Modular Design of Highly Stable Semiconducting Porous Coordination Polymer for Efficient Electrosynthesis of Ammonia - Xue, Ziqian; Yao, Ming‐Shui; Otake, Ken‐ichi; Nishiyama, Yusuke; Aoyama, Yoshitaka; Zheng, Jia‐Jia; Zhang, Siquan; Kajiwara, Takashi; Horike, Satoshi; Kitagawa, Susumu (Angewandte Chemie International Edition, 2024)
Keywords: Absorption spectroscopy; Ammonia; Chemical reduction; Columnar structure; Coordination polymers; Electrical conductivity; Electrical resistivity; Electrocatalysts; Electrochemistry; Electron diffraction; Electron transport; Electrosynthesis ammonia; In-situ XAFS; Iron; Metal clusters; Model electrocatalyst; Modular design; Nitrate reduction; Polymers; Porous coordination polymer/Metal–organic framework; Pyrazole; Pyrazoles; Structural stability; Synergistic effect; Model electrocatalyst; Porous coordination polymer/Metal–organic framework; Electrical conductivity; In-situ XAFS; Electrosynthesis ammonia