([pi]-[pi]* transitions) shifts, [nu] sub(max, were analyzed using a wide range of parameters such as refractive index, dielectric constant and Kamlet-Taft parameters [hydrogen bond donating ability ( alpha ) and hydrogen bond accepting ability ( beta )]. The electronic transitions are assigned and the solvent-induced spectral shifts have been analyzed in relation to the different solute-solvent interaction mechanism using computational chemistry. The intermolecular interaction types in the azobenzene derivatives solutions have been established on the basis of a multiple linear regression analysis. The fitting coefficients obtained from this analysis allowed us to estimate the contribution of each type of interactions to the total spectral shifts in the studied solutions.) The electronic absorption spectra of 4-((2-ethylphenyl)diazenyl)benzene-1,3-diol and 2-((2-ethylphenyl)diazenyl)benzene-1,3,5-triol molecules in the nine different solvent variable electronic characters have been recorded. The solvent dependent maximum absorption band (π–π* transitions) shifts, ν max, were analyzed using a wide range of parameters such as refractive index, dielectric constant and Kamlet–Taft parameters [hydrogen bond donating ability ( α) and hydrogen bond accepting ability ( β)]. The electronic transitions are assigned and the solvent-induced spectral shifts have been analyzed in relation to the different solute–solvent interaction mechanism using computational chemistry. The intermolecular interaction types in the azobenzene derivatives solutions have been established on the basis of a multiple linear regression analysis. The fitting coefficients obtained from this analysis allowed us to estimate the contribution of each type of interactions to the total spectral shifts in the studied solutions. |
Author | Güngör, Tayyar Berber, Halil Sıdır, İsa Taşal, Erol Öğretir, Cemil Gülseven, Yadigar |
Author_xml | – sequence: 1 givenname: Yadigar surname: Gülseven fullname: Gülseven, Yadigar organization: Department of Physics, Faculty of Arts & Sciences, Eskişehir Osmangazi University, Eskişehir 26480, Turkey – sequence: 2 givenname: Erol surname: Taşal fullname: Taşal, Erol email: etasal@ogu.edu.tr organization: Department of Physics, Faculty of Arts & Sciences, Eskişehir Osmangazi University, Eskişehir 26480, Turkey – sequence: 3 givenname: İsa surname: Sıdır fullname: Sıdır, İsa organization: Department of Physics, Faculty of Arts & Sciences, Eskişehir Osmangazi University, Eskişehir 26480, Turkey – sequence: 4 givenname: Tayyar surname: Güngör fullname: Güngör, Tayyar organization: Department of Physics, Faculty of Arts & Sciences, Akdeniz University, Antalya, Turkey – sequence: 5 givenname: Halil surname: Berber fullname: Berber, Halil organization: Department of Chemistry, Faculty of Sciences, Anadolu University, Eskişehir, Turkey – sequence: 6 givenname: Cemil surname: Öğretir fullname: Öğretir, Cemil organization: Department of Chemistry, Faculty of Arts & Sciences, Eskişehir Osmangazi University, Eskişehir, Turkey |
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Keywords | Solvent–solute interactions Electronic absorption spectra Solvatochromic effect Azoaromatic compounds Solvent effect Dyes Solvent-solute interactions Linear regression Benzene derivatives Solvatochromism Azo compound Azo dye Solar energy Azobenzene |
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References | Muruganandham, Shabana, Swaminathan (bib8) 2006; 246 Sakthivel, Neppolian, Shankar, Arabindo, Palanichamy, Murugesan (bib6) 2003; 77 Rau (bib1) 1990; vol. 2 Rusu E, Dorohoi DO, Airinei A. Solvatochromic effects in the absorption spectra of some azobenzene compounds. J Mol Struct, doi:10.1016/j.molstruc.2008.01.053. Fraleoni-Morgera, Giorgini, Zanirato (bib15) 2008; 76 Airinei, Rusu, Dorohoi (bib16) 2001; 34 Masoud, Ali, Shaker, Ghani (bib4) 2004; 60A Mijin, Ušćumlić, Perišić-Janjić, Valentić (bib12) 2006; 418 Masoud, Ali, Shaker, Ghani (bib14) 2005; 61A Muruganandham, Swaminathan (bib7) 2004; 81 Kamlet, Abboud, Abraham, Taft (bib20) 1983; 48 Reichardt (bib9) 1991 Yarushchuk, Sergan, Lindau, Leve, Chien (bib3) 2001; 114 Aksu N. Synthesis of monoazo compounds of some substitue anilin with benzene-1,3-diol and investigation of their tautomeric equilibrium, Anadolu University, Graduate School of Science, Chemistry Program, Master of Science thesis, January 2007. Lakowicz (bib10) 1983 Liu, Zou, Ye, Ni, Zhang (bib22) 1999; 863 Marcus (bib11) 1998 Kim, Funabiki, Muramatsu, Shibata, Kim, Shiazaki (bib23) 2001 Lide (bib21) 1995 Kumar (bib2) 1992 Klymchenko, Demchenko (bib17) 2006; 418 Yıldırım S. Synthesis of monoazo compounds of some substitue aniline with benzene-1,3,5-triol investigation of their tautomeric equilibrium, Anadolu University, Graduate School of Science, Chemistry Program, Master of Science thesis, January 2007. Nakamura, Shibusawa (bib5) 2000; 70 |
