Conversion coating growth on 2024-T3 Al alloy. The effect of pre-treatments

The cleaning pre-treatments, generally based on alkaline etching and acid pickling, provide a surface standard condition before the application of conversion coatings. In this work, the effect of cleaning pre-treatments on the surface morphology and activity of 2024-T3 Al alloy and on chromium-free...

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Published inSurface & coatings technology Vol. 202; no. 14; pp. 3396 - 3402
Main Authors Rangel, C.M., Paiva, T.I., da Luz, P.P
Format Journal Article
LanguageEnglish
Published Lausanne Elsevier B.V 15.04.2008
Elsevier
Subjects
2024 aluminium alloy
Applied sciences
Benzotriazole
Cerium salts
Conversion coatings
Corrosion
Corrosion prevention
Cross-disciplinary physics: materials science; rheology
Exact sciences and technology
Materials science
Metals. Metallurgy
Physics
Pre-treatments
Production techniques
Surface treatment
Surface treatments
2024 aluminium alloy
Pre-treatments
Cerium salts
Conversion coatings
Benzotriazole
Aluminium base alloys
Conversion coating
Cerium
Surface treatments
Corrosion protection
Coatings
Corrosion inhibitors
Rare earths
Pretreatment
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Abstract The cleaning pre-treatments, generally based on alkaline etching and acid pickling, provide a surface standard condition before the application of conversion coatings. In this work, the effect of cleaning pre-treatments on the surface morphology and activity of 2024-T3 Al alloy and on chromium-free Ce-based conversion coatings formation has been studied. Variations in the open circuit potential of the alloy of ~ 1.5 V were registered during the cleaning pre-treatment, accounting for the complex electrochemical phenomena involved. Even though, the presence and concentration of additives such as H 2O 2 was found to be essential to a fast kinetics coating formation, effective cleaning pre-treatments are demonstrated to be associated to the production of grained well structured coatings, allowing necessary redox reactions for conversion coating formation. The effect of copper-rich areas and its effect on the conversion coating growth rate and morphology were also studied using benzotriazole additions at different stages in the cleaning pre-treatments.
AbstractList The cleaning pre-treatments, generally based on alkaline etching and acid pickling, provide a surface standard condition before the application of conversion coatings. In this work, the effect of cleaning pre-treatments on the surface morphology and activity of 2024-T3 Al alloy and on chromium-free Ce-based conversion coatings formation has been studied. Variations in the open circuit potential of the alloy of ~1.5V were registered during the cleaning pre-treatment, accounting for the complex electrochemical phenomena involved. Even though, the presence and concentration of additives such as H2O2 was found to be essential to a fast kinetics coating formation, effective cleaning pre-treatments are demonstrated to be associated to the production of grained well structured coatings, allowing necessary redox reactions for conversion coating formation. The effect of copper-rich areas and its effect on the conversion coating growth rate and morphology were also studied using benzotriazole additions at different stages in the cleaning pre-treatments.
The cleaning pre-treatments, generally based on alkaline etching and acid pickling, provide a surface standard condition before the application of conversion coatings. In this work, the effect of cleaning pre-treatments on the surface morphology and activity of 2024-T3 Al alloy and on chromium-free Ce-based conversion coatings formation has been studied. Variations in the open circuit potential of the alloy of ~ 1.5 V were registered during the cleaning pre-treatment, accounting for the complex electrochemical phenomena involved. Even though, the presence and concentration of additives such as H 2O 2 was found to be essential to a fast kinetics coating formation, effective cleaning pre-treatments are demonstrated to be associated to the production of grained well structured coatings, allowing necessary redox reactions for conversion coating formation. The effect of copper-rich areas and its effect on the conversion coating growth rate and morphology were also studied using benzotriazole additions at different stages in the cleaning pre-treatments.
Author da Luz, P.P
Paiva, T.I.
Rangel, C.M.
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Issue 14
Keywords 2024 aluminium alloy
Pre-treatments
Cerium salts
Conversion coatings
Benzotriazole
Aluminium base alloys
Conversion coating
Cerium
Surface treatments
Corrosion protection
Coatings
Corrosion inhibitors
Rare earths
Pretreatment
Language English
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Snippet The cleaning pre-treatments, generally based on alkaline etching and acid pickling, provide a surface standard condition before the application of conversion...
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SubjectTerms 2024 aluminium alloy
Applied sciences
Benzotriazole
Cerium salts
Conversion coatings
Corrosion
Corrosion prevention
Cross-disciplinary physics: materials science; rheology
Exact sciences and technology
Materials science
Metals. Metallurgy
Physics
Pre-treatments
Production techniques
Surface treatment
Surface treatments
Title Conversion coating growth on 2024-T3 Al alloy. The effect of pre-treatments
URI https://dx.doi.org/10.1016/j.surfcoat.2007.12.017
https://search.proquest.com/docview/32295836
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