Fluorinating the Solid Electrolyte Interphase by Rational Molecular Design for Practical Lithium‐Metal Batteries

• Published in: Angewandte Chemie International Edition Vol. 61; no. 29; pp. e202204776 - n/a
• Main Authors: Xie, Jin, Sun, Shu‐Yu, Chen, Xiang, Hou, Li‐Peng, Li, Bo‐Quan, Peng, Hong‐Jie, Huang, Jia‐Qi, Zhang, Xue‐Qiang, Zhang, Qiang
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 18.07.2022; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Anodes; Chemistry; Chemistry, Multidisciplinary; Defluorination; Design; Electrolytes; Fluorinated Electrolytes; Fluorinated Solid Electrolyte Interphase; Fluorination; Interphase; Life span; Lithium; Lithium-Metal Batteries; Metals; Molecular Design; Physical Sciences; Pouch Cells; Principles; Science & Technology; Solid electrolytes; Sulfur; Pouch Cells; CATHODES; Fluorinated Solid Electrolyte Interphase; SULFUR BATTERIES; PERFORMANCE; Fluorinated Electrolytes; LIF; Lithium-Metal Batteries; HIGH-ENERGY-DENSITY; Molecular Design; RECHARGEABLE LITHIUM; CHALLENGES; SOLVENTS; PROGRESS; ANODE

The lifespan of practical lithium (Li)‐metal batteries is severely hindered by the instability of Li‐metal anodes. Fluorinated solid electrolyte interphase (SEI) emerges as a promising strategy to improve the stability of Li‐metal anodes. The rational design of fluorinated molecules is pivotal to co...