Abnormal electrochemical behavior of rounded graphite

Round-shaped natural graphite is commonly used as anode material for rechargeable lithium-ion batteries. We report atypical electrochemical behavior of round-shaped graphite anodes in Li-ion batteries: an intriguing phenomenon whereby substantial progressive increase in capacity is observed over ten...

Full description

Saved in:
Bibliographic Details
Published inCarbon (New York) Vol. 154; pp. 313 - 321
Main Authors Lavi, Ortal, Haik, Ortal, Hirshberg, Daniel, Talyosef, Yosef, Zinigard, Ella, Markovsky, Boris, Vestfrid, Yulia, Elias, Yuval, Aurbach, Doron, Kovacheva, Daniela
Format Journal Article
LanguageEnglish
Published New York Elsevier Ltd 01.12.2019
Elsevier BV
Subjects
Anodes
Batteries
Electrochemical analysis
Electrode materials
Exfoliation
Fracture toughness
Graphene
Graphite
Lithium
Lithium-ion batteries
Raman spectroscopy
Rechargeable batteries
Spectrum analysis
Online AccessGet full text

Cover

Abstract Round-shaped natural graphite is commonly used as anode material for rechargeable lithium-ion batteries. We report atypical electrochemical behavior of round-shaped graphite anodes in Li-ion batteries: an intriguing phenomenon whereby substantial progressive increase in capacity is observed over tens of cycles. To understand the reasons underlying this abnormal behavior, we investigated the surface and bulk structure properties using HRSEM, XRD and Raman spectroscopy. Graphite particles with tense structure undergo exfoliation and fracture due to multiple transformations in intercalation/deintercalation processes. The increased capacity may result from enhanced particle exfoliation, compared with non-rounded graphite, which is accompanied by appearance of graphene sheets and fracture. [Display omitted]
AbstractList Round-shaped natural graphite is commonly used as anode material for rechargeable lithium-ion batteries. We report atypical electrochemical behavior of round-shaped graphite anodes in Li-ion batteries: an intriguing phenomenon whereby substantial progressive increase in capacity is observed over tens of cycles. To understand the reasons underlying this abnormal behavior, we investigated the surface and bulk structure properties using HRSEM, XRD and Raman spectroscopy. Graphite particles with tense structure undergo exfoliation and fracture due to multiple transformations in intercalation/deintercalation processes. The increased capacity may result from enhanced particle exfoliation, compared with non-rounded graphite, which is accompanied by appearance of graphene sheets and fracture. [Display omitted]
Round-shaped natural graphite is commonly used as anode material for rechargeable lithium-ion batteries. We report atypical electrochemical behavior of round-shaped graphite anodes in Li-ion batteries: an intriguing phenomenon whereby substantial progressive increase in capacity is observed over tens of cycles. To understand the reasons underlying this abnormal behavior, we investigated the surface and bulk structure properties using HRSEM, XRD and Raman spectroscopy. Graphite particles with tense structure undergo exfoliation and fracture due to multiple transformations in intercalation/deintercalation processes. The increased capacity may result from enhanced particle exfoliation, compared with non-rounded graphite, which is accompanied by appearance of graphene sheets and fracture.
Author Hirshberg, Daniel
Elias, Yuval
Talyosef, Yosef
Zinigard, Ella
Lavi, Ortal
Markovsky, Boris
Vestfrid, Yulia
Haik, Ortal
Kovacheva, Daniela
Aurbach, Doron
Author_xml – sequence: 1
  givenname: Ortal
  surname: Lavi
  fullname: Lavi, Ortal
  email: ortal.yariv@biu.ac.il
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 2
  givenname: Ortal
  surname: Haik
  fullname: Haik, Ortal
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 3
  givenname: Daniel
  surname: Hirshberg
  fullname: Hirshberg, Daniel
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 4
  givenname: Yosef
  surname: Talyosef
  fullname: Talyosef, Yosef
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 5
  givenname: Ella
  surname: Zinigard
  fullname: Zinigard, Ella
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 6
  givenname: Boris
  surname: Markovsky
