Molecule-based electrorheological material with luminescence property
Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C 6 O 5 H 10 ) 7 , β-CD] inclusion compounds between β-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using β-CD, Tb(NO 3 ) 3 ,...
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| Published in | Korea-Australia rheology journal Vol. 25; no. 1; pp. 9 - 18 |
|---|---|
| Main Authors | , , , , |
| Format | Journal Article |
| Language | English Korean |
| Published |
Heidelberg
Korean Society of Rheology, Australian Society of Rheology
01.02.2013
한국유변학회 |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C
6
O
5
H
10
)
7
, β-CD] inclusion compounds between β-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using β-CD, Tb(NO
3
)
3
, Eu(NO
3
)
3
, sulphosalicylic acid (C
7
H
6
O
6
S·2H
2
O, SSA) and m-phthalic acid (C
8
H
6
O
4
, MPA) as original materials. The composition, ER performance, luminescence property and dielectric property of the materials have been studied. The results show that the rare earth complex in the cavity of β-CD may enhance the ER performance of β-CD, and the complex (Tb-SSA) of Tb
3+
can improve more effectively the ER activity of β-CD than that (Eu-MPA) of Eu
3+
among both of the complexes. The composition and structure are the dominant factors in improving the ER effect. The fluorescence intensity, fluorescence lifetime and emission quantum yield of the particle materials and their suspensions in silicone oil have been tested, and fine luminescence performance has been detected. The material with ER activity and luminescence performance is a novel multifunctional material which would have wide application prospect. |
|---|---|
| AbstractList | Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C
6
O
5
H
10
)
7
, β-CD] inclusion compounds between β-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using β-CD, Tb(NO
3
)
3
, Eu(NO
3
)
3
, sulphosalicylic acid (C
7
H
6
O
6
S·2H
2
O, SSA) and m-phthalic acid (C
8
H
6
O
4
, MPA) as original materials. The composition, ER performance, luminescence property and dielectric property of the materials have been studied. The results show that the rare earth complex in the cavity of β-CD may enhance the ER performance of β-CD, and the complex (Tb-SSA) of Tb
3+
can improve more effectively the ER activity of β-CD than that (Eu-MPA) of Eu
3+
among both of the complexes. The composition and structure are the dominant factors in improving the ER effect. The fluorescence intensity, fluorescence lifetime and emission quantum yield of the particle materials and their suspensions in silicone oil have been tested, and fine luminescence performance has been detected. The material with ER activity and luminescence performance is a novel multifunctional material which would have wide application prospect. Molecule-based electrorheological (ER) materials with luminescence property, based on ${\beta}$-cyclodextrin [($C_6O_5H_{10})_7$, ${\beta}$-CD] inclusion compounds between ${\beta}$-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using ${\beta}$-CD, $Tb(NO_3)_3$, $Eu(NO_3)_3$, sulphosalicylic acid ($C_7H_6O_6S{\cdot}2H_2O$, SSA) and m-phthalic acid ($C_8H_6O_4$, MPA) as original materials. The composition, ER performance, luminescence property and dielectric property of the materials have been studied. The results show that the rare earth complex in the cavity of ${\beta}$-CD may enhance the ER performance of ${\beta}$-CD, and the complex (Tb-SSA) of $Tb^{3+}$ can improve more effectively the ER activity of ${\beta}$-CD than that (Eu-MPA) of $Eu^{3+}$ among both of the complexes. The composition and structure are the dominant factors in improving the ER effect. The fluorescence intensity, fluorescence lifetime and emission quantum yield of the particle materials and their suspensions in silicone oil have been tested, and fine luminescence performance has been detected. The material with ER activity and luminescence performance is a novel multifunctional material which would have wide application prospect. Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C6O5H10)7, β-CD] inclusion compounds between β-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using β-CD, Tb(NO3)3, Eu(NO3)3, sulphosalicylic acid (C7H6O6S·2H2O, SSA) and m-phthalic acid (C8H6O4, MPA) as original materials. The composition, ER performance, luminescence property and dielectric property of the materials have been studied. The results show that the rare earth complex in the cavity of β-CD may enhance the ER performance of β-CD, and the complex (Tb-SSA) of Tb3+ can improve more effectively the ER activity of β-CD than that (Eu-MPA) of Eu3+ among both of the complexes. The composition and structure are the dominant factors in improving the ER effect. The fluorescence intensity, fluorescence lifetime and emission quantum yield of the particle materials and their suspensions in silicone oil have been tested, and fine luminescence performance has been detected. The material with ER activity and luminescence performance is a novel multifunctional material which would have wide application prospect. KCI Citation Count: 3 |
| Author | Jia, Yun-Ling Li, Jun-Ran Liao, Fu-Hui Shang, Yan-Li Chen, Ming-Xing |
| Author_xml | – sequence: 1 givenname: Ming-Xing surname: Chen fullname: Chen, Ming-Xing organization: College of Chemistry and Molecular Engineering, Peking University – sequence: 2 givenname: Fu-Hui surname: Liao fullname: Liao, Fu-Hui organization: College of Chemistry and Molecular Engineering, Peking University – sequence: 3 givenname: Yan-Li surname: Shang fullname: Shang, Yan-Li organization: College of Chemistry and Environmental Science, Hebei University – sequence: 4 givenname: Yun-Ling surname: Jia fullname: Jia, Yun-Ling organization: College of Chemistry and Molecular Engineering, Peking University – sequence: 5 givenname: Jun-Ran surname: Li fullname: Li, Jun-Ran email: lijunran@pku.edu.cn organization: College of Chemistry and Molecular Engineering, Peking University |
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| CitedBy_id | crossref_primary_10_1016_S1002_0721_14_60177_0 crossref_primary_10_1016_j_compscitech_2014_05_036 crossref_primary_10_1007_s13367_017_0004_4 |
| Cites_doi | 10.1016/j.jallcom.2008.11.087 10.1039/c1jm12443a 10.1016/j.colsurfa.2011.11.020 10.1002/1521-4095(200112)13:24<1847::AID-ADMA1847>3.0.CO;2-A 10.1002/app.26333 10.1016/S0032-3861(00)00887-9 10.1063/1.1698285 10.1016/S0001-8686(01)00045-8 10.1007/978-94-011-4505-3 10.1021/la026969d 10.1177/1045389X9300400215 10.1021/la971062e 10.1021/la035051z 10.1088/0022-3727/21/12/001 10.1016/j.physa.2005.01.033 10.1007/978-94-015-8575-0 10.1016/j.polymer.2007.09.013 10.1155/2009/275398 10.1039/b818368f |
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| Copyright | Korean Society of Rheology (KSR) and the Australian Society of Rheology (ASR) and Springer-Verlag Berlin Heidelberg 2013 |
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| Keywords | rare earth complex luminescence property electrorheological property β-cyclodextrin inclusion compound {\beta}$-cyclodextrin inclusion compound |
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Compd. year: 1986 ident: 2_CR18 contributor: fullname: K Nakamoto – volume: 20 start-page: 1137 issue: 12 year: 1949 ident: 2_CR1 publication-title: Journal of Applied Physics doi: 10.1063/1.1698285 contributor: fullname: WM Winslow – volume: 394 start-page: 33 year: 2012 ident: 2_CR13 publication-title: Colloids and Surfaces A: Physicochemical and Engineering Aspects doi: 10.1016/j.colsurfa.2011.11.020 contributor: fullname: FH Liao – volume: 4 start-page: 248 year: 1993 ident: 2_CR3 publication-title: Journal of Intelligent Material Systems and Structures doi: 10.1177/1045389X9300400215 contributor: fullname: JP Coulter – volume: 14 start-page: 1256 issue: 5 year: 1998 ident: 2_CR20 publication-title: Langmuir doi: 10.1021/la971062e contributor: fullname: T Hao – volume-title: Infrared Absorpt. Spectrosc. year: 1977 ident: 2_CR17 contributor: fullname: K Nakanishi – volume: 21 start-page: 17396 year: 2011 ident: 2_CR22 publication-title: J. Mater. Chem. doi: 10.1039/c1jm12443a contributor: fullname: YD Liu – volume: 20 start-page: 202 