Molecule-based electrorheological material with luminescence property

Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C 6 O 5 H 10 ) 7 , β-CD] inclusion compounds between β-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using β-CD, Tb(NO 3 ) 3 ,...

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Published inKorea-Australia rheology journal Vol. 25; no. 1; pp. 9 - 18
Main Authors Chen, Ming-Xing, Liao, Fu-Hui, Shang, Yan-Li, Jia, Yun-Ling, Li, Jun-Ran
Format Journal Article
LanguageEnglish
Korean
Published Heidelberg Korean Society of Rheology, Australian Society of Rheology 01.02.2013
한국유변학회
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Abstract Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C 6 O 5 H 10 ) 7 , β-CD] inclusion compounds between β-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using β-CD, Tb(NO 3 ) 3 , Eu(NO 3 ) 3 , sulphosalicylic acid (C 7 H 6 O 6 S·2H 2 O, SSA) and m-phthalic acid (C 8 H 6 O 4 , MPA) as original materials. The composition, ER performance, luminescence property and dielectric property of the materials have been studied. The results show that the rare earth complex in the cavity of β-CD may enhance the ER performance of β-CD, and the complex (Tb-SSA) of Tb 3+ can improve more effectively the ER activity of β-CD than that (Eu-MPA) of Eu 3+ among both of the complexes. The composition and structure are the dominant factors in improving the ER effect. The fluorescence intensity, fluorescence lifetime and emission quantum yield of the particle materials and their suspensions in silicone oil have been tested, and fine luminescence performance has been detected. The material with ER activity and luminescence performance is a novel multifunctional material which would have wide application prospect.
AbstractList Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C 6 O 5 H 10 ) 7 , β-CD] inclusion compounds between β-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using β-CD, Tb(NO 3 ) 3 , Eu(NO 3 ) 3 , sulphosalicylic acid (C 7 H 6 O 6 S·2H 2 O, SSA) and m-phthalic acid (C 8 H 6 O 4 , MPA) as original materials. The composition, ER performance, luminescence property and dielectric property of the materials have been studied. The results show that the rare earth complex in the cavity of β-CD may enhance the ER performance of β-CD, and the complex (Tb-SSA) of Tb 3+ can improve more effectively the ER activity of β-CD than that (Eu-MPA) of Eu 3+ among both of the complexes. The composition and structure are the dominant factors in improving the ER effect. The fluorescence intensity, fluorescence lifetime and emission quantum yield of the particle materials and their suspensions in silicone oil have been tested, and fine luminescence performance has been detected. The material with ER activity and luminescence performance is a novel multifunctional material which would have wide application prospect.
Molecule-based electrorheological (ER) materials with luminescence property, based on ${\beta}$-cyclodextrin [($C_6O_5H_{10})_7$, ${\beta}$-CD] inclusion compounds between ${\beta}$-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using ${\beta}$-CD, $Tb(NO_3)_3$, $Eu(NO_3)_3$, sulphosalicylic acid ($C_7H_6O_6S{\cdot}2H_2O$, SSA) and m-phthalic acid ($C_8H_6O_4$, MPA) as original materials. The composition, ER performance, luminescence property and dielectric property of the materials have been studied. The results show that the rare earth complex in the cavity of ${\beta}$-CD may enhance the ER performance of ${\beta}$-CD, and the complex (Tb-SSA) of $Tb^{3+}$ can improve more effectively the ER activity of ${\beta}$-CD than that (Eu-MPA) of $Eu^{3+}$ among both of the complexes. The composition and structure are the dominant factors in improving the ER effect. The fluorescence intensity, fluorescence lifetime and emission quantum yield of the particle materials and their suspensions in silicone oil have been tested, and fine luminescence performance has been detected. The material with ER activity and luminescence performance is a novel multifunctional material which would have wide application prospect.
Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C6O5H10)7, β-CD] inclusion compounds between β-CD (host) and the rare earth (RE) (RE=Tb, Eu) complex (guest), have been synthesized as a novel type of ER materials using β-CD, Tb(NO3)3, Eu(NO3)3, sulphosalicylic acid (C7H6O6S·2H2O, SSA) and m-phthalic acid (C8H6O4, MPA) as original materials. The composition, ER performance, luminescence property and dielectric property of the materials have been studied. The results show that the rare earth complex in the cavity of β-CD may enhance the ER performance of β-CD, and the complex (Tb-SSA) of Tb3+ can improve more effectively the ER activity of β-CD than that (Eu-MPA) of Eu3+ among both of the complexes. The composition and structure are the dominant factors in improving the ER effect. The fluorescence intensity, fluorescence lifetime and emission quantum yield of the particle materials and their suspensions in silicone oil have been tested, and fine luminescence performance has been detected. The material with ER activity and luminescence performance is a novel multifunctional material which would have wide application prospect. KCI Citation Count: 3
Author Jia, Yun-Ling
Li, Jun-Ran
Liao, Fu-Hui
Shang, Yan-Li
Chen, Ming-Xing
Author_xml – sequence: 1
  givenname: Ming-Xing
  surname: Chen
  fullname: Chen, Ming-Xing
  organization: College of Chemistry and Molecular Engineering, Peking University
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  givenname: Fu-Hui
  surname: Liao
  fullname: Liao, Fu-Hui
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  givenname: Yan-Li
  surname: Shang
  fullname: Shang, Yan-Li
  organization: College of Chemistry and Environmental Science, Hebei University
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  givenname: Yun-Ling
  surname: Jia
  fullname: Jia, Yun-Ling
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  givenname: Jun-Ran
  surname: Li
  fullname: Li, Jun-Ran
  email: lijunran@pku.edu.cn
  organization: College of Chemistry and Molecular Engineering, Peking University
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CitedBy_id crossref_primary_10_1016_S1002_0721_14_60177_0
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crossref_primary_10_1007_s13367_017_0004_4
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Issue 1
Keywords rare earth complex
luminescence property
electrorheological property
β-cyclodextrin inclusion compound
{\beta}$-cyclodextrin inclusion compound
Language English
Korean
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PublicationTitle Korea-Australia rheology journal
PublicationTitleAbbrev Korea-Aust. Rheol. J
PublicationTitleAlternate Korea-Australia rheology journal
PublicationYear 2013
Publisher Korean Society of Rheology, Australian Society of Rheology
한국유변학회
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Snippet Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C 6 O 5 H 10 ) 7 , β-CD] inclusion compounds between...
Molecule-based electrorheological (ER) materials with luminescence property, based on ${\beta}$-cyclodextrin [($C_6O_5H_{10})_7$, ${\beta}$-CD] inclusion...
Molecule-based electrorheological (ER) materials with luminescence property, based on β-cyclodextrin [(C6O5H10)7, β-CD] inclusion compounds between β-CD (host)...
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SubjectTerms Characterization and Evaluation of Materials
Chemistry and Materials Science
Complex Fluids and Microfluidics
Food Science
Materials Science
Mechanical Engineering
Polymer Sciences
Soft and Granular Matter
공학일반
Title Molecule-based electrorheological material with luminescence property
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