Copper‐Catalyzed Enantioselective Markovnikov Protoboration of α‐Olefins Enabled by a Buttressed N‐Heterocyclic Carbene Ligand - Cai, Yuan; Yang, Xin‐Tuo; Zhang, Shuo‐Qing; Li, Feng; Li, Yu‐Qing; Ruan, Lin‐Xin; Hong, Xin; Shi, Shi‐Liang (Angewandte Chemie International Edition, 2018)
Keywords: Alkenes; Ambient temperature; asymmetric synthesis; Buttresses; Chemistry; Chemistry, Multidisciplinary; Copper; Enantiomers; Esters; Functional groups; ligand design; Ligands; N-heterocyclic carbenes; olefins; Physical Sciences; Regioselectivity; Science & Technology; Substrates; TRANSITION-METAL CATALYSIS; STYRENES; TRISUBSTITUTED ALKENES; ASYMMETRIC HYDROBORATION; olefins; DESYMMETRIZATION; TERTIARY BORONIC ESTERS; CROSS-COUPLING REACTIONS; asymmetric synthesis; ligand design; copper; 1,1-DISUBSTITUTED ARYL ALKENES; UNACTIVATED TERMINAL ALKENES; ADDITIONS; N-heterocyclic carbenes