Metal-free polymerization: synthesis and properties of fused benzo[1,2-:4,5-′]bis[]benzothiophene (BBBT) polymers
We report the "green" synthesis and characterization of a series of fused benzo[1,2- b :4,5- b ′]bis[ b ]benzothiophene (BBBT) polymers containing a phenyl ring and naphthalene as comonomers, as well as BBBT homopolymers. These novel fused polymers have been obtained from simple acid and h...
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| Published in | Polymer chemistry Vol. 11; no. 22; pp. 3695 - 37 |
|---|---|
| Main Authors | , , , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Cambridge
Royal Society of Chemistry
14.06.2020
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| Subjects | |
| Online Access | Get full text |
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| Abstract | We report the "green" synthesis and characterization of a series of fused benzo[1,2-
b
:4,5-
b
′]bis[
b
]benzothiophene (BBBT) polymers containing a phenyl ring and naphthalene as comonomers, as well as BBBT homopolymers. These novel fused polymers have been obtained from simple acid and hexaethyltriaminophosphine catalyzed polymerization without involving any metal catalyst. The effect of the different aromatic units on the optical and electronic properties of the resulting polymers has been studied. It was found that these polymers possess high electron affinities due to the presence of electron-deficient lactams on each repeat unit. BBBT-P and BBBT-N exhibit NIR absorption spectra with the tail extending to 1000 nm, while the BBBT homopolymer exhibits a large blue-shifted absorption.
A family of fused semiconducting polymers containing the thienoacenes
BBBT
has been synthesized efficiently by non-metal and environmentally benign polymerization. |
|---|---|
| AbstractList | We report the "green" synthesis and characterization of a series of fused benzo[1,2-
b
:4,5-
b
′]bis[
b
]benzothiophene (BBBT) polymers containing a phenyl ring and naphthalene as comonomers, as well as BBBT homopolymers. These novel fused polymers have been obtained from simple acid and hexaethyltriaminophosphine catalyzed polymerization without involving any metal catalyst. The effect of the different aromatic units on the optical and electronic properties of the resulting polymers has been studied. It was found that these polymers possess high electron affinities due to the presence of electron-deficient lactams on each repeat unit. BBBT-P and BBBT-N exhibit NIR absorption spectra with the tail extending to 1000 nm, while the BBBT homopolymer exhibits a large blue-shifted absorption.
A family of fused semiconducting polymers containing the thienoacenes
BBBT
has been synthesized efficiently by non-metal and environmentally benign polymerization. We report the “green” synthesis and characterization of a series of fused benzo[1,2-b:4,5-b′]bis[b]benzothiophene (BBBT) polymers containing a phenyl ring and naphthalene as comonomers, as well as BBBT homopolymers. These novel fused polymers have been obtained from simple acid and hexaethyltriaminophosphine catalyzed polymerization without involving any metal catalyst. The effect of the different aromatic units on the optical and electronic properties of the resulting polymers has been studied. It was found that these polymers possess high electron affinities due to the presence of electron-deficient lactams on each repeat unit. BBBT-P and BBBT-N exhibit NIR absorption spectra with the tail extending to 1000 nm, while the BBBT homopolymer exhibits a large blue-shifted absorption. We report the “green” synthesis and characterization of a series of fused benzo[1,2- b :4,5- b ′]bis[ b ]benzothiophene (BBBT) polymers containing a phenyl ring and naphthalene as comonomers, as well as BBBT homopolymers. These novel fused polymers have been obtained from simple acid and hexaethyltriaminophosphine catalyzed polymerization without involving any metal catalyst. The effect of the different aromatic units on the optical and electronic properties of the resulting polymers has been studied. It was found that these polymers possess high electron affinities due to the presence of electron-deficient lactams on each repeat unit. BBBT-P and BBBT-N exhibit NIR absorption spectra with the tail extending to 1000 nm, while the BBBT homopolymer exhibits a large blue-shifted absorption. |
| Author | Yue, Wan Liao, Hailiang Li, Zhengke Yao, Liping Ravva, Mahesh Kumar McCulloch, Iain Wang, Yazhou Guo, Yanjun Yu, Yaping Duan, Jiayao |
| AuthorAffiliation | State Key Laboratory of Optoelectronic Materials and Technologies Guangxi University for Nationalities King Abdullah University of Science and Technology (KAUST) KAUST Solar Centre Imperial College London Sun Yet-Sen University Guangxi Key Laboratory of Chemistry and Engineering of Forest Products Guangxi Collaborative Innovation Center for Chemistry and Engineering of Forest Products Department of Chemistry Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education School of Materials and Engineering Department of Chemistry and Centre for Plastic Electronics College of Chemistry and Chemical Engineering SRM University - AP |
| AuthorAffiliation_xml | – name: State Key Laboratory of Optoelectronic Materials and Technologies – name: School of Materials and Engineering – name: King Abdullah University of Science and Technology (KAUST) KAUST Solar Centre – name: Department of Chemistry – name: Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education – name: Guangxi Key Laboratory of Chemistry and Engineering of Forest Products – name: Imperial College London – name: Guangxi Collaborative Innovation Center for Chemistry and Engineering of Forest Products – name: Department of Chemistry and Centre for Plastic Electronics – name: Guangxi University for Nationalities – name: College of Chemistry and Chemical Engineering – name: Sun Yet-Sen University – name: SRM University - AP |
| Author_xml | – sequence: 1 givenname: Liping surname: Yao fullname: Yao, Liping – sequence: 2 givenname: Hailiang surname: Liao fullname: Liao, Hailiang – sequence: 3 givenname: Mahesh Kumar surname: Ravva fullname: Ravva, Mahesh Kumar – sequence: 4 givenname: Yanjun surname: Guo fullname: Guo, Yanjun – sequence: 5 givenname: Jiayao surname: Duan fullname: Duan, Jiayao – sequence: 6 givenname: Yazhou surname: Wang fullname: Wang, Yazhou – sequence: 7 givenname: Yaping surname: Yu fullname: Yu, Yaping – sequence: 8 givenname: Zhengke surname: Li fullname: Li, Zhengke – sequence: 9 givenname: Iain surname: McCulloch fullname: McCulloch, Iain – sequence: 10 givenname: Wan surname: Yue fullname: Yue, Wan |
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| Snippet | We report the "green" synthesis and characterization of a series of fused benzo[1,2-
b
:4,5-
b
′]bis[
b
]benzothiophene (BBBT) polymers containing a phenyl... We report the “green” synthesis and characterization of a series of fused benzo[1,2- b :4,5- b ′]bis[ b ]benzothiophene (BBBT) polymers containing a phenyl... We report the “green” synthesis and characterization of a series of fused benzo[1,2-b:4,5-b′]bis[b]benzothiophene (BBBT) polymers containing a phenyl ring and... |
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| SubjectTerms | Absorption spectra Benzothiophene Blue shift Chemical synthesis Naphthalene Optical properties Polymer chemistry Polymerization Polymers |
| Title | Metal-free polymerization: synthesis and properties of fused benzo[1,2-:4,5-′]bis[]benzothiophene (BBBT) polymers |
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