Oriented Assembly of 2D Metal-Pyridylporphyrinic Framework Films for Giant Nonlinear Optical Limiting

• Published in: Nano letters Vol. 21; no. 23; pp. 10012 - 10018
• Main Authors: Li, De-Jing, Li, Qiao-hong, Gu, Zhi-Gang, Zhang, Jian
• Format: Journal Article
• Language: English
• Published: United States 08.12.2021
• Subjects: Ligands; Metal-Organic Frameworks; Metalloporphyrins; Porphyrins; Zinc Compounds; Metal−organic framework; Metalloporphyrin; Third-order nonlinear optics; Film; Two-dimensional

The development of metal-organic frameworks (MOFs) with nonlinear optical (NLO) properties is of pronounced significance for optical devices. Herein, a series of 2D MOFs ZnTPyP(M) (TPyP = 5,10,15,20-tetrakis(4-pyridyl)porphyrin, M = Cu, Ni, Mn, H ) films with [010]-orientation growth composed of ult...