year: 2004 ident: 2_CR7 publication-title: Langmuir doi: 10.1021/la035051z contributor: fullname: MS Cho – volume: 21 start-page: 1661 year: 1988 ident: 2_CR2 publication-title: Journal of Physics D: Applied Physics doi: 10.1088/0022-3727/21/12/001 contributor: fullname: H Block – volume: 5 start-page: 1562 issue: 8 year: 2009 ident: 2_CR21 publication-title: Soft Matter. doi: 10.1039/b818368f contributor: fullname: HJ Choi – volume: 25 start-page: 24 issue: Suppl.1 year: 2007 ident: 2_CR11 publication-title: Journal of Rare Earths contributor: fullname: YL Jia – volume: 105 start-page: 2427 issue: 4 year: 2007 ident: 2_CR25 publication-title: J. Appl. Polym. Sci. doi: 10.1002/app.26333 contributor: fullname: Y Ma – start-page: 363 volume-title: Rare Earth Coordination Chem. year: 1997 ident: 2_CR15 contributor: fullname: CH Huang – volume-title: Molecular Engineering for Advanced Materials year: 1995 ident: 2_CR8 doi: 10.1007/978-94-015-8575-0 contributor: fullname: J Becher – volume: 353 start-page: 21 year: 2005 ident: 2_CR26 publication-title: Physica A-Statistical Mechanics and its Applications doi: 10.1016/j.physa.2005.01.033 contributor: fullname: V Pavlinek – volume: 97 start-page: 1 issue: 1–3 year: 2002 ident: 2_CR6 publication-title: Advances in Colloid and Interface Science doi: 10.1016/S0001-8686(01)00045-8 contributor: fullname: T Hao – volume: 478 start-page: 538 issue: 1–2 year: 2009 ident: 2_CR14 publication-title: Journal of Alloys and Compounds doi: 10.1016/j.jallcom.2008.11.087 contributor: fullname: YL Jia – volume: 19 start-page: 5875 year: 2003 ident: 2_CR24 publication-title: Langmuir doi: 10.1021/la026969d contributor: fullname: MS Cho – ident: 2_CR4 – volume-title: Crystal Engineering: From Molecules and Crystals to Materials year: 1999 ident: 2_CR9 doi: 10.1007/978-94-011-4505-3 contributor: fullname: D Braga – volume: 22 start-page: 43 issue: 1 year: 2010 ident: 2_CR12 publication-title: Korea-Australia Rheology Journal contributor: fullname: YL Shang – volume: 23 start-page: 51 issue: 1 year: 2009 ident: 2_CR16 publication-title: Spectroscopy-an International Journal doi: 10.1155/2009/275398 contributor: fullname: I Bratu – volume: 25 start-page: 9 issue: Suppl.1 year: 2007 ident: 2_CR10 publication-title: Journal of Rare Earths contributor: fullname: YL Jia – volume: 48 start-page: 6622 year: 2007 ident: 2_CR19 publication-title: Polymer doi: 10.1016/j.polymer.2007.09.013 contributor: fullname: SG Kim – volume: 42 start-page: 5005 year: 2001 ident: 2_CR23 publication-title: Polymer doi: 10.1016/S0032-3861(00)00887-9 contributor: fullname: SG Kim – volume: 13 start-page: 1847 issue: 24 year: 2001 ident: 2_CR5 publication-title: Advanced Materials doi: 10.1002/1521-4095(200112)13:24<1847::AID-ADMA1847>3.0.CO;2-A contributor: fullname: T Hao |
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| Snippet | Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C
6
O
5
H
10
)
7
, β-CD] inclusion compounds between... Molecule-based electrorheological (ER) materials with luminescence property, based on ${\beta}$-cyclodextrin [($C_6O_5H_{10})_7$, ${\beta}$-CD] inclusion... Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C6O5H10)7, β-CD] inclusion compounds between β-CD (host)... |
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| SubjectTerms | Characterization and Evaluation of Materials Chemistry and Materials Science Complex Fluids and Microfluidics Food Science Materials Science Mechanical Engineering Polymer Sciences Soft and Granular Matter 공학일반 |
| Title | Molecule-based electrorheological material with luminescence property |
| URI | https://link.springer.com/article/10.1007/s13367-013-0002-0 http://click.ndsl.kr/servlet/LinkingDetailView?cn=JAKO201309938855493&dbt=JAKO&org_code=O481&site_code=SS1481&service_code=01 https://www.kci.go.kr/kciportal/ci/sereArticleSearch/ciSereArtiView.kci?sereArticleSearchBean.artiId=ART001742938 |
| Volume | 25 |
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| ispartofPNX | The Korea-Australia Rheology Journal, 2013, 25(1), , pp.9-18 |
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