  fullname: Markovsky, Boris
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 7
  givenname: Yulia
  surname: Vestfrid
  fullname: Vestfrid, Yulia
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 8
  givenname: Yuval
  surname: Elias
  fullname: Elias, Yuval
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 9
  givenname: Doron
  surname: Aurbach
  fullname: Aurbach, Doron
  organization: Bar-Ilan Institute for Nanotechnology and Advanced Materials and Department of Chemistry, Bar-Ilan University, Ramat-Gan, 5290002, Israel
– sequence: 10
  givenname: Daniela
  surname: Kovacheva
  fullname: Kovacheva, Daniela
  organization: Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia, 1113, Bulgaria
BookMark eNp9kEFPwzAMhSM0JLbBP-BQiXOL3TRNekGaJhhIk7jAOWpTl6XampF0k_j3ZCpnTral957tb8FmgxuIsXuEDAHLxz4ztW_ckOWAVQYyAwVXbI5K8pSrCmdsDgAqLfOc37BFCH0cC4XFnIlVMzh_qPcJ7cmM3pkdHayJc0O7-mydT1yXeHcaWmqTL18fd3akW3bd1ftAd391yT5fnj_Wr-n2ffO2Xm1TwyUfU6FAcYQCW0FdGZvclNR0JFSBMueNNKqKhzQlcpANgsxLyY2gChVKXkm-ZA9T7tG77xOFUffu5Ie4UuccBQjOhYqqYlIZ70Lw1Omjt4fa_2gEfQGkez0B0hdAGqSOgKLtabJR_OBsyetgLA2GWusjCt06-3_AL0Emb7E
CitedBy_id crossref_primary_10_1021_acsomega_0c01270
Cites_doi 10.2113/gselements.6.1.19
10.1098/rspa.1942.0063
10.1021/jp962815t
10.1016/j.electacta.2004.06.006
10.1021/nl300901a
10.1103/PhysRevB.26.5867
10.1016/j.elecom.2009.07.019
10.1016/S0378-7753(99)00288-8
10.1149/1.3294774
10.1016/S0008-6223(98)00290-5
10.1016/j.electacta.2007.03.052
10.1016/S0379-6779(98)00141-6
10.1103/PhysRevB.84.035433
10.1149/1.2054777
10.1016/j.jnucmat.2013.08.053
10.1016/j.radphyschem.2015.02.007
10.1002/pc.10229
10.1021/jp9701909
10.1038/258136a0
10.1016/S0378-7753(03)00116-2
10.1002/jrs.4475
10.1149/1.2048659
10.1016/S0378-7753(03)00603-7
10.1016/j.jpowsour.2005.03.107
10.1149/1.1837300
10.1155/2014/549019
10.1016/0001-6160(53)90006-6
10.1098/rsta.2004.1442
10.1016/0013-4686(95)00163-9
10.1016/0167-2738(96)00352-9
10.1351/pac199567030473
10.1016/0013-4686(94)00221-5
10.1557/JMR.1990.1271
ContentType Journal Article
Copyright 2019
Copyright Elsevier BV Dec 2019
Copyright_xml – notice: 2019
– notice: Copyright Elsevier BV Dec 2019
DBID AAYXX
CITATION
7SR
8FD
JG9
DOI 10.1016/j.carbon.2019.07.080
DatabaseName CrossRef
Engineered Materials Abstracts
Technology Research Database
Materials Research Database
DatabaseTitle CrossRef
Materials Research Database
Technology Research Database
Engineered Materials Abstracts
DatabaseTitleList
Materials Research Database
DeliveryMethod fulltext_linktorsrc
Discipline Chemistry
EISSN 1873-3891
EndPage 321
ExternalDocumentID 10_1016_j_carbon_2019_07_080
S0008622319307730
GroupedDBID --K
--M
-~X
.~1
0R~
1B1
1~.
1~5
29B
4.4
457
4G.
5GY
5VS
7-5
71M
8P~
9JN
AABNK
AABXZ
AACTN
AAEDT
AAEDW
AAEPC
AAHCO
AAIAV
AAIKJ
AAKOC
AALRI
AAOAW
AAQFI
AAQXK
AARJD
AAXUO
ABFNM
ABMAC
ABXDB
ABXRA
ABYKQ
ACDAQ
ACGFS
ACIWK
ACNNM
ACRLP
ADBBV
ADEZE
ADMUD
AEBSH
AEKER
AENEX
AEZYN
AFKWA
AFRZQ
AFTJW
AGHFR
AGUBO
AGYEJ
AHHHB
AHIDL
AIEXJ
AIKHN
AITUG
AJBFU
AJOXV
ALMA_UNASSIGNED_HOLDINGS
AMFUW
AMRAJ
ASPBG
AVWKF
AXJTR
AZFZN
BELTK
BKOJK
BLXMC
CS3
DU5
EBS
EFJIC
EFLBG
EJD
EO8
EO9
EP2
EP3
F5P
FDB
FEDTE
FGOYB
FIRID
FNPLU
FYGXN
G-2
G-Q
GBLVA
HVGLF
HZ~
IHE
J1W
JARJE
KOM
M24
M41
MAGPM
MO0
N9A
O-L
O9-
OAUVE
OZT
P-8
P-9
P2P
PC.
Q38
R2-
RIG
RNS
ROL
RPZ
SDF
SDG
SDP
SES
SEW
SMS
SPC
SPCBC
SSM
SSR
SSZ
T5K
TWZ
WUQ
XPP
ZMT
~02
~G-
AAHBH
AAXKI
AAYXX
AKRWK
CITATION
7SR
8FD
JG9
ID FETCH-LOGICAL-c373t-580831041d5ef61042c6ebfe5841723b7c89004b61307b1072673c5e918173973
IEDL.DBID .~1
ISSN 0008-6223
IngestDate Fri Sep 13 00:11:53 EDT 2024
Thu Sep 12 17:45:05 EDT 2024
Fri Feb 23 02:32:48 EST 2024
IsPeerReviewed true
IsScholarly true
Language English
LinkModel DirectLink
MergedId FETCHMERGED-LOGICAL-c373t-580831041d5ef61042c6ebfe5841723b7c89004b61307b1072673c5e918173973
PQID 2315053358
PQPubID 2045273
PageCount 9
ParticipantIDs proquest_journals_2315053358
crossref_primary_10_1016_j_carbon_2019_07_080
elsevier_sciencedirect_doi_10_1016_j_carbon_2019_07_080
PublicationCentury 2000
PublicationDate 2019-12-01
PublicationDateYYYYMMDD 2019-12-01
PublicationDate_xml – month: 12
  year: 2019
  text: 2019-12-01
  day: 01
PublicationDecade 2010
PublicationPlace New York
PublicationPlace_xml – name: New York
PublicationTitle Carbon (New York)