References_xml | – year: 1992 ident: bib2 article-title: Azo functional polymers contributor: fullname: Kumar – volume: 418 start-page: 223 year: 2006 end-page: 229 ident: bib12 article-title: Substituent and solvent effects on the UV/vis absorption spectra of 5-(3- and 4-substituted arylazo)-4,6-dimethyl-3-cyano-2-pyridones publication-title: Chem Phys Lett contributor: fullname: Valentić – year: 1995 ident: bib21 article-title: Hanbook of chemistry and physics contributor: fullname: Lide – start-page: 379 year: 2001 ident: bib23 article-title: Synthesis, structure, and UV–VIS absorption spectra of azo dyes derived from (dialkylamino)thiazole dimers publication-title: J Chem Soc Perkin Trans 2 contributor: fullname: Shiazaki – volume: 34 start-page: 65 year: 2001 end-page: 74 ident: bib16 article-title: Solvent influence on the electronic absorption spectra of some azoaromatic compounds publication-title: Spectrosc Lett contributor: fullname: Dorohoi – volume: 48 start-page: 2877 year: 1983 ident: bib20 article-title: Linear solvation energy relationships. 23. A comprehensive collection of the solvatochromic parameters, π publication-title: J Org Chem contributor: fullname: Taft – volume: 60A start-page: 3155 year: 2004 end-page: 3159 ident: bib4 article-title: Solvatochromic behavior of the electronic absorption spectra of some azo derivatives of amino pyridines publication-title: Spectrochim Acta contributor: fullname: Ghani – volume: vol. 2 year: 1990 ident: bib1 publication-title: Photochemistry and photophysics contributor: fullname: Rau – volume: 70 start-page: 801 year: 2000 end-page: 809 ident: bib5 article-title: Color change of disperse dyes on Nylon 6 films with the dye concentration publication-title: Text Res J contributor: fullname: Shibusawa – volume: 81 start-page: 439 year: 2004 end-page: 457 ident: bib7 article-title: Solar photocatalytic degradation of a reactive azo dye in TiO publication-title: Solar Energy Solar Cells contributor: fullname: Swaminathan – volume: 246 start-page: 154 year: 2006 end-page: 161 ident: bib8 article-title: Optimization of solar photocatalytic degradation conditions of Reactive Yellow 14 azo dye in aqueous TiO publication-title: J Mol Catal A Chem contributor: fullname: Swaminathan – volume: 418 start-page: 223 year: 2006 end-page: 229 ident: bib17 article-title: Multiparametric probing of intermolecular interactions with fluorescent dye exhibiting excited state intramolecular proton transfer publication-title: Chem Phys Lett contributor: fullname: Demchenko – volume: 61A start-page: 3102 year: 2005 end-page: 3107 ident: bib14 article-title: Solvent and substituent effects on spectroscopical changes of some diazoaminobenzene derivatives publication-title: Spectrochim Acta contributor: fullname: Ghani – volume: 76 start-page: 394 year: 2008 end-page: 399 ident: bib15 article-title: [Arylazobenzene-BF publication-title: Dyes Pigments contributor: fullname: Zanirato – volume: 77 start-page: 65 year: 2003 end-page: 82 ident: bib6 article-title: Solar photocatalytic degradation of azo dye: Comparison of photocatalytic efficiency of ZnO and TiO publication-title: Solar Energy Mater Solar Cells contributor: fullname: Murugesan – volume: 114 start-page: 5330 year: 2001 ident: bib3 article-title: Light induced structures in liquid crystalline side-chain polymers with azobenzene functional groups publication-title: J Chem Phys contributor: fullname: Chien – volume: 863 start-page: 69 year: 1999 end-page: 76 ident: bib22 article-title: Effects of organic modifiers on retention mechanism and selectivity in micellar electrokinetic capillary chromatography studied by linear solvation energy relationships publication-title: J Chromatogr A contributor: fullname: Zhang – year: 1998 ident: bib11 article-title: The properties of solvents contributor: fullname: Marcus – year: 1983 ident: bib10 article-title: Principle of flourescence spectroscopy contributor: fullname: Lakowicz – year: 1991 ident: bib9 article-title: Solvents and solvent effects in organic chemistry contributor: fullname: Reichardt |
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SubjectTerms | Absorption spectra Applied sciences Azoaromatic compounds Chemical industry and chemicals Derivatives Dyes, pigments Electronic absorption spectra Electronics Energy Exact sciences and technology Hydrogen bonds Industrial chemicals Mathematical models Natural energy Regression analysis Solar energy Solvatochromic effect Solvents Solvent–solute interactions Spectra |
Title | Solvatochromic effect studies on the absorption spectra of 4-((2-ethylphenyl)diazenyl)benzene-1,3-diol and 2-((2-ethylphenyl)diazenyl)benzene-1,3,5-triol molecules |
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