Single‐Atom Iron Catalyst as an Advanced Redox Mediator for Anodic Oxidation of Organic Electrosynthesis

• Published in: Angewandte Chemie International Edition Vol. 63; no. 27; pp. e202404295 - n/a
• Main Authors: Wang, Xin‐Yu, Pan, Yong‐Zhou, Yang, Jiarui, Li, Wen‐Hao, Gan, Tao, Pan, Ying‐Ming, Tang, Hai‐Tao, Wang, Dingsheng
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 01.07.2024; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Amides; Anodizing; Catalysts; Catalytic activity; Chemistry; Chemistry, Multidisciplinary; Electrocatalysts; Electrochemistry; Electron transfer; Indirect oxidation; Iron; Organic compounds; Organic electrosynthesis; Oxidation; Physical Sciences; Pyrolysis; Redox mediator; Science & Technology; Single-atom catalysts; Single-electron transfer; Substrates; FUNCTIONALIZATION; SITE; Single-atom catalysts; PLATINUM; Redox mediator; Organic electrosynthesis; Indirect oxidation; Single-electron transfer; WATER
• ISSN: 1433-7851; 1521-3773; 1521-3773
• DOI: 10.1002/anie.202404295

Homogeneous electrocatalysts can indirect oxidate the high overpotential substrates through single‐electron transfer on the electrode surface, enabling efficient operation of organic electrosynthesis catalytic cycles. However, the problems of this chemistry still exist such as high dosage, difficult...