PublicationYear 2019
Publisher Elsevier Ltd
Elsevier BV
Publisher_xml – name: Elsevier Ltd
– name: Elsevier BV
References Williamson, Hall (bib22) 1953; 1
Focke, Radusch (bib15) 2014; vol. 2
Badenhorst, Focke (bib14) 2013; 442
Venezuela, Lazzeri, Mauri (bib29) 2011; 84
Gottlieb, Amalraj, Aurbach, Martha, Markovsky, Gofer (bib8) 2010; 157
Herstedt, Fransson, Börjesson, Edström (bib23) 2001
Markervich, Salitra, Levi, Aurbach (bib24) 2005; 146
Julien, Pereira-Ramos, Momchilov (bib26) 2002
Herstedt, Andersson, Rensmo, Siegbahn, Edström (bib16) 2004; 49
Zaghib, Song, Guerfi, Rioux, Kinoshita (bib18) 2003; 119–121
Chieu, Dresselhaus, Endo (bib34) 1982; 26
Del Corro, Taravillo, Baonza (bib31) 2014; 45
Wang, Ikeda, Fukuda, Yoshio (bib13) 1999; 83
Endo, Kim, Karaki, Fujino, Matthews, Brown, Dresslhaus (bib28) 1998; 98
Trucano, Chen (bib36) 1975; 258
Flandrois, Simon (bib2) 1999; 37
Yoshida, Kaburagi, Hishiyama (bib35) 2007; vols. 1–7
Aurbach, Levi, Levi, Schechter (bib5) 2002; 101
Steinrötter (bib11) 2011
Eckmann, Felten, Mishchenko, Britnell, Krupke, Novoselov (bib30) 2012; 12
Fitzer, Kochling, Boehm, Marsh (bib39) 1995; 67
Menkin, Golodnitsky, Peled (bib4) 2009; 11
Li, Lu, Huang, Wang, Huang, Xue, Chen (bib25) 1996; 89
Thomas, Vattappalam, Mathew, Augustine (bib20) 2014; 2014
Tan, Dimovski, Gogotsi (bib33) 2004; 362
Levi, Aurbach (bib12) 2002; 101
Aurbach, Markovsky, Schechter, Ein-Eli, Cohen (bib6) 1996; 143
Aurbach (bib7) 1995; 142
Armand (bib1) 1980
Peled, Golodnitsky, Ardel, Eshkenazy (bib3) 1995; 40
Ein-Eli, Markovsky, Aurbach, Carmeli, Yamin, Luski (bib10) 1994; 39
Krishna, Jones, Edge, Marsden (bib32) 2015; 111
Herstedt, Fransson, Edström (bib17) 2003; 124
McCoy (bib38) 2010; 6
Lipson, Stokes (bib37) 1942; 181
Aurbach (bib9) 2006; 141
Ko, Kuo, Chang (bib27) 2000; 21
Takamura, Endo, Fu, Wu, Lee, Matsumoto (bib19) 2007; 53
Hamada, Furuyama, Sajiki, Tomioka, Endo (bib21) 1990; 5
Ko (10.1016/j.carbon.2019.07.080_bib27) 2000; 21
Chieu (10.1016/j.carbon.2019.07.080_bib34) 1982; 26
Lipson (10.1016/j.carbon.2019.07.080_bib37) 1942; 181
Badenhorst (10.1016/j.carbon.2019.07.080_bib14) 2013; 442
Eckmann (10.1016/j.carbon.2019.07.080_bib30) 2012; 12
Aurbach (10.1016/j.carbon.2019.07.080_bib5) 2002; 101
Herstedt (10.1016/j.carbon.2019.07.080_bib17) 2003; 124
Williamson (10.1016/j.carbon.2019.07.080_bib22) 1953; 1
Hamada (10.1016/j.carbon.2019.07.080_bib21) 1990; 5
Tan (10.1016/j.carbon.2019.07.080_bib33) 2004; 362
Aurbach (10.1016/j.carbon.2019.07.080_bib6) 1996; 143
Aurbach (10.1016/j.carbon.2019.07.080_bib7) 1995; 142
Herstedt (10.1016/j.carbon.2019.07.080_bib16) 2004; 49
Krishna (10.1016/j.carbon.2019.07.080_bib32) 2015; 111
Trucano (10.1016/j.carbon.2019.07.080_bib36) 1975; 258
Focke (10.1016/j.carbon.2019.07.080_bib15) 2014; vol. 2
Endo (10.1016/j.carbon.2019.07.080_bib28) 1998; 98
Takamura (10.1016/j.carbon.2019.07.080_bib19) 2007; 53
Yoshida (10.1016/j.carbon.2019.07.080_bib35) 2007; vols. 1–7
McCoy (10.1016/j.carbon.2019.07.080_bib38) 2010; 6
Peled (10.1016/j.carbon.2019.07.080_bib3) 1995; 40
Gottlieb (10.1016/j.carbon.2019.07.080_bib8) 2010; 157
Wang (10.1016/j.carbon.2019.07.080_bib13) 1999; 83
Thomas (10.1016/j.carbon.2019.07.080_bib20) 2014; 2014
Julien (10.1016/j.carbon.2019.07.080_bib26) 2002
Steinrötter (10.1016/j.carbon.2019.07.080_bib11) 2011
Venezuela (10.1016/j.carbon.2019.07.080_bib29) 2011; 84
Markervich (10.1016/j.carbon.2019.07.080_bib24) 2005; 146
Flandrois (10.1016/j.carbon.2019.07.080_bib2) 1999; 37
Aurbach (10.1016/j.carbon.2019.07.080_bib9) 2006; 141
Fitzer (10.1016/j.carbon.2019.07.080_bib39) 1995; 67
Ein-Eli (10.1016/j.carbon.2019.07.080_bib10) 1994; 39
Levi (10.1016/j.carbon.2019.07.080_bib12) 2002; 101
Menkin (10.1016/j.carbon.2019.07.080_bib4) 2009; 11
Herstedt (10.1016/j.carbon.2019.07.080_bib23) 2001
Del Corro (10.1016/j.carbon.2019.07.080_bib31) 2014; 45
Armand (10.1016/j.carbon.2019.07.080_bib1) 1980
Li (10.1016/j.carbon.2019.07.080_bib25) 1996; 89
Zaghib (10.1016/j.carbon.2019.07.080_bib18) 2003; 119–121
References_xml – volume: 362
  start-page: 2289
  year: 2004
  end-page: 2310
  ident: bib33
  article-title: Raman scattering of non-planar graphite: arched edges, polyhedral crystals, whiskers and cones
  publication-title: Philos. Trans. R. Soc. A Math. Phys. Eng. Sci.
