Isobutene hydration over Amberlyst-15 in a slurry reactor

The synthesis of tertiary butyl alcohol (TBA) via isobutene (iB) hydration was studied over Amberlyst-15 sulfonic acid catalyst particles using pure water and aqueous TBA solutions in a bubbling slurry reactor. Preliminary studies to investigate mass transfer effects showed that pore diffusion was p...

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Published inChemical engineering and processing Vol. 42; no. 12; pp. 985 - 991
Main Authors Zhang, C.M., Adesina, A.A., Wainwright, M.S.
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 01.12.2003
Elsevier
Subjects
Amberlyst-15
Applied sciences
Bubbling slurry reactor
Catalysis
Catalytic reactions
Chemical engineering
Chemistry
Exact sciences and technology
General and physical chemistry
Isobutene hydration
Reactors
TBA effect
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Bubbling slurry reactor
Amberlyst-15
Isobutene hydration
TBA effect
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Abstract The synthesis of tertiary butyl alcohol (TBA) via isobutene (iB) hydration was studied over Amberlyst-15 sulfonic acid catalyst particles using pure water and aqueous TBA solutions in a bubbling slurry reactor. Preliminary studies to investigate mass transfer effects showed that pore diffusion was present for catalyst particles greater than 165 μm in diameter. Therefore, intrinsic kinetic measurements were made using 90.5 μm catalyst particles and a catalyst loading of 10 kg m −3. The kinetic measurements revealed that iB hydration is a pseudo-first-order reaction with an activation energy of 69 kJ mol −1. Isobutene hydration experiments using TBA concentrations in water revealed a hindering effect of TBA, which indicates that separation of TBA formed by iB hydration in three-phase reactors using catalytic distillation is promising from a process design perspective.
AbstractList The synthesis of tertiary butyl alcohol (TBA) via isobutene (iB) hydration was studied over Amberlyst-15 sulfonic acid catalyst particles using pure water and aqueous TBA solutions in a bubbling slurry reactor. Preliminary studies to investigate mass transfer effects showed that pore diffusion was present for catalyst particles greater than 165 μm in diameter. Therefore, intrinsic kinetic measurements were made using 90.5 μm catalyst particles and a catalyst loading of 10 kg m −3. The kinetic measurements revealed that iB hydration is a pseudo-first-order reaction with an activation energy of 69 kJ mol −1. Isobutene hydration experiments using TBA concentrations in water revealed a hindering effect of TBA, which indicates that separation of TBA formed by iB hydration in three-phase reactors using catalytic distillation is promising from a process design perspective.
Author Zhang, C.M.
Wainwright, M.S.
Adesina, A.A.
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  email: m.wainwright@unsw.edu.au
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Issue 12
Keywords Bubbling slurry reactor
Amberlyst-15
Isobutene hydration
TBA effect
Language English
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Snippet The synthesis of tertiary butyl alcohol (TBA) via isobutene (iB) hydration was studied over Amberlyst-15 sulfonic acid catalyst particles using pure water and...
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SubjectTerms Amberlyst-15
Applied sciences
Bubbling slurry reactor
Catalysis
Catalytic reactions
Chemical engineering
Chemistry
Exact sciences and technology
General and physical chemistry
Isobutene hydration
Reactors
TBA effect
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Title Isobutene hydration over Amberlyst-15 in a slurry reactor
URI https://dx.doi.org/10.1016/S0255-2701(02)00169-1
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