Post‐Assembly Modification of Homochiral Titanium–Organic Cages for Recognition and Separation of Molecular Isomers
A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a post‐assembly modification strategy, which made it easier to study the host–guest chemistry of the solid‐state MOC using a single‐crystal diffraction technique. Anionic Ti4L6 (L=embonate) cage can be used as a 4...
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| Published in | Angewandte Chemie International Edition Vol. 62; no. 16; pp. e202300726 - n/a |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Germany
Wiley Subscription Services, Inc
11.04.2023
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| Edition | International ed. in English |
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| Abstract | A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a post‐assembly modification strategy, which made it easier to study the host–guest chemistry of the solid‐state MOC using a single‐crystal diffraction technique. Anionic Ti4L6 (L=embonate) cage can be used as a 4‐connecting crystal engineering tecton, and its optical resolution was achieved, thus homochiral ΔΔΔΔ‐ and ΛΛΛΛ‐[Ti4L6] cages were obtained. Accordingly, a pair of homochiral cage‐based microporous frameworks (PTC‐236(Δ) and PTC‐236(Λ)) were easily prepared by a post‐assembly reaction. PTC‐236 has rich recognition sites provided by the Ti4L6 moieties, chiral channels and high framework stability, affording a single‐crystal‐to‐single‐crystal transformation for guest structure analyses. Thus it was successfully utilized for the recognition and separation of isomeric molecules. This study provides a new approach for the orderly combination of well‐defined MOCs into functional porous frameworks.
A chiral metal–organic cage has been extended and introduced into a porous framework by using a post‐assembly modification strategy. The microporous frameworks were successfully utilized for the recognition and separation of isomeric molecules, including aromatic compounds, nitriles, and chiral aromatic alcohols. |
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| AbstractList | A chiral metal-organic cage (MOC) was extended and fixed into a porous framework using a post-assembly modification strategy, which made it easier to study the host-guest chemistry of the solid-state MOC using a single-crystal diffraction technique. Anionic Ti4 L6 (L=embonate) cage can be used as a 4-connecting crystal engineering tecton, and its optical resolution was achieved, thus homochiral ΔΔΔΔ- and ΛΛΛΛ-[Ti4 L6 ] cages were obtained. Accordingly, a pair of homochiral cage-based microporous frameworks (PTC-236(Δ) and PTC-236(Λ)) were easily prepared by a post-assembly reaction. PTC-236 has rich recognition sites provided by the Ti4 L6 moieties, chiral channels and high framework stability, affording a single-crystal-to-single-crystal transformation for guest structure analyses. Thus it was successfully utilized for the recognition and separation of isomeric molecules. This study provides a new approach for the orderly combination of well-defined MOCs into functional porous frameworks.A chiral metal-organic cage (MOC) was extended and fixed into a porous framework using a post-assembly modification strategy, which made it easier to study the host-guest chemistry of the solid-state MOC using a single-crystal diffraction technique. Anionic Ti4 L6 (L=embonate) cage can be used as