  contributor:
    fullname: Gogotsi
– volume: 442
  start-page: 75
  year: 2013
  end-page: 82
  ident: bib14
  article-title: Comparative analysis of graphite oxidation behaviour based on microstructure
  publication-title: J. Nucl. Mater.
  contributor:
    fullname: Focke
– volume: 124
  start-page: 191
  year: 2003
  end-page: 196
  ident: bib17
  article-title: Rate capability of natural Swedish graphite as anode material in Li-ion batteries
  publication-title: J. Power Sources
  contributor:
    fullname: Edström
– volume: 40
  start-page: 2197
  year: 1995
  end-page: 2204
  ident: bib3
  article-title: The sei model—application to lithium-polymer electrolyte batteries
  publication-title: Electrochim. Acta
  contributor:
    fullname: Eshkenazy
– volume: 67
  start-page: 473
  year: 1995
  end-page: 506
  ident: bib39
  article-title: Recommended terminology for the description of carbon as a solid (IUPAC Recommendations 1995)
  publication-title: Pure Appl. Chem.
  contributor:
    fullname: Marsh
– volume: 11
  start-page: 1789
  year: 2009
  end-page: 1791
  ident: bib4
  article-title: Artificial solid-electrolyte interphase (SEI) for improved cycleability and safety of lithium–ion cells for EV applications
  publication-title: Electrochem. Commun.
  contributor:
    fullname: Peled
– volume: 119–121
  start-page: 8
  year: 2003
  end-page: 15
  ident: bib18
  article-title: Purification process of natural graphite as anode for Li-ion batteries: chemical versus thermal
  publication-title: J. Power Sources
  contributor:
    fullname: Kinoshita
– volume: 21
  start-page: 745
  year: 2000
  end-page: 750
  ident: bib27
  article-title: Raman study of the microstructure changes of phenolic resin during pyrolysis
  publication-title: Polym. Compos.
  contributor:
    fullname: Chang
– start-page: 1
  year: 2001
  ident: bib23
  article-title: A high capacity natural Swedish graphite – the beneficial effect of jet-milling
  publication-title: Joint International Meeting–the 200th Meeting of The Electrochemical Society Inc. and the 52nd Annual Meeting of the International Society of Electrochemistry
  contributor:
    fullname: Edström
– volume: 84
  year: 2011
  ident: bib29
  article-title: Theory of double-resonant Raman spectra in graphene: intensity and line shape of defect-induced and two-phonon bands
  publication-title: Phys. Rev. B.
  contributor:
    fullname: Mauri
– start-page: 145
  year: 1980
  end-page: 161
  ident: bib1
  article-title: Intercalation electrodes
  publication-title: Materials for Advanced Batteries
  contributor:
    fullname: Armand
– volume: vol. 2
  year: 2014
  ident: bib15
  publication-title: Engineering of Polymers and Chemical Complexity: New Approaches, Limitations and Control
  contributor:
    fullname: Radusch
– volume: 101
  start-page: 4630
  year: 2002
  end-page: 4640
  ident: bib12
  article-title: Simultaneous measurements and modeling of the electrochemical impedance and the cyclic voltammetric characteristics of graphite electrodes doped with lithium
  publication-title: J. Phys. Chem. B
  contributor:
    fullname: Aurbach
– volume: 101
  start-page: 2195
  year: 2002
  end-page: 2206
  ident: bib5
  article-title: Failure and stabilization mechanisms of graphite electrodes
  publication-title: J. Phys. Chem. B
  contributor:
    fullname: Schechter
– volume: 157
  start-page: A423
  year: 2010
  end-page: A429
  ident: bib8
  article-title: On the electrochemical behavior of aluminum electrodes in nonaqueous electrolyte solutions of lithium salts
  publication-title: J. Electrochem. Soc.
  contributor:
    fullname: Gofer
– volume: 5
  start-page: 1271
  year: 1990
  end-page: 1280
  ident: bib21
  article-title: Preferred orientation of pitch precursor fibers
  publication-title: J. Mater. Res.
  contributor:
    fullname: Endo
– volume: 45
  start-page: 476
  year: 2014
  end-page: 480
  ident: bib31
  article-title: Stress-dependent correlations for resonant Raman bands in graphite with defects
  publication-title: J. Raman Spectrosc.
  contributor:
    fullname: Baonza
– volume: 53
  start-page: 1055
  year: 2007
  end-page: 1061
  ident: bib19
  article-title: Identification of nano-sized holes by TEM in the graphene layer of graphite and the high rate discharge capability of Li-ion battery anodes
  publication-title: Electrochim. Acta
  contributor:
    fullname: Matsumoto
– volume: 2014
  start-page: 549019
  year: 2014
  ident: bib20
  article-title: Appraisal on textured grain growth and photoconductivity of ZnO Thin Film SILAR
  publication-title: Adv. Chem.
