A Nuclearity‐Dependent Enantiodivergent Epoxide Opening via Enthalpy‐Controlled Mononuclear and Entropy‐Controlled Dinuclear (Salen)Titanium Catalysis - Li, Shengxiao; Zhu, Hui; Li, Longfei; Chen, Wanjiao; Jiang, Jie; Qu, Zheng‐Wang; Grimme, Stefan; Zhang, Yong‐Qiang (Angewandte Chemie International Edition, 2023)
Keywords: Catalysis; Catalysts; Chemistry; Chemistry, Multidisciplinary; Coordination compounds; Enantiodivergent; Enthalpy; Entropy; Epoxide Opening; Metal complexes; Nuclearity-Dependent; Physical Sciences; Radical; Science & Technology; Self-assembly; Titanium; Titanium Catalysis; ENANTIOSELECTIVITY; Enantiodivergent; CONFORMATIONAL FLEXIBILITY; ASYMMETRIC ADDITION; ZETA-VALENCE QUALITY; Radical; MICHAEL ADDITION; REVERSAL; Nuclearity-Dependent; Titanium Catalysis; BASIS-SETS; METAL; Epoxide Opening; FRIEDEL-CRAFTS REACTION; TRIMETHYLSILYL CYANIDE