Bottom‐Up Construction of Ni(II)‐Incorporated Covalent Organic Framework for Metallaphotoredox Catalysis

• Published in: Chemistry : a European journal Vol. 30; no. 10; pp. e202303476 - n/a
• Main Authors: Hu, Hai‐Chao, Wang, Zhi‐Peng, Liang, Lin, Du, Xin‐Yu, Li, Ting, Feng, Jie, Xiao, Tian‐Tian, Jin, Ze‐Ming, Ding, San‐Yuan, Liu, Qiang, Lu, Liang‐Qiu, Xiao, Wen‐Jing, Wang, Wei
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 16.02.2024; Wiley Subscription Services, Inc
• Subjects: Active sites; bottom-up strategy; Catalysis; Catalysts; Catalytic activity; Chemical reactions; Chemistry; Chemistry, Multidisciplinary; covalent organic framework; Cross coupling; cross-coupling reactions; metallaphotoredox catalysis; Nickel; Physical Sciences; Recyclability; Science & Technology; Transition metals; bottom-up strategy; NICKEL CATALYSIS; PHOTOREDOX; TRANSITION-METAL; metallaphotoredox catalysis; ARYL; CRYSTALLINE; EFFICIENT; covalent organic framework; cross-coupling reactions; PHOTOCATALYST; TRANSFORMATIONS

The construction of an all‐in‐one catalyst, in which the photosensitizer and the transition metal site are close to each other, is important for improving the efficiency of metallaphotoredox catalysis. However, the development of convenient synthetic strategies for the precise construction of an all...