  contributor:
    fullname: Augustine
– volume: 111
  start-page: 14
  year: 2015
  end-page: 23
  ident: bib32
  article-title: Residual stress measurements in polycrystalline graphite with micro-Raman spectroscopy
  publication-title: Radiat. Phys. Chem.
  contributor:
    fullname: Marsden
– volume: 83
  start-page: 141
  year: 1999
  end-page: 147
  ident: bib13
  article-title: Effect of milling on the electrochemical performance of natural graphite as an anode material for lithium-ion battery
  publication-title: J. Power Sources
  contributor:
    fullname: Yoshio
– volume: 258
  start-page: 136
  year: 1975
  end-page: 137
  ident: bib36
  article-title: Structure of graphite by neutron diffraction
  publication-title: Nature
  contributor:
    fullname: Chen
– volume: 141
  start-page: 603
  year: 2006
  end-page: 611
  ident: bib9
  article-title: The correlation between the surface chemistry and the performance of Li-Carbon intercalation anodes for rechargeable ‘rocking-chair’ type batteries
  publication-title: J. Electrochem. Soc.
  contributor:
    fullname: Aurbach
– volume: 98
  start-page: 17
  year: 1998
  end-page: 24
  ident: bib28
  article-title: In situ Raman study of PPP-based disordered carbon as an anode in a Li ion battery
  publication-title: Synth. Met.
  contributor:
    fullname: Dresslhaus
– volume: 142
  start-page: 2882
  year: 1995
  end-page: 2890
  ident: bib7
  article-title: The study of electrolyte solutions based on ethylene and diethyl carbonates for rechargeable Li batteries
  publication-title: J. Electrochem. Soc.
  contributor:
    fullname: Aurbach
– volume: 143
  start-page: 3809
  year: 1996
  end-page: 3820
  ident: bib6
  article-title: A comparative study of synthetic graphite and Li electrodes in electrolyte solutions based on ethylene carbonate-dimethyl carbonate mixtures
  publication-title: J. Electrochem. Soc.
  contributor:
    fullname: Cohen
– volume: 49
  start-page: 4939
  year: 2004
  end-page: 4947
  ident: bib16
  article-title: Characterisation of the SEI formed on natural graphite in PC-based electrolytes
  publication-title: Electrochim. Acta
  contributor:
    fullname: Edström
– volume: vols. 1–7
  year: 2007
  ident: bib35
  publication-title: Raman Spectra of Graphite Edge Planes ; Edge Planes of HOPG Prepared by Ar Ion Cutting and Kish Graphite Formed on its Crystal Grain
  contributor:
    fullname: Hishiyama
– year: 2002
  ident: bib26
  article-title: New Trends in Intercalation Compounds for Energy Storage NATO Science Series
  contributor:
    fullname: Momchilov
– volume: 39
  start-page: 2559
  year: 1994
  end-page: 2569
  ident: bib10
  article-title: The dependence of the performance of Li-C intercalation anodes for Li-ion secondary batteries on the electrolyte solution composition
  publication-title: Electrochim. Acta
  contributor:
    fullname: Luski
– volume: 37
  start-page: 165
  year: 1999
  end-page: 180
  ident: bib2
  article-title: Carbon materials for lithium-ion rechargeable batteries
  publication-title: Carbon
  contributor:
    fullname: Simon
– volume: 1
  start-page: 22
  year: 1953
  end-page: 31
  ident: bib22
  article-title: X-ray line broadening from filed aluminium and wolfram
  publication-title: Acta Metall.
  contributor:
    fullname: Hall
– volume: 12
  start-page: 3925
  year: 2012
  end-page: 3930
  ident: bib30
  article-title: Probing the nature of defects in graphene by Raman spectroscopy
  publication-title: Nano Lett.
  contributor:
    fullname: Novoselov
– volume: 6
  start-page: 19
  year: 2010
  end-page: 23
  ident: bib38
  article-title: Mineralogical evolution of meteorites
  publication-title: Elements
  contributor:
    fullname: McCoy
– start-page: 65
  year: 2011
  end-page: 75
  ident: bib11
  article-title: Carbon-based anodes - a “rare earth” situation?
  publication-title: BEST Winter
  contributor:
    fullname: Steinrötter
– volume: 146
  start-page: 146
  year: 2005
  end-page: 150
  ident: bib24
  article-title: Capacity fading of lithiated graphite electrodes studied by a combination of electroanalytical methods, Raman spectroscopy and SEM
  publication-title: J. Power Sources
  contributor:
    fullname: Aurbach
– volume: 26
  start-page: 5867
  year: 1982
  end-page: 5877
  ident: bib34
  article-title: Raman studies of benzene-derived graphite fibers
  publication-title: Phys. Rev. B
  contributor:
    fullname: Endo
– volume: 181
  start-page: 101
  year: 1942
  end-page: 105
  ident: bib37
  article-title: The structure of graphite
  publication-title: Proc. R. Soc. A Math. Phys. Eng. Sci.
  contributor:
    fullname: Stokes
– volume: 89
  start-page: 327
  year: 1996
  end-page: 331
  ident: bib25
  article-title: Raman scattering investigation of carbons obtained by heat treatment of a polyfurfuryl alcohol
  publication-title: Solid State Ion.
