Dynamic light scattering of iota carrageenan gelling system

The sol–gel transition of iota carrageenan, a thermoreversible polysaccharide gelling system, was investigated using the dynamic light scattering technique as a function of concentration and temperature, and the results were compared with the earlier viscoelastic results on the same system. At highe...

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Published inJournal of non-crystalline solids Vol. 235; pp. 682 - 687
Main Authors Hossain, Khandker S., Nemoto, Norio
Format Journal Article
LanguageEnglish
Published Elsevier B.V 01.08.1998
Subjects
L130
G120
S310
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Abstract The sol–gel transition of iota carrageenan, a thermoreversible polysaccharide gelling system, was investigated using the dynamic light scattering technique as a function of concentration and temperature, and the results were compared with the earlier viscoelastic results on the same system. At higher temperatures where the system behaved as a viscous fluid, the field correlation function g (1)( t) is described by a stretched exponential type of decay in the long time region. As temperature decreases, the time profile of g (1)( t) changed, and finally at temperature, T d, it took the form of a power law type of decay, being a measure of the sol–gel transition point. T d was observed to be comparatively less than T c, the temperature at which the power law relaxation was observed in the dynamic viscoelastic (DVE) study.
AbstractList The sol–gel transition of iota carrageenan, a thermoreversible polysaccharide gelling system, was investigated using the dynamic light scattering technique as a function of concentration and temperature, and the results were compared with the earlier viscoelastic results on the same system. At higher temperatures where the system behaved as a viscous fluid, the field correlation function g (1)( t) is described by a stretched exponential type of decay in the long time region. As temperature decreases, the time profile of g (1)( t) changed, and finally at temperature, T d, it took the form of a power law type of decay, being a measure of the sol–gel transition point. T d was observed to be comparatively less than T c, the temperature at which the power law relaxation was observed in the dynamic viscoelastic (DVE) study.
Author Nemoto, Norio
Hossain, Khandker S.
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CitedBy_id crossref_primary_10_1021_bm000117f
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Cites_doi 10.1103/PhysRevLett.61.373
10.1007/BF00263470
10.1016/S0144-8617(96)00074-4
10.1016/0022-2836(69)90211-3
10.1021/ma00003a028
10.1122/1.549853
10.1103/PhysRevA.45.2416
10.1016/0022-2836(80)90291-0
10.1678/rheology1973.25.3_135
10.1103/PhysRevLett.61.706
10.1021/ma00028a082
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