Regio‐ and Enantioselective γ‐Allylic Alkylation of In Situ‐Generated Free Dienolates via Scandium/Iridium Dual Catalysis - Zhang, Jian; Yang, Wu‐Lin; Zheng, Hanliang; Wang, Yi; Deng, Wei‐Ping (Angewandte Chemie International Edition, 2022)
Keywords: Alkylation; Allylation; Asymmetric Synthesis; Bimetals; Catalysis; Chemistry; Chemistry, Multidisciplinary; Computer applications; Density functional theory; Dienolates; Dual Catalysis; Enantiomers; Iridium; Physical Sciences; Reaction mechanisms; Scandium; Science & Technology; Stereoisomerism; Dual Catalysis; N-HETEROCYCLIC CARBENE; ASYMMETRIC-SYNTHESIS; SYNERGISTIC IRIDIUM; ENANTIO; ALPHA-AMINO-ACIDS; SUBSTITUTION-REACTIONS; Dienolates; DIASTEREO; Allylation; ALCOHOLS; REARRANGEMENT; Asymmetric Synthesis; Iridium