a 4-connecting crystal engineering tecton, and its optical resolution was achieved, thus homochiral ΔΔΔΔ- and ΛΛΛΛ-[Ti4 L6 ] cages were obtained. Accordingly, a pair of homochiral cage-based microporous frameworks (PTC-236(Δ) and PTC-236(Λ)) were easily prepared by a post-assembly reaction. PTC-236 has rich recognition sites provided by the Ti4 L6 moieties, chiral channels and high framework stability, affording a single-crystal-to-single-crystal transformation for guest structure analyses. Thus it was successfully utilized for the recognition and separation of isomeric molecules. This study provides a new approach for the orderly combination of well-defined MOCs into functional porous frameworks. A chiral metal-organic cage (MOC) was extended and fixed into a porous framework using a post-assembly modification strategy, which made it easier to study the host-guest chemistry of the solid-state MOC using a single-crystal diffraction technique. Anionic Ti L (L=embonate) cage can be used as a 4-connecting crystal engineering tecton, and its optical resolution was achieved, thus homochiral ΔΔΔΔ- and ΛΛΛΛ-[Ti L ] cages were obtained. Accordingly, a pair of homochiral cage-based microporous frameworks (PTC-236(Δ) and PTC-236(Λ)) were easily prepared by a post-assembly reaction. PTC-236 has rich recognition sites provided by the Ti L moieties, chiral channels and high framework stability, affording a single-crystal-to-single-crystal transformation for guest structure analyses. Thus it was successfully utilized for the recognition and separation of isomeric molecules. This study provides a new approach for the orderly combination of well-defined MOCs into functional porous frameworks. A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a post‐assembly modification strategy, which made it easier to study the host–guest chemistry of the solid‐state MOC using a single‐crystal diffraction technique. Anionic Ti4L6 (L=embonate) cage can be used as a 4‐connecting crystal engineering tecton, and its optical resolution was achieved, thus homochiral ΔΔΔΔ‐ and ΛΛΛΛ‐[Ti4L6] cages were obtained. Accordingly, a pair of homochiral cage‐based microporous frameworks (PTC‐236(Δ) and PTC‐236(Λ)) were easily prepared by a post‐assembly reaction. PTC‐236 has rich recognition sites provided by the Ti4L6 moieties, chiral channels and high framework stability, affording a single‐crystal‐to‐single‐crystal transformation for guest structure analyses. Thus it was successfully utilized for the recognition and separation of isomeric molecules. This study provides a new approach for the orderly combination of well‐defined MOCs into functional porous frameworks. A chiral metal–organic cage has been extended and introduced into a porous framework by using a post‐assembly modification strategy. The microporous frameworks were successfully utilized for the recognition and separation of isomeric molecules, including aromatic compounds, nitriles, and chiral aromatic alcohols. A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a post‐assembly modification strategy, which made it easier to study the host–guest chemistry of the solid‐state MOC using a single‐crystal diffraction technique. Anionic Ti 4 L 6 (L=embonate) cage can be used as a 4‐connecting crystal engineering tecton, and its optical resolution was achieved, thus homochiral ΔΔΔΔ‐ and ΛΛΛΛ‐[Ti 4 L 6 ] cages were obtained. Accordingly, a pair of homochiral cage‐based microporous