  contributor:
    fullname: Chen
– volume: 6
  start-page: 19
  year: 2010
  ident: 10.1016/j.carbon.2019.07.080_bib38
  article-title: Mineralogical evolution of meteorites
  publication-title: Elements
  doi: 10.2113/gselements.6.1.19
  contributor:
    fullname: McCoy
– volume: 181
  start-page: 101
  year: 1942
  ident: 10.1016/j.carbon.2019.07.080_bib37
  article-title: The structure of graphite
  publication-title: Proc. R. Soc. A Math. Phys. Eng. Sci.
  doi: 10.1098/rspa.1942.0063
  contributor:
    fullname: Lipson
– volume: 101
  start-page: 2195
  year: 2002
  ident: 10.1016/j.carbon.2019.07.080_bib5
  article-title: Failure and stabilization mechanisms of graphite electrodes
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp962815t
  contributor:
    fullname: Aurbach
– volume: 49
  start-page: 4939
  year: 2004
  ident: 10.1016/j.carbon.2019.07.080_bib16
  article-title: Characterisation of the SEI formed on natural graphite in PC-based electrolytes
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2004.06.006
  contributor:
    fullname: Herstedt
– volume: 12
  start-page: 3925
  year: 2012
  ident: 10.1016/j.carbon.2019.07.080_bib30
  article-title: Probing the nature of defects in graphene by Raman spectroscopy
  publication-title: Nano Lett.
  doi: 10.1021/nl300901a
  contributor:
    fullname: Eckmann
– volume: 26
  start-page: 5867
  year: 1982
  ident: 10.1016/j.carbon.2019.07.080_bib34
  article-title: Raman studies of benzene-derived graphite fibers
  publication-title: Phys. Rev. B
  doi: 10.1103/PhysRevB.26.5867
  contributor:
    fullname: Chieu
– volume: 11
  start-page: 1789
  year: 2009
  ident: 10.1016/j.carbon.2019.07.080_bib4
  article-title: Artificial solid-electrolyte interphase (SEI) for improved cycleability and safety of lithium–ion cells for EV applications
  publication-title: Electrochem. Commun.
  doi: 10.1016/j.elecom.2009.07.019
  contributor:
    fullname: Menkin
– volume: 83
  start-page: 141
  year: 1999
  ident: 10.1016/j.carbon.2019.07.080_bib13
  article-title: Effect of milling on the electrochemical performance of natural graphite as an anode material for lithium-ion battery
  publication-title: J. Power Sources
  doi: 10.1016/S0378-7753(99)00288-8
  contributor:
    fullname: Wang
– volume: 157
  start-page: A423
  year: 2010
  ident: 10.1016/j.carbon.2019.07.080_bib8
  article-title: On the electrochemical behavior of aluminum electrodes in nonaqueous electrolyte solutions of lithium salts
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1.3294774
  contributor:
    fullname: Gottlieb
– volume: 37
  start-page: 165
  year: 1999
  ident: 10.1016/j.carbon.2019.07.080_bib2
  article-title: Carbon materials for lithium-ion rechargeable batteries
  publication-title: Carbon
  doi: 10.1016/S0008-6223(98)00290-5
  contributor:
    fullname: Flandrois
– volume: 53
  start-page: 1055
  year: 2007
  ident: 10.1016/j.carbon.2019.07.080_bib19
  article-title: Identification of nano-sized holes by TEM in the graphene layer of graphite and the high rate discharge capability of Li-ion battery anodes
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2007.03.052
  contributor:
    fullname: Takamura
– volume: 98
  start-page: 17
  year: 1998
  ident: 10.1016/j.carbon.2019.07.080_bib28
  article-title: In situ Raman study of PPP-based disordered carbon as an anode in a Li ion battery
  publication-title: Synth. Met.
  doi: 10.1016/S0379-6779(98)00141-6
  contributor:
    fullname: Endo
– volume: 84
  year: 2011
  ident: 10.1016/j.carbon.2019.07.080_bib29
  article-title: Theory of double-resonant Raman spectra in graphene: intensity and line shape of defect-induced and two-phonon bands
  publication-title: Phys. Rev. B.
  doi: 10.1103/PhysRevB.84.035433
  contributor:
    fullname: Venezuela
– volume: 141
  start-page: 603
  year: 2006
  ident: 10.1016/j.carbon.2019.07.080_bib9
  article-title: The correlation between the surface chemistry and the performance of Li-Carbon intercalation anodes for rechargeable ‘rocking-chair’ type batteries
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1.2054777
  contributor:
    fullname: Aurbach
– volume: 442
  start-page: 75
  year: 2013
  ident: 10.1016/j.carbon.2019.07.080_bib14
  article-title: Comparative analysis of graphite oxidation behaviour based on microstructure
  publication-title: J. Nucl. Mater.
  doi: 10.1016/j.jnucmat.2013.08.053
  contributor:
    fullname: Badenhorst
– volume: 111
  start-page: 14
  year: 2015
  ident: 10.1016/j.carbon.2019.07.080_bib32
  article-title: Residual stress measurements in polycrystalline graphite with micro-Raman spectroscopy
  publication-title: Radiat. Phys. Chem.
  doi: 10.1016/j.radphyschem.2015.02.007
  contributor:
    fullname: Krishna
– volume: vols. 1–7
  year: 2007
  ident: 10.1016/j.carbon.2019.07.080_bib35
  contributor:
    fullname: Yoshida
– year: 2002
  ident: 10.1016/j.carbon.2019.07.080_bib26
  contributor:
    fullname: Julien
– start-page: 145
  year: 1980
  ident: 10.1016/j.carbon.2019.07.080_bib1
  article-title: Intercalation electrodes
  contributor:
    fullname: Armand
– start-page: 65
  year: 2011
  ident: 10.1016/j.carbon.2019.07.080_bib11
  article-title: Carbon-based anodes - a “rare earth” situation?
