A Rational Biphasic Tailoring Strategy Enabling High‐Performance Layered Cathodes for Sodium‐Ion Batteries
Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na‐ion batteries. These abundant components lead to complicated structural chemistry, closely affecting the stacking preference, phase transition and Na+ kinetics. With th...
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| Published in | Angewandte Chemie International Edition Vol. 61; no. 19; pp. e202117728 - n/a |
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| Main Authors | , , , , , , , , , , , |
| Format | Journal Article |
| Language | English |
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02.05.2022
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| Edition | International ed. in English |
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| Abstract | Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na‐ion batteries. These abundant components lead to complicated structural chemistry, closely affecting the stacking preference, phase transition and Na+ kinetics. With this perspective, we explore the thermodynamically stable phase diagram of various P2/O3 composites based on a rational biphasic tailoring strategy. Then a specific P2/O3 composite is investigated and compared with its monophasic counterparts. A highly reversible structural evolution of P2/O3–P2/O3/P3–P2/P3–P2/Z/O3′–Z/O3′ based on the Ni2+/Ni3.5+, Fe3+/Fe4+ and Mn3.8+/Mn4+ redox couples upon sequential Na extraction/insertion is revealed. The reduced structural strain at the phase boundary alleviates the phase transition and decreases the lattice mismatch during cycling, endowing the biphasic electrode a large reversible capacity of 144 mAh g−1 with the energy density approaching 514 Wh kg−1.
A rational biphasic tailoring strategy to prepare layered composite cathodes with the desired phase ratio is proposed. Benefiting from the reversible phase transition within transition metal slabs and the decreased structure strain at the phase boundary of the intergrowth structure during Na extraction and insertion, the Com‐NaNMFT composite material demonstrates excellent electrochemical performance. |
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| AbstractList | Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na‐ion batteries. These abundant components lead to complicated structural chemistry, closely affecting the stacking preference, phase transition and Na+ kinetics. With this perspective, we explore the thermodynamically stable phase diagram of various P2/O3 composites based on a rational biphasic tailoring strategy. Then a specific P2/O3 composite is investigated and compared with its monophasic counterparts. A highly reversible structural evolution of P2/O3–P2/O3/P3–P2/P3–P2/Z/O3′–Z/O3′ based on the Ni2+/Ni3.5+, Fe3+/Fe4+ and Mn3.8+/Mn4+ redox couples upon sequential Na extraction/insertion is revealed. The reduced structural strain at the phase boundary alleviates the phase transition and decreases the lattice mismatch during cycling, endowing the biphasic electrode a large reversible capacity of 144 mAh g−1 with the energy density approaching 514 Wh kg−1.
A rational biphasic tailoring strategy to prepare layered composite cathodes with the desired phase ratio is proposed. Benefiting from the reversible phase transition within transition metal slabs and the decreased structure strain at the phase boundary of the intergrowth structure during Na extraction and insertion, the Com‐NaNMFT composite material demonstrates excellent electrochemical performance. Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na‐ion batteries. These abundant components lead to complicated structural chemistry, closely affecting the stacking preference, phase transition and Na + kinetics. With this perspective, we explore the thermodynamically stable phase diagram of various P2/O3 composites based on a rational biphasic tailoring strategy. Then a specific P2/O3 composite is investigated and compared with its monophasic counterparts. A highly reversible structural evolution of P2/O3–P2/O3/P3–P2/P3–P2/Z/O3′–Z/O3′ based on the Ni 2+ /Ni 3.5+ , Fe 3+ /Fe 4+ and Mn 3.8+ /Mn 4+ redox couples upon sequential Na extraction/insertion is revealed. The reduced structural strain at the phase boundary alleviates the phase transition and decreases the lattice mismatch during cycling, endowing the biphasic electrode a large reversible capacity of 144 mAh g −1 with the energy density approaching 514 Wh kg −1 . Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na-ion batteries. These abundant components lead to complicated structural chemistry, closely affecting the stacking preference, phase transition and Na kinetics. With this perspective, we explore the thermodynamically stable phase diagram of various P2/O3 composites based on a rational biphasic tailoring strategy. Then a specific P2/O3 composite is investigated and compared with its monophasic counterparts. A highly reversible structural evolution of P2/O3-P2/O3/P3-P2/P3-P2/Z/O3'-Z/O3' based on the Ni /Ni , Fe /Fe and Mn /Mn redox couples upon sequential Na extraction/insertion is revealed. The reduced structural strain at the phase boundary alleviates the phase transition and decreases the lattice mismatch during cycling, endowing the biphasic electrode a large reversible capacity of 144 mAh g with the energy density approaching 514 Wh kg . Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na‐ion batteries. These abundant components lead to complicated structural chemistry, closely affecting the stacking preference, phase transition and Na+ kinetics. With this perspective, we explore the thermodynamically stable phase diagram of various P2/O3 composites based on a rational biphasic tailoring strategy. Then a specific P2/O3 composite is investigated and compared with its monophasic counterparts. A highly reversible structural evolution of P2/O3–P2/O3/P3–P2/P3–P2/Z/O3′–Z/O3′ based on the Ni2+/Ni3.5+, Fe3+/Fe4+ and Mn3.8+/Mn4+ redox couples upon sequential Na extraction/insertion is revealed. The reduced structural strain at the phase boundary alleviates the phase transition and decreases the lattice mismatch during cycling, endowing the biphasic electrode a large reversible capacity of 144 mAh g−1 with the energy density approaching 514 Wh kg−1. Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na-ion batteries. These abundant components lead to complicated structural chemistry, closely affecting the stacking preference, phase transition and Na+ kinetics. With this perspective, we explore the thermodynamically stable phase diagram of various P2/O3 composites based on a rational biphasic tailoring strategy. Then a specific P2/O3 composite is investigated and compared with its monophasic counterparts. A highly reversible structural evolution of P2/O3-P2/O3/P3-P2/P3-P2/Z/O3'-Z/O3' based on the Ni2+ /Ni3.5+ , Fe3+ /Fe4+ and Mn3.8+ /Mn4+ redox couples upon sequential Na extraction/insertion is revealed. The reduced structural strain at the phase boundary alleviates the phase transition and decreases the lattice mismatch during cycling, endowing the biphasic electrode a large reversible capacity of 144 mAh g-1 with the energy density approaching 514 Wh kg-1 .Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na-ion batteries. These abundant components lead to complicated structural chemistry, closely affecting the stacking preference, phase transition and Na+ kinetics. With this perspective, we explore the thermodynamically stable phase diagram of various P2/O3 composites based on a rational biphasic tailoring strategy. Then a specific P2/O3 composite is investigated and compared with its monophasic counterparts. A highly reversible structural evolution of P2/O3-P2/O3/P3-P2/P3-P2/Z/O3'-Z/O3' based on the Ni2+ /Ni3.5+ , Fe3+ /Fe4+ and Mn3.8+ /Mn4+ redox couples upon sequential Na extraction/insertion is revealed. The reduced structural strain at the phase boundary alleviates the phase transition and decreases the lattice mismatch during cycling, endowing the biphasic electrode a large reversible capacity of 144 mAh g-1 with the energy density approaching 514 Wh kg-1 . |
| Author | Yin, Ya‐Xia Yu, Lianzheng Hua, Weibo Liu, Mengting Han, Xiaogang Fan, Xin‐Yu Guo, Yu‐Guo Wang, Peng‐Fei Ji, Fang‐Di Guo, Yu‐Jie Cheng, Zhiwei Feng, Yi‐Hu |
| Author_xml | – sequence: 1 givenname: Zhiwei surname: Cheng fullname: Cheng, Zhiwei organization: Xi'an Jiaotong University – sequence: 2 givenname: Xin‐Yu surname: Fan fullname: Fan, Xin‐Yu organization: Xi'an Jiaotong University – sequence: 3 givenname: Lianzheng surname: Yu fullname: Yu, Lianzheng organization: Xi'an Jiaotong University – sequence: 4 givenname: Weibo surname: Hua fullname: Hua, Weibo email: weibo.hua@xjtu.edu.cn organization: Xi'an Jiaotong University – sequence: 5 givenname: Yu‐Jie surname: Guo fullname: Guo, Yu‐Jie organization: University of Chinese Academy of Sciences – sequence: 6 givenname: Yi‐Hu surname: Feng fullname: Feng, Yi‐Hu organization: Xi'an Jiaotong University – sequence: 7 givenname: Fang‐Di surname: Ji fullname: Ji, Fang‐Di organization: Xi'an Jiaotong University – sequence: 8 givenname: Mengting surname: Liu fullname: Liu, Mengting organization: Xi'an Jiaotong University – sequence: 9 givenname: Ya‐Xia surname: Yin fullname: Yin, Ya‐Xia organization: University of Chinese Academy of Sciences – sequence: 10 givenname: Xiaogang surname: Han fullname: Han, Xiaogang organization: Xi'an Jiaotong University – sequence: 11 givenname: Yu‐Guo surname: Guo fullname: Guo, Yu‐Guo organization: University of Chinese Academy of Sciences – sequence: 12 givenname: Peng‐Fei orcidid: 0000-0001-9882-5059 surname: Wang fullname: Wang, Peng‐Fei email: pfwang@xjtu.edu.cn organization: Xi'an Jiaotong University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/35233902$$D View this record in MEDLINE/PubMed |
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| Keywords | Electrochemistry Layered Oxides Intergrowth Structure Sodium-Ion Batteries Cathodes |
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| Snippet | Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na‐ion batteries. These... Layered oxide cathodes usually exhibit high compositional diversity, thus providing controllable electrochemical performance for Na-ion batteries. These... |
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| SubjectTerms | Batteries Cathodes Electrochemical analysis Electrochemistry Flux density Intergrowth Structure Iron Layered Oxides Manganese Phase diagrams Phase transitions Rechargeable batteries Redox properties Sodium Sodium-Ion Batteries Structural strain |
| Title | A Rational Biphasic Tailoring Strategy Enabling High‐Performance Layered Cathodes for Sodium‐Ion Batteries |
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