frameworks ( PTC‐236(Δ) and PTC‐236(Λ) ) were easily prepared by a post‐assembly reaction. PTC‐236 has rich recognition sites provided by the Ti 4 L 6 moieties, chiral channels and high framework stability, affording a single‐crystal‐to‐single‐crystal transformation for guest structure analyses. Thus it was successfully utilized for the recognition and separation of isomeric molecules. This study provides a new approach for the orderly combination of well‐defined MOCs into functional porous frameworks. A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a post‐assembly modification strategy, which made it easier to study the host–guest chemistry of the solid‐state MOC using a single‐crystal diffraction technique. Anionic Ti4L6 (L=embonate) cage can be used as a 4‐connecting crystal engineering tecton, and its optical resolution was achieved, thus homochiral ΔΔΔΔ‐ and ΛΛΛΛ‐[Ti4L6] cages were obtained. Accordingly, a pair of homochiral cage‐based microporous frameworks (PTC‐236(Δ) and PTC‐236(Λ)) were easily prepared by a post‐assembly reaction. PTC‐236 has rich recognition sites provided by the Ti4L6 moieties, chiral channels and high framework stability, affording a single‐crystal‐to‐single‐crystal transformation for guest structure analyses. Thus it was successfully utilized for the recognition and separation of isomeric molecules. This study provides a new approach for the orderly combination of well‐defined MOCs into functional porous frameworks. |
| Author | Wang, Fei Gu, Zhi‐Gang Li, Shangda Zhang, Jian Chen, Guang‐Hui Yu, Yinghua He, Yan‐Ping Lv, Hong |
| Author_xml | – sequence: 1 givenname: Guang‐Hui surname: Chen fullname: Chen, Guang‐Hui organization: Chinese Academy of Sciences – sequence: 2 givenname: Yan‐Ping surname: He fullname: He, Yan‐Ping organization: University of Chinese Academy of Sciences – sequence: 3 givenname: Yinghua surname: Yu fullname: Yu, Yinghua organization: Chinese Academy of Sciences – sequence: 4 givenname: Hong surname: Lv fullname: Lv, Hong organization: Chinese Academy of Sciences – sequence: 5 givenname: Shangda surname: Li fullname: Li, Shangda organization: Chinese Academy of Sciences – sequence: 6 givenname: Fei surname: Wang fullname: Wang, Fei organization: Chinese Academy of Sciences – sequence: 7 givenname: Zhi‐Gang surname: Gu fullname: Gu, Zhi‐Gang organization: Chinese Academy of Sciences – sequence: 8 givenname: Jian orcidid: 0000-0003-3373-9621 surname: Zhang fullname: Zhang, Jian email: zhj@fjirsm.ac.cn organization: Chinese Academy of Sciences |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/36807676$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1021/jacs.2c00760 10.1002/anie.201901668 10.1021/acsmaterialslett.0c00511 10.1002/advs.202104753 10.1016/j.memsci.2021.119564 10.1039/C9CS00091G 10.1016/j.xcrp.2021.100692 10.1002/anie.202209340 10.1021/acs.chemrev.0c00672 10.1021/acs.accounts.8b00328 10.1039/D1CS00759A 10.1021/jacs.9b04909 10.1021/jacs.0c00459 10.1016/j.ccr.2022.214439 10.1038/nature20771 10.1016/j.ccr.2017.10.031 10.1002/ange.201501081 10.1002/ange.202013839 10.1021/jacs.1c05613 10.1016/j.chempr.2020.06.038 10.1002/ange.202003220 10.1021/jacs.8b03781 10.1021/jacs.1c09278 10.1039/C9SC04543K 10.3389/fchem.2021.696081 10.1021/jacs.1c00108 10.1021/jacs.9b07178 10.1002/ange.202209340 10.1038/s41570-022-00380-y 10.1021/jacs.0c00640 10.1021/jacs.9b04520 10.1016/j.ccr.2020.213656 10.1002/ange.201901668 10.1021/acs.nanolett.1c02379 