  publication-title: BEST Winter
  contributor:
    fullname: Steinrötter
– volume: 21
  start-page: 745
  year: 2000
  ident: 10.1016/j.carbon.2019.07.080_bib27
  article-title: Raman study of the microstructure changes of phenolic resin during pyrolysis
  publication-title: Polym. Compos.
  doi: 10.1002/pc.10229
  contributor:
    fullname: Ko
– volume: 101
  start-page: 4630
  year: 2002
  ident: 10.1016/j.carbon.2019.07.080_bib12
  article-title: Simultaneous measurements and modeling of the electrochemical impedance and the cyclic voltammetric characteristics of graphite electrodes doped with lithium
  publication-title: J. Phys. Chem. B
  doi: 10.1021/jp9701909
  contributor:
    fullname: Levi
– volume: 258
  start-page: 136
  year: 1975
  ident: 10.1016/j.carbon.2019.07.080_bib36
  article-title: Structure of graphite by neutron diffraction
  publication-title: Nature
  doi: 10.1038/258136a0
  contributor:
    fullname: Trucano
– volume: 119–121
  start-page: 8
  year: 2003
  ident: 10.1016/j.carbon.2019.07.080_bib18
  article-title: Purification process of natural graphite as anode for Li-ion batteries: chemical versus thermal
  publication-title: J. Power Sources
  doi: 10.1016/S0378-7753(03)00116-2
  contributor:
    fullname: Zaghib
– volume: 45
  start-page: 476
  year: 2014
  ident: 10.1016/j.carbon.2019.07.080_bib31
  article-title: Stress-dependent correlations for resonant Raman bands in graphite with defects
  publication-title: J. Raman Spectrosc.
  doi: 10.1002/jrs.4475
  contributor:
    fullname: Del Corro
– volume: 142
  start-page: 2882
  year: 1995
  ident: 10.1016/j.carbon.2019.07.080_bib7
  article-title: The study of electrolyte solutions based on ethylene and diethyl carbonates for rechargeable Li batteries
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1.2048659
  contributor:
    fullname: Aurbach
– volume: 124
  start-page: 191
  year: 2003
  ident: 10.1016/j.carbon.2019.07.080_bib17
  article-title: Rate capability of natural Swedish graphite as anode material in Li-ion batteries
  publication-title: J. Power Sources
  doi: 10.1016/S0378-7753(03)00603-7
  contributor:
    fullname: Herstedt
– volume: 146
  start-page: 146
  year: 2005
  ident: 10.1016/j.carbon.2019.07.080_bib24
  article-title: Capacity fading of lithiated graphite electrodes studied by a combination of electroanalytical methods, Raman spectroscopy and SEM
  publication-title: J. Power Sources
  doi: 10.1016/j.jpowsour.2005.03.107
  contributor:
    fullname: Markervich
– volume: 143
  start-page: 3809
  year: 1996
  ident: 10.1016/j.carbon.2019.07.080_bib6
  article-title: A comparative study of synthetic graphite and Li electrodes in electrolyte solutions based on ethylene carbonate-dimethyl carbonate mixtures
  publication-title: J. Electrochem. Soc.
  doi: 10.1149/1.1837300
  contributor:
    fullname: Aurbach
– volume: 2014
  start-page: 549019
  year: 2014
  ident: 10.1016/j.carbon.2019.07.080_bib20
  article-title: Appraisal on textured grain growth and photoconductivity of ZnO Thin Film SILAR
  publication-title: Adv. Chem.
  doi: 10.1155/2014/549019
  contributor:
    fullname: Thomas
– volume: 1
  start-page: 22
  year: 1953
  ident: 10.1016/j.carbon.2019.07.080_bib22
  article-title: X-ray line broadening from filed aluminium and wolfram
  publication-title: Acta Metall.
  doi: 10.1016/0001-6160(53)90006-6
  contributor:
    fullname: Williamson
– volume: 362
  start-page: 2289
  year: 2004
  ident: 10.1016/j.carbon.2019.07.080_bib33
  article-title: Raman scattering of non-planar graphite: arched edges, polyhedral crystals, whiskers and cones
  publication-title: Philos. Trans. R. Soc. A Math. Phys. Eng. Sci.
  doi: 10.1098/rsta.2004.1442
  contributor:
    fullname: Tan
– volume: 40
  start-page: 2197
  year: 1995
  ident: 10.1016/j.carbon.2019.07.080_bib3
  article-title: The sei model—application to lithium-polymer electrolyte batteries
  publication-title: Electrochim. Acta
  doi: 10.1016/0013-4686(95)00163-9
  contributor:
    fullname: Peled
– volume: 89
  start-page: 327
  year: 1996
  ident: 10.1016/j.carbon.2019.07.080_bib25
  article-title: Raman scattering investigation of carbons obtained by heat treatment of a polyfurfuryl alcohol
  publication-title: Solid State Ion.
