Terpenes and Terpenoids: Building Blocks to Produce Biopolymers

Polymers are essential materials in our daily life. The synthesis of value-added polymers is mainly performed from fossil fuel-derived monomers. However, the adoption of the circular economy model based on the bioeconomy will reduce the dependence on fossil fuels. In this context, biorefineries have...

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Published inSustainable chemistry Vol. 2; no. 3; pp. 467 - 492
Main Authors Mosquera, Marta. E. G., Jiménez, Gerardo, Tabernero, Vanessa, Vinueza-Vaca, Joan, García-Estrada, Carlos, Kosalková, Katarina, Sola-Landa, Alberto, Monje, Belén, Acosta, Carolina, Alonso, Rafael, Valera, Miguel Ángel
Format Journal Article
LanguageEnglish
Published Basel MDPI AG 01.09.2021
Subjects
bio-based polymers
Biodegradation
Biomass
Bioplastics
Biopolymers
Biorefineries
Carbohydrates
catalyst
Cellulose acetate
Chemical properties
Chemical synthesis
Circular economy
Climate change
Consumer goods
Copolymers
Environmental impact
Fatty acids
Fossil fuels
Glucose
Lignin
Lignocellulose
Microorganisms
Monomers
Plastics
Polyethylene terephthalate
Polylactic acid
Polymerization
Polymers
Polyvinyl alcohol
Proteins
REX
Terpenes
terpenoids
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Abstract Polymers are essential materials in our daily life. The synthesis of value-added polymers is mainly performed from fossil fuel-derived monomers. However, the adoption of the circular economy model based on the bioeconomy will reduce the dependence on fossil fuels. In this context, biorefineries have emerged to convert biomass into bioenergy and produce high value-added products, including molecules that can be further used as building blocks for the synthesis of biopolymers and bioplastics. The achievement of catalytic systems able to polymerize the natural monomer counterparts, such as terpenes or terpenoids, is still a challenge in the development of polymers with good mechanical, thermal, and chemical properties. This review describes the most common types of bioplastics and biopolymers and focuses specifically on the polymerization of terpenes and terpenoids, which represent a source of promising monomers to create bio-based polymers and copolymers.
AbstractList Polymers are essential materials in our daily life. The synthesis of value-added polymers is mainly performed from fossil fuel-derived monomers. However, the adoption of the circular economy model based on the bioeconomy will reduce the dependence on fossil fuels. In this context, biorefineries have emerged to convert biomass into bioenergy and produce high value-added products, including molecules that can be further used as building blocks for the synthesis of biopolymers and bioplastics. The achievement of catalytic systems able to polymerize the natural monomer counterparts, such as terpenes or terpenoids, is still a challenge in the development of polymers with good mechanical, thermal, and chemical properties. This review describes the most common types of bioplastics and biopolymers and focuses specifically on the polymerization of terpenes and terpenoids, which represent a source of promising monomers to create bio-based polymers and copolymers.
Author Alonso, Rafael
Valera, Miguel Ángel
Monje, Belén
Acosta, Carolina
Mosquera, Marta. E. G.
García-Estrada, Carlos
Vinueza-Vaca, Joan
Sola-Landa, Alberto
Tabernero, Vanessa
Jiménez, Gerardo
Kosalková, Katarina
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Snippet Polymers are essential materials in our daily life. The synthesis of value-added polymers is mainly performed from fossil fuel-derived monomers. However, the...
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SubjectTerms bio-based polymers
Biodegradation
Biomass
Bioplastics
Biopolymers
Biorefineries
Carbohydrates
catalyst
Cellulose acetate
Chemical properties
Chemical synthesis
Circular economy
Climate change
Consumer goods
Copolymers
Environmental impact
Fatty acids
Fossil fuels
Glucose
Lignin
Lignocellulose
Microorganisms
Monomers
Plastics
Polyethylene terephthalate
Polylactic acid
Polymerization
Polymers
Polyvinyl alcohol
Proteins
REX
Terpenes
terpenoids
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Title Terpenes and Terpenoids: Building Blocks to Produce Biopolymers
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