10.1039/D1CC01185E 10.1002/ange.202001059 10.1021/jacs.5b00832 10.1021/jacs.8b11527 10.1039/C9CC01745C 10.1021/jacs.0c02806 10.1016/j.ccr.2021.214354 10.1002/anie.202013839 10.1002/anie.201900429 10.1246/cl.190131 10.1021/jacs.9b05155 10.1021/acs.chemrev.1c00811 10.1021/jacs.0c08589 10.1002/anie.202003220 10.1002/asia.202000744 10.1002/ange.202205725 10.1016/j.memsci.2021.119354 10.1016/j.chempr.2021.07.017 10.1002/ange.202013977 10.1021/jacs.2c07978 10.1038/s41467-018-05818-w 10.1002/ange.201900429 10.1126/sciadv.1701126 10.1002/ange.202104164 10.1021/acs.cgd.0c01059 10.1002/asia.202100080 10.1002/cplu.202200172 10.1039/D1SC02883A 10.1002/anie.202205725 10.1021/jacs.8b08030 10.1021/jacs.8b09582 10.1021/acsami.0c16366 10.1002/anie.202001059 10.1002/anie.202013977 10.1039/D0CC01205J 10.1038/s41586-018-0339-0 10.1039/D0CS00038H 10.1002/anie.201501081 10.1002/anie.202104164 10.1021/jacs.0c01626 10.1021/jacs.9b06222 10.1021/jacs.7b09463 10.1039/C9SC01892A |
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| Keywords | Post-Assembly Modification Chiral Cage-Based Frameworks Recognition and Separation Titanium-Organic Cages |
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| References | 2021; 9 2018; 560 2021; 7 2021; 21 2018; 140 2017; 3 2021; 3 2020; 20 2020; 120 2020; 142 2019; 55 2022; 51 2019; 10 2020 2020; 59 132 2016; 540 2020; 15 2020; 12 2020; 56 2022; 87 2021; 143 2019; 141 2022; 459 2019 2019; 58 131 2017; 139 2022; 455 2022; 122 2022; 144 2021; 57 2020; 6 2018; 9 2021; 16 2022 2022; 61 134 2021; 12 2020; 2 2022; 3 2015; 137 2021; 632 2022; 6 2019; 48 2022; 9 2021; 636 2020; 49 2021 2021; 60 133 2015 2015; 54 127 2019; 378 2018; 51 2021; 430 e_1_2_7_5_2 e_1_2_7_3_2 e_1_2_7_9_2 e_1_2_7_7_2 e_1_2_7_19_2 e_1_2_7_17_2 e_1_2_7_15_2 e_1_2_7_60_2 e_1_2_7_13_3 e_1_2_7_1_1 e_1_2_7_13_2 e_1_2_7_41_2 e_1_2_7_62_2 e_1_2_7_11_2 e_1_2_7_43_2 e_1_2_7_64_2 e_1_2_7_45_2 e_1_2_7_66_2 e_1_2_7_47_2 e_1_2_7_68_2 e_1_2_7_26_2 e_1_2_7_47_3 e_1_2_7_49_1 e_1_2_7_28_2 e_1_2_7_28_3 Liu G. (e_1_2_7_55_2) 2020; 2 e_1_2_7_71_2 e_1_2_7_73_1 e_1_2_7_50_2 e_1_2_7_25_3 e_1_2_7_25_2 e_1_2_7_52_2 e_1_2_7_75_2 e_1_2_7_23_3 e_1_2_7_77_1 e_1_2_7_23_2 e_1_2_7_31_2 e_1_2_7_54_2 e_1_2_7_21_3 e_1_2_7_33_1 e_1_2_7_21_2 e_1_2_7_56_2 e_1_2_7_35_2 e_1_2_7_58_2 e_1_2_7_37_2 e_1_2_7_58_3 e_1_2_7_39_2 e_1_2_7_4_2 e_1_2_7_2_2 e_1_2_7_8_2 e_1_2_7_6_2 e_1_2_7_18_2 e_1_2_7_16_2 e_1_2_7_61_1 e_1_2_7_14_2 e_1_2_7_40_2 e_1_2_7_63_2 e_1_2_7_12_2 e_1_2_7_42_2 e_1_2_7_65_2 e_1_2_7_44_2 e_1_2_7_67_2 e_1_2_7_10_1 e_1_2_7_44_3 e_1_2_7_46_2 e_1_2_7_69_2 e_1_2_7_48_2 e_1_2_7_27_2 e_1_2_7_27_3 e_1_2_7_29_2 e_1_2_7_72_2 e_1_2_7_70_2 e_1_2_7_74_3 e_1_2_7_76_1 e_1_2_7_24_2 e_1_2_7_30_2 e_1_2_7_51_2 e_1_2_7_32_1 e_1_2_7_22_2 e_1_2_7_53_2 e_1_2_7_74_2 e_1_2_7_34_2 e_1_2_7_20_1 e_1_2_7_36_2 e_1_2_7_57_2 e_1_2_7_38_1 e_1_2_7_59_2 |
| References_xml | – volume: 636 year: 2021 publication-title: J. Membr. Sci. – volume: 55 start-page: 6177 year: 2019 end-page: 6180 publication-title: Chem. Commun. – volume: 459 year: 2022 publication-title: Coord. Chem. Rev. – volume: 430 year: 2021 publication-title: Coord. Chem. Rev. – volume: 632 year: 2021 publication-title: J. Membr. Sci. – volume: 455 year: 2022 publication-title: Coord. Chem. Rev. – volume: 59 132 start-page: 7435 7505 year: 2020 2020 end-page: 7438 7508 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 9 year: 2021 publication-title: Front. Chem. – volume: 139 start-page: 16845 year: 