Regulating Reversible Oxygen Electrocatalysis by Built‐in Electric Field of Heterojunction Electrocatalyst with Modified d‐Band
Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high‐performance electrochemical energy devices. Here, a Mott–Schottky heterojunction composed of porous cobalt–nitrogen–carbon (Co‐N‐C) polyhedra containing abundant metal‐phosphides for reversible oxygen electr...
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| Published in | Small (Weinheim an der Bergstrasse, Germany) Vol. 19; no. 15; pp. e2207474 - n/a |
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| Main Authors | , , , , , , |
| Format | Journal Article |
| Language | English |
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01.04.2023
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| Abstract | Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high‐performance electrochemical energy devices. Here, a Mott–Schottky heterojunction composed of porous cobalt–nitrogen–carbon (Co‐N‐C) polyhedra containing abundant metal‐phosphides for reversible oxygen electrocatalysis is reported. As a demonstration, this catalyst shows excellent activity in the oxygen electrocatalysis and thus delivers outstanding performance in rechargeable zinc‐air batteries (ZABs). The built‐in electric field in the Mott–Schottky heterojunction can promote electron transfer in oxygen electrocatalysis. More importantly, an appropriate d‐band center of the heterojunction catalyst also endows oxygen intermediates with a balanced adsorption/desorption capability, thus enhancing oxygen electrocatalysis and consequently improving the performance of ZABs. The work demonstrates an important design principle for preparing efficient multifunctional catalysts in energy conversion technologies.
The built‐in electric field and modified d‐band of the Mott–Schottky heterojunction electrocatalyst modulate the adsorption/desorption of oxygenate intermediates in reversible oxygen electrocatalysis. |
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| AbstractList | Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high‐performance electrochemical energy devices. Here, a Mott–Schottky heterojunction composed of porous cobalt–nitrogen–carbon (Co‐N‐C) polyhedra containing abundant metal‐phosphides for reversible oxygen electrocatalysis is reported. As a demonstration, this catalyst shows excellent activity in the oxygen electrocatalysis and thus delivers outstanding performance in rechargeable zinc‐air batteries (ZABs). The built‐in electric field in the Mott–Schottky heterojunction can promote electron transfer in oxygen electrocatalysis. More importantly, an appropriate
d
‐band center of the heterojunction catalyst also endows oxygen intermediates with a balanced adsorption/desorption capability, thus enhancing oxygen electrocatalysis and consequently improving the performance of ZABs. The work demonstrates an important design principle for preparing efficient multifunctional catalysts in energy conversion technologies. Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high‐performance electrochemical energy devices. Here, a Mott–Schottky heterojunction composed of porous cobalt–nitrogen–carbon (Co‐N‐C) polyhedra containing abundant metal‐phosphides for reversible oxygen electrocatalysis is reported. As a demonstration, this catalyst shows excellent activity in the oxygen electrocatalysis and thus delivers outstanding performance in rechargeable zinc‐air batteries (ZABs). The built‐in electric field in the Mott–Schottky heterojunction can promote electron transfer in oxygen electrocatalysis. More importantly, an appropriate d‐band center of the heterojunction catalyst also endows oxygen intermediates with a balanced adsorption/desorption capability, thus enhancing oxygen electrocatalysis and consequently improving the performance of ZABs. The work demonstrates an important design principle for preparing efficient multifunctional catalysts in energy conversion technologies. Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high‐performance electrochemical energy devices. Here, a Mott–Schottky heterojunction composed of porous cobalt–nitrogen–carbon (Co‐N‐C) polyhedra containing abundant metal‐phosphides for reversible oxygen electrocatalysis is reported. As a demonstration, this catalyst shows excellent activity in the oxygen electrocatalysis and thus delivers outstanding performance in rechargeable zinc‐air batteries (ZABs). The built‐in electric field in the Mott–Schottky heterojunction can promote electron transfer in oxygen electrocatalysis. More importantly, an appropriate d‐band center of the heterojunction catalyst also endows oxygen intermediates with a balanced adsorption/desorption capability, thus enhancing oxygen electrocatalysis and consequently improving the performance of ZABs. The work demonstrates an important design principle for preparing efficient multifunctional catalysts in energy conversion technologies. The built‐in electric field and modified d‐band of the Mott–Schottky heterojunction electrocatalyst modulate the adsorption/desorption of oxygenate intermediates in reversible oxygen electrocatalysis. Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high-performance electrochemical energy devices. Here, a Mott-Schottky heterojunction composed of porous cobalt-nitrogen-carbon (Co-N-C) polyhedra containing abundant metal-phosphides for reversible oxygen electrocatalysis is reported. As a demonstration, this catalyst shows excellent activity in the oxygen electrocatalysis and thus delivers outstanding performance in rechargeable zinc-air batteries (ZABs). The built-in electric field in the Mott-Schottky heterojunction can promote electron transfer in oxygen electrocatalysis. More importantly, an appropriate d-band center of the heterojunction catalyst also endows oxygen intermediates with a balanced adsorption/desorption capability, thus enhancing oxygen electrocatalysis and consequently improving the performance of ZABs. The work demonstrates an important design principle for preparing efficient multifunctional catalysts in energy conversion technologies.Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high-performance electrochemical energy devices. Here, a Mott-Schottky heterojunction composed of porous cobalt-nitrogen-carbon (Co-N-C) polyhedra containing abundant metal-phosphides for reversible oxygen electrocatalysis is reported. As a demonstration, this catalyst shows excellent activity in the oxygen electrocatalysis and thus delivers outstanding performance in rechargeable zinc-air batteries (ZABs). The built-in electric field in the Mott-Schottky heterojunction can promote electron transfer in oxygen electrocatalysis. More importantly, an appropriate d-band center of the heterojunction catalyst also endows oxygen intermediates with a balanced adsorption/desorption capability, thus enhancing oxygen electrocatalysis and consequently improving the performance of ZABs. The work demonstrates an important design principle for preparing efficient multifunctional catalysts in energy conversion technologies. |
| Author | Xia, Chenfeng Li, Fu‐Min He, Chaohui Guo, Wei Liu, Qingqing Wang, Hongming Xia, Bao Yu |
| Author_xml | – sequence: 1 givenname: Chaohui surname: He fullname: He, Chaohui organization: Huazhong University of Science and Technology (HUST) – sequence: 2 givenname: Qingqing surname: Liu fullname: Liu, Qingqing organization: Huazhong University of Science and Technology (HUST) – sequence: 3 givenname: Hongming surname: Wang fullname: Wang, Hongming organization: Nanchang University – sequence: 4 givenname: Chenfeng surname: Xia fullname: Xia, Chenfeng organization: Huazhong University of Science and Technology (HUST) – sequence: 5 givenname: Fu‐Min surname: Li fullname: Li, Fu‐Min organization: Huazhong University of Science and Technology (HUST) – sequence: 6 givenname: Wei surname: Guo fullname: Guo, Wei email: wguo@hust.edu.cn organization: Huazhong University of Science and Technology (HUST) – sequence: 7 givenname: Bao Yu orcidid: 0000-0002-2054-908X surname: Xia fullname: Xia, Bao Yu email: byxia@hust.edu.cn organization: Huazhong University of Science and Technology (HUST) |
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| Snippet | Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high‐performance electrochemical energy devices. Here, a Mott–Schottky... Developing bifunctional catalysts for oxygen electrochemical reactions is essential for high-performance electrochemical energy devices. Here, a Mott-Schottky... |
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| SubjectTerms | Catalysts Chemical reactions Cobalt d‐band center electric field Electric fields Electrocatalysis Electrocatalysts Electron transfer Energy conversion Heterojunctions Metal air batteries Mott–Schottky heterojunction Nanotechnology Phosphides Rechargeable batteries Zinc-oxygen batteries zinc‐air batteries |
| Title | Regulating Reversible Oxygen Electrocatalysis by Built‐in Electric Field of Heterojunction Electrocatalyst with Modified d‐Band |
| URI | https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fsmll.202207474 https://www.ncbi.nlm.nih.gov/pubmed/36604992 https://www.proquest.com/docview/2799939073 https://www.proquest.com/docview/2761975232 |
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