Methyl‐Selective α‐Oxygenation of Tertiary Amines to Formamides by Employing Copper/Moderately Hindered Nitroxyl Radical (DMN‐AZADO or 1‐Me‐AZADO) - Nakai, Satoru; Yatabe, Takafumi; Suzuki, Kosuke; Sasano, Yusuke; Iwabuchi, Yoshiharu; Hasegawa, Jun‐ya; Mizuno, Noritaka; Yamaguchi, Kazuya (Angewandte Chemie International Edition, 2019)
Keywords: Amines; Catalysts; Chemical industry; Copper; formamides; methyl-selective α-oxygenation; nitroxyl radical; Oxidizing agents; Oxygen; Oxygenation; Reaction mechanisms; Regioselectivity; Substrates; tertiary amines; tertiary amines; copper; formamides; methyl-selective α-oxygenation; nitroxyl radical