2017 end-page: 16851 publication-title: J. Am. Chem. Soc. – volume: 51 start-page: 2447 year: 2018 end-page: 2455 publication-title: Acc. Chem. Res. – volume: 143 start-page: 3562 year: 2021 end-page: 3570 publication-title: J. Am. Chem. Soc. – volume: 144 start-page: 4244 year: 2022 end-page: 4253 publication-title: J. Am. Chem. Soc. – volume: 7 start-page: 2771 year: 2021 end-page: 2786 publication-title: Chem – volume: 378 start-page: 333 year: 2019 end-page: 349 publication-title: Coord. Chem. Rev. – volume: 142 start-page: 17721 year: 2020 end-page: 17729 publication-title: J. Am. Chem. Soc. – volume: 12 start-page: 56310 year: 2020 end-page: 56318 publication-title: ACS Appl. Mater. Interfaces – volume: 137 start-page: 3967 year: 2015 end-page: 3974 publication-title: J. Am. Chem. Soc. – volume: 48 start-page: 597 year: 2019 end-page: 600 publication-title: Chem. Lett. – volume: 560 start-page: 65 year: 2018 end-page: 69 publication-title: Nature – volume: 120 start-page: 13480 year: 2020 end-page: 13544 publication-title: Chem. Rev. – volume: 141 start-page: 19634 year: 2019 end-page: 19643 publication-title: J. Am. Chem. Soc. – volume: 10 start-page: 10833 year: 2019 end-page: 10842 publication-title: Chem. Sci. – volume: 59 132 start-page: 11101 11194 year: 2020 2020 end-page: 11107 11200 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 60 133 start-page: 16594 16730 year: 2021 2021 end-page: 16599 16735 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 142 start-page: 6907 year: 2020 end-page: 6912 publication-title: J. Am. Chem. Soc. – volume: 140 start-page: 16877 year: 2018 end-page: 16881 publication-title: J. Am. Chem. Soc. – volume: 54 127 start-page: 6190 6288 year: 2015 2015 end-page: 6195 6293 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 6 start-page: 2395 year: 2020 end-page: 2406 publication-title: Chem – volume: 140 start-page: 14547 year: 2018 end-page: 14551 publication-title: J. Am. Chem. Soc. – volume: 140 start-page: 7674 year: 2018 end-page: 7680 publication-title: J. Am. Chem. Soc. – volume: 3 start-page: 268 year: 2021 end-page: 274 publication-title: ACS Mater. Lett. – volume: 87 year: 2022 publication-title: ChemPlusChem – volume: 16 start-page: 1092 year: 2021 end-page: 1100 publication-title: Chem. Asian J. – volume: 143 start-page: 14956 year: 2021 end-page: 14961 publication-title: J. Am. Chem. Soc. – volume: 142 start-page: 7270 year: 2020 end-page: 7275 publication-title: J. Am. Chem. Soc. – volume: 20 start-page: 6316 year: 2020 end-page: 6320 publication-title: Cryst. Growth Des. – volume: 15 start-page: 3275 year: 2020 end-page: 3280 publication-title: Chem. Asian J. – volume: 3 year: 2022 publication-title: Cell Rep. Phys. Sci. – volume: 2 start-page: 1382 year: 2020 end-page: 1390 publication-title: CCS Chem. – volume: 61 134 year: 2022 2022 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 51 start-page: 4876 year: 2022 end-page: 4889 publication-title: Chem. Soc. Rev. – volume: 49 start-page: 3889 year: 2020 end-page: 3919 publication-title: Chem. Soc. Rev. – volume: 10 start-page: 6661 year: 2019 end-page: 6665 publication-title: Chem. Sci. – volume: 58 131 start-page: 6347 6413 year: 2019 2019 end-page: 6350 6416 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 122 start-page: 12244 year: 2022 end-page: 12307 publication-title: Chem. Rev. – volume: 143 start-page: 21195 year: 2021 end-page: 21199 publication-title: J. Am. Chem. Soc. – volume: 56 start-page: 8031 year: 2020 end-page: 8034 publication-title: Chem. Commun. – volume: 141 start-page: 1045 year: 2019 end-page: 1053 publication-title: J. Am. Chem. Soc. – volume: 21 start-page: 9021 year: 2021 end-page: 9029 publication-title: Nano Lett. – volume: 57 start-page: 5187 year: 2021 end-page: 5190 publication-title: Chem. Commun. – volume: 9 year: 2022 publication-title: Adv. Sci. – volume: 142 start-page: 9594 year: 2020 end-page: 9598 publication-title: J. Am. Chem. Soc. – volume: 48 start-page: 4707 year: 2019 end-page: 4730 publication-title: Chem. Soc. Rev. – volume: 60 133 start-page: 2920 2956 year: 2021 2021 end-page: 2923 2959 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 60 133 start-page: 5729 5793 year: 2021 2021 end-page: 5733 5797 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 141 start-page: 13114 year: 2019 end-page: 13123 publication-title: J. Am. Chem. Soc. – volume: 141 start-page: 11621 year: 2019 end-page: 11627 publication-title: J. Am. Chem. Soc. – volume: 3 start-page: 636 year: 2017 end-page: 647 publication-title: Sci. Adv. – volume: 144 start-page: 19475 year: 2022 end-page: 19484 publication-title: J. Am. Chem. Soc. – volume: 540 start-page: 563 year: 2016 end-page: 566 publication-title: Nature – volume: 9 start-page: 3587 year: 2018 publication-title: Nat. Commun. – volume: 6 start-page: 339 year: 2022 end-page: 356 publication-title: Nat. Chem. Rev. – volume: 58 131 start-page: 7982 8066 year: 2019 2019 end-page: 7986 8070 publication-title: Angew. Chem. Int. Ed. Angew. Chem. – volume: 142 start-page: 5504 year: 2020 end-page: 5508 publication-title: J. Am. Chem. Soc. – volume: 141 start-page: 12064 year: 2019 end-page: 12070 publication-title: J. Am. Chem. Soc. – volume: 12 start-page: 12556 year: 2021 end-page: 12563 publication-title: Chem. Sci. – volume: 141 start-page: 14005 year: 2019 end-page: 14020 publication-title: J. Am. Chem. Soc. – ident: e_1_2_7_32_1 doi: 10.1021/jacs.2c00760 – ident: e_1_2_7_47_2 doi: 10.1002/anie.201901668 – ident: e_1_2_7_65_2 doi: 10.1021/acsmaterialslett.0c00511 – ident: e_1_2_7_73_1 – ident: e_1_2_7_20_1 – ident: e_1_2_7_34_2 doi: 10.1002/advs.202104753 – ident: e_1_2_7_62_2 doi: 10.1016/j.memsci.2021.119564 – ident: e_1_2_7_15_2 doi: 10.1039/C9CS00091G – ident: e_1_2_7_22_2 doi: 10.1016/j.xcrp.2021.100692 – ident: e_1_2_7_23_2 doi: 10.1002/anie.202209340 – ident: e_1_2_7_5_2 doi: 10.1021/acs.chemrev.0c00672 – ident: e_1_2_7_8_2 doi: 10.1021/acs.accounts.8b00328 – ident: e_1_2_7_36_2 doi: 10.1039/D1CS00759A – ident: e_1_2_7_16_2 doi: 10.1021/jacs.9b04909 – ident: e_1_2_7_26_2 doi: 10.1021/jacs.0c00459 – ident: e_1_2_7_3_2 doi: 10.1016/j.ccr.2022.214439 – ident: e_1_2_7_33_1 – ident: e_1_2_7_9_2 doi: 10.1038/nature20771 – ident: e_1_2_7_7_2 doi: 10.1016/j.ccr.2017.10.031 – ident: e_1_2_7_28_3 doi: 10.1002/ange.201501081 – ident: e_1_2_7_44_3 doi: 10.1002/ange.202013839 – ident: e_1_2_7_53_2 doi: 10.1021/jacs.1c05613 – ident: e_1_2_7_14_2 doi: 10.1016/j.chempr.2020.06.038 – ident: e_1_2_7_10_1 – ident: e_1_2_7_27_3 doi: 10.1002/ange.202003220 – ident: e_1_2_7_60_2 doi: 10.1021/jacs.8b03781 – ident: e_1_2_7_51_2 doi: 10.1021/jacs.1c09278 – ident: e_1_2_7_57_2 doi: 10.1039/C9SC04543K – ident: e_1_2_7_64_2 doi: 10.3389/fchem.2021.696081 – ident: e_1_2_7_41_2 doi: 10.1021/jacs.1c00108 – ident: e_1_2_7_17_2 doi: 10.1021/jacs.9b07178 – ident: e_1_2_7_23_3 doi: 10.1002/ange.202209340 – ident: