Modular Design of Highly Stable Semiconducting Porous Coordination Polymer for Efficient Electrosynthesis of Ammonia

• Published in: Angewandte Chemie International Edition Vol. 63; no. 21; pp. e202401005 - n/a
• Main Authors: Xue, Ziqian, Yao, Ming‐Shui, Otake, Ken‐ichi, Nishiyama, Yusuke, Aoyama, Yoshitaka, Zheng, Jia‐Jia, Zhang, Siquan, Kajiwara, Takashi, Horike, Satoshi, Kitagawa, Susumu
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 21.05.2024
• Edition: International ed. in English
• Subjects: Absorption spectroscopy; Ammonia; Chemical reduction; Columnar structure; Coordination polymers; Electrical conductivity; Electrical resistivity; Electrocatalysts; Electrochemistry; Electron diffraction; Electron transport; Electrosynthesis ammonia; In-situ XAFS; Iron; Metal clusters; Model electrocatalyst; Modular design; Nitrate reduction; Polymers; Porous coordination polymer/Metal–organic framework; Pyrazole; Pyrazoles; Structural stability; Synergistic effect; Model electrocatalyst; Porous coordination polymer/Metal–organic framework; Electrical conductivity; In-situ XAFS; Electrosynthesis ammonia

Developing highly stable porous coordination polymers (PCPs) with integrated electrical conductivity is crucial for advancing our understanding of electrocatalytic mechanisms and the structure–activity relationship of electrocatalysts. However, achieving this goal remains a formidable challenge beca...