  doi: 10.1016/0167-2738(96)00352-9
  contributor:
    fullname: Li
– start-page: 1
  year: 2001
  ident: 10.1016/j.carbon.2019.07.080_bib23
  article-title: A high capacity natural Swedish graphite – the beneficial effect of jet-milling
  contributor:
    fullname: Herstedt
– volume: vol. 2
  year: 2014
  ident: 10.1016/j.carbon.2019.07.080_bib15
  contributor:
    fullname: Focke
– volume: 67
  start-page: 473
  year: 1995
  ident: 10.1016/j.carbon.2019.07.080_bib39
  article-title: Recommended terminology for the description of carbon as a solid (IUPAC Recommendations 1995)
  publication-title: Pure Appl. Chem.
  doi: 10.1351/pac199567030473
  contributor:
    fullname: Fitzer
– volume: 39
  start-page: 2559
  year: 1994
  ident: 10.1016/j.carbon.2019.07.080_bib10
  article-title: The dependence of the performance of Li-C intercalation anodes for Li-ion secondary batteries on the electrolyte solution composition
  publication-title: Electrochim. Acta
  doi: 10.1016/0013-4686(94)00221-5
  contributor:
    fullname: Ein-Eli
– volume: 5
  start-page: 1271
  year: 1990
  ident: 10.1016/j.carbon.2019.07.080_bib21
  article-title: Preferred orientation of pitch precursor fibers
  publication-title: J. Mater. Res.
  doi: 10.1557/JMR.1990.1271
  contributor:
    fullname: Hamada
SSID ssj0004814
Score 2.357837
Snippet Round-shaped natural graphite is commonly used as anode material for rechargeable lithium-ion batteries. We report atypical electrochemical behavior of...
SourceID proquest
crossref
elsevier
SourceType Aggregation Database
Publisher
StartPage 313
SubjectTerms Anodes
Batteries
Electrochemical analysis
Electrode materials
Exfoliation
Fracture toughness
Graphene
Graphite
Lithium
Lithium-ion batteries
Raman spectroscopy
Rechargeable batteries
Spectrum analysis
Title Abnormal electrochemical behavior of rounded graphite
URI https://dx.doi.org/10.1016/j.carbon.2019.07.080
https://www.proquest.com/docview/2315053358/abstract/
Volume 154
hasFullText 1
inHoldings 1
isFullTextHit
isPrint
link http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1NS8NAEB1KPehF_MRqLTl4Xdsmu9nssRRLVezJQm9Ld7OBiqSl1qu_3ZnNLqIIgseEJCRvJzNvmZk3ADdDJ6ThdslUnjrGS-WYcrllKTeUhZLC-FTM0yyfzvnDQixaMI69MFRWGXx_49O9tw5n-gHN_ma1oh5fouPITxTaKRoqdbBjMEKbvv34KvPgRaPvTWl-ujq2z_kaL7vcmjWpoA6Vl_Akccjfw9MPR-2jz-QIDgNtTEbNmx1Dy9UnsD-O09pOQYxMTfTzNQmDbWxQAkhiI36yrpItDVFyZeJlqpFsnsF8cvc8nrIwEoHZTGY7Jgo_GYwPS-EqZD48tbkzlUMagUwkM9IWCr_Z0K5AGtzapbnMrHAKA7lE6pGdQ7te1-6CmrUHuXWk1IlbCmX50gpVKcFlWVnDs7wDLCKhN43yhY4lYS-6QU4TcnogNSLXARnh0t9WUKNz_uPObkRXhz_oTeO6CuoTFsXlvx98BQd01FSfdKG92767a-QQO9PzRtKDvdH943T2CfHVw0U
link.rule.ids 315,786,790,4521,24144,27957,27958,45620,45714
linkProvider Elsevier
linkToHtml http://utb.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV09T8MwELVKGcqC-BSFAhlYTdvEjuOxqqgKtJ1aqZtVO45UhNKqhJXfzp1jC4GQkFjzpeT5cvesu3tHyF3fcqGZWVGZxpayXFoqbWpozDRmoQTXLhUznaXjBXta8mWDDEMvDJZVet9f-3Tnrf2Rrkezu12vsccX6TjwEwl2Coa6R_aRzuP8hvuPrzoPltUC35jnx8tD_5wr8jKrnd6gDGpfOg1PVIf8PT798NQu_IyOyKHnjdGgfrVj0rDlCWkNw7i2U8IHukT--Rr5yTbGSwFEoRM_2hTRDqco2TxyOtXANs_IYvQwH46pn4lATSKSivLMjQZj_ZzbAqgPi01qdWGBRwAVSbQwmYRv1rgtEBr2dnEqEsOthEgugHsk56RZbkp7gd3avdRYlOqEPYU0bGW4LCRnIi-MZknaJjQgoba19IUKNWEvqkZOIXKqJxQg1yYiwKW-LaEC7_zHnZ2ArvK_0JuCheXYKMyzy38_-Ja0xvPpRE0eZ89X5ADP1KUoHdKsdu_2GghFpW-cwXwCsCrE1w
openUrl ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Abnormal+electrochemical+behavior+of+rounded+graphite&rft.jtitle=Carbon+%28New+York%29&rft.au=Lavi%2C+Ortal&rft.au=Haik%2C+Ortal&rft.au=Hirshberg%2C+Daniel&rft.au=Talyosef%2C+Yosef&rft.date=2019-12-01&rft.pub=Elsevier+Ltd&rft.issn=0008-6223&rft.eissn=1873-3891&rft.volume=154&rft.spage=313&rft.epage=321&rft_id=info:doi/10.1016%2Fj.carbon.2019.07.080&rft.externalDocID=S0008622319307730
thumbnail_l http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0008-6223&client=summon
thumbnail_m http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0008-6223&client=summon
thumbnail_s http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0008-6223&client=summon