e_1_2_7_35_2 doi: 10.1038/s41570-022-00380-y – ident: e_1_2_7_38_1 – ident: e_1_2_7_42_2 doi: 10.1021/jacs.0c00640 – ident: e_1_2_7_30_2 doi: 10.1021/jacs.9b04520 – ident: e_1_2_7_12_2 doi: 10.1016/j.ccr.2020.213656 – ident: e_1_2_7_47_3 doi: 10.1002/ange.201901668 – ident: e_1_2_7_40_2 doi: 10.1021/acs.nanolett.1c02379 – ident: e_1_2_7_52_2 doi: 10.1039/D1CC01185E – ident: e_1_2_7_25_3 doi: 10.1002/ange.202001059 – ident: e_1_2_7_49_1 – ident: e_1_2_7_29_2 doi: 10.1021/jacs.5b00832 – ident: e_1_2_7_70_2 doi: 10.1021/jacs.8b11527 – ident: e_1_2_7_68_2 doi: 10.1039/C9CC01745C – ident: e_1_2_7_56_2 doi: 10.1021/jacs.0c02806 – ident: e_1_2_7_2_2 doi: 10.1016/j.ccr.2021.214354 – ident: e_1_2_7_44_2 doi: 10.1002/anie.202013839 – ident: e_1_2_7_58_2 doi: 10.1002/anie.201900429 – ident: e_1_2_7_71_2 doi: 10.1246/cl.190131 – ident: e_1_2_7_69_2 doi: 10.1021/jacs.9b05155 – ident: e_1_2_7_11_2 doi: 10.1021/acs.chemrev.1c00811 – ident: e_1_2_7_31_2 doi: 10.1021/jacs.0c08589 – ident: e_1_2_7_27_2 doi: 10.1002/anie.202003220 – ident: e_1_2_7_43_2 doi: 10.1002/asia.202000744 – ident: e_1_2_7_21_3 doi: 10.1002/ange.202205725 – ident: e_1_2_7_66_2 doi: 10.1016/j.memsci.2021.119354 – ident: e_1_2_7_24_2 doi: 10.1016/j.chempr.2021.07.017 – ident: e_1_2_7_74_3 doi: 10.1002/ange.202013977 – ident: e_1_2_7_39_2 doi: 10.1021/jacs.2c07978 – ident: e_1_2_7_59_2 doi: 10.1038/s41467-018-05818-w – ident: e_1_2_7_1_1 – ident: e_1_2_7_58_3 doi: 10.1002/ange.201900429 – ident: e_1_2_7_19_2 doi: 10.1126/sciadv.1701126 – volume: 2 start-page: 1382 year: 2020 ident: e_1_2_7_55_2 publication-title: CCS Chem. – ident: e_1_2_7_13_3 doi: 10.1002/ange.202104164 – ident: e_1_2_7_76_1 doi: 10.1021/acs.cgd.0c01059 – ident: e_1_2_7_63_2 doi: 10.1002/asia.202100080 – ident: e_1_2_7_37_2 doi: 10.1002/cplu.202200172 – ident: e_1_2_7_50_2 doi: 10.1039/D1SC02883A – ident: e_1_2_7_21_2 doi: 10.1002/anie.202205725 – ident: e_1_2_7_48_2 doi: 10.1021/jacs.8b08030 – ident: e_1_2_7_77_1 – ident: e_1_2_7_18_2 doi: 10.1021/jacs.8b09582 – ident: e_1_2_7_54_2 doi: 10.1021/acsami.0c16366 – ident: e_1_2_7_25_2 doi: 10.1002/anie.202001059 – ident: e_1_2_7_74_2 doi: 10.1002/anie.202013977 – ident: e_1_2_7_61_1 – ident: e_1_2_7_67_2 doi: 10.1039/D0CC01205J – ident: e_1_2_7_72_2 doi: 10.1038/s41586-018-0339-0 – ident: e_1_2_7_4_2 doi: 10.1039/D0CS00038H – ident: e_1_2_7_28_2 doi: 10.1002/anie.201501081 – ident: e_1_2_7_13_2 doi: 10.1002/anie.202104164 – ident: e_1_2_7_45_2 doi: 10.1021/jacs.0c01626 – ident: e_1_2_7_6_2 doi: 10.1021/jacs.9b06222 – ident: e_1_2_7_75_2 doi: 10.1021/jacs.7b09463 – ident: e_1_2_7_46_2 doi: 10.1039/C9SC01892A |
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| Snippet | A chiral metal–organic cage (MOC) was extended and fixed into a porous framework using a post‐assembly modification strategy, which made it easier to study the... A chiral metal-organic cage (MOC) was extended and fixed into a porous framework using a post-assembly modification strategy, which made it easier to study the... |
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| SubjectTerms | Assembly Cages Chiral Cage-Based Frameworks Isomers Post-Assembly Modification Recognition Recognition and Separation Separation Supramolecular compounds Titanium Titanium–Organic Cages |
| Title | Post‐Assembly Modification of Homochiral Titanium–Organic Cages for Recognition and Separation of Molecular Isomers |
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