Selective Hydrodeoxygenation of Lignin‐Derived Phenolic Monomers to Cyclohexanol over Tungstated Zirconia Supported Ruthenium Catalysts
The selective hydrodeoxygenation (HDO) of lignin‐derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion since cyclohexanol is an important industrial raw material. This study has disclosed a series of tungstated zirconia with different Zr/W ratio s...
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| Published in | ChemSusChem Vol. 17; no. 23; pp. e202400644 - n/a |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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06.12.2024
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| Abstract | The selective hydrodeoxygenation (HDO) of lignin‐derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion since cyclohexanol is an important industrial raw material. This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation (HDO) of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity, which can achieve 92 % yield of cyclohexanol under the conditions of 180 °C and 1 MPa H2 pressure for 2 h (TOF 231 h−1). Compared with Ru/ZrO2, Ru/16ZrW has smaller particles, more dispersed and electron‐rich Ru species, significant hydrogen spillover and more acid sites, which are the main reason for its excellent performance on this reaction. Apart from guaiacol, other methoxy substitution phenols and organosolv lignin can also be converted into cyclohexanol via hydrodeoxygenation reactions over this catalyst.
This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity. Compared with Ru/ZrO2, Ru/16ZrW has smaller particles, more dispersed and electron‐rich Ru species, significant hydrogen spillover and more acid sites. |
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| AbstractList | The selective hydrodeoxygenation (HDO) of lignin‐derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion since cyclohexanol is an important industrial raw material. This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation (HDO) of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity, which can achieve 92 % yield of cyclohexanol under the conditions of 180 °C and 1 MPa H
2
pressure for 2 h (TOF 231 h
−1
). Compared with Ru/ZrO
2
, Ru/16ZrW has smaller particles, more dispersed and electron‐rich Ru species, significant hydrogen spillover and more acid sites, which are the main reason for its excellent performance on this reaction. Apart from guaiacol, other methoxy substitution phenols and organosolv lignin can also be converted into cyclohexanol
via
hydrodeoxygenation reactions over this catalyst. The selective hydrodeoxygenation (HDO) of lignin-derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion since cyclohexanol is an important industrial raw material. This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation (HDO) of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity, which can achieve 92 % yield of cyclohexanol under the conditions of 180 °C and 1 MPa H pressure for 2 h (TOF 231 h ). Compared with Ru/ZrO , Ru/16ZrW has smaller particles, more dispersed and electron-rich Ru species, significant hydrogen spillover and more acid sites, which are the main reason for its excellent performance on this reaction. Apart from guaiacol, other methoxy substitution phenols and organosolv lignin can also be converted into cyclohexanol via hydrodeoxygenation reactions over this catalyst. The selective hydrodeoxygenation (HDO) of lignin‐derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion since cyclohexanol is an important industrial raw material. This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation (HDO) of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity, which can achieve 92 % yield of cyclohexanol under the conditions of 180 °C and 1 MPa H2 pressure for 2 h (TOF 231 h−1). Compared with Ru/ZrO2, Ru/16ZrW has smaller particles, more dispersed and electron‐rich Ru species, significant hydrogen spillover and more acid sites, which are the main reason for its excellent performance on this reaction. Apart from guaiacol, other methoxy substitution phenols and organosolv lignin can also be converted into cyclohexanol via hydrodeoxygenation reactions over this catalyst. This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity. Compared with Ru/ZrO2, Ru/16ZrW has smaller particles, more dispersed and electron‐rich Ru species, significant hydrogen spillover and more acid sites. The selective hydrodeoxygenation (HDO) of lignin‐derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion since cyclohexanol is an important industrial raw material. This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation (HDO) of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity, which can achieve 92 % yield of cyclohexanol under the conditions of 180 °C and 1 MPa H2 pressure for 2 h (TOF 231 h−1). Compared with Ru/ZrO2, Ru/16ZrW has smaller particles, more dispersed and electron‐rich Ru species, significant hydrogen spillover and more acid sites, which are the main reason for its excellent performance on this reaction. Apart from guaiacol, other methoxy substitution phenols and organosolv lignin can also be converted into cyclohexanol via hydrodeoxygenation reactions over this catalyst. The selective hydrodeoxygenation (HDO) of lignin-derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion since cyclohexanol is an important industrial raw material. This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation (HDO) of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity, which can achieve 92 % yield of cyclohexanol under the conditions of 180 °C and 1 MPa H2 pressure for 2 h (TOF 231 h-1). Compared with Ru/ZrO2, Ru/16ZrW has smaller particles, more dispersed and electron-rich Ru species, significant hydrogen spillover and more acid sites, which are the main reason for its excellent performance on this reaction. Apart from guaiacol, other methoxy substitution phenols and organosolv lignin can also be converted into cyclohexanol via hydrodeoxygenation reactions over this catalyst.The selective hydrodeoxygenation (HDO) of lignin-derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion since cyclohexanol is an important industrial raw material. This study has disclosed a series of tungstated zirconia with different Zr/W ratio supported Ru catalysts (Ru/xZrW, x means the molar ration of Zr/W) for the hydrodeoxygenation (HDO) of guaiacol to cyclohexanol. Among these catalysts, Ru/16ZrW has the best catalytic activity, which can achieve 92 % yield of cyclohexanol under the conditions of 180 °C and 1 MPa H2 pressure for 2 h (TOF 231 h-1). Compared with Ru/ZrO2, Ru/16ZrW has smaller particles, more dispersed and electron-rich Ru species, significant hydrogen spillover and more acid sites, which are the main reason for its excellent performance on this reaction. Apart from guaiacol, other methoxy substitution phenols and organosolv lignin can also be converted into cyclohexanol via hydrodeoxygenation reactions over this catalyst. |
| Author | Gan, Quan Lu, Guo‐Ping Lin, Yamei Zhang, Xueping Huang, Shenlin Zhou, Weihao |
| Author_xml | – sequence: 1 givenname: Quan surname: Gan fullname: Gan, Quan organization: Nanjing University of Science and Technology – sequence: 2 givenname: Weihao surname: Zhou fullname: Zhou, Weihao organization: Nanjing University of Science and Technology – sequence: 3 givenname: Xueping surname: Zhang fullname: Zhang, Xueping organization: Nanjing University of Science and Technology – sequence: 4 givenname: Yamei surname: Lin fullname: Lin, Yamei organization: Nanjing Normal University – sequence: 5 givenname: Shenlin surname: Huang fullname: Huang, Shenlin organization: Nanjing Forestry University – sequence: 6 givenname: Guo‐Ping orcidid: 0000-0003-4476-964X surname: Lu fullname: Lu, Guo‐Ping email: glu@njust.edu.cn organization: Nanjing Forestry University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38923356$$D View this record in MEDLINE/PubMed |
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| Keywords | lignin-derived phenols Ruthenium Hydrodeoxygenation Cyclohexanol |
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| Snippet | The selective hydrodeoxygenation (HDO) of lignin‐derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion... The selective hydrodeoxygenation (HDO) of lignin-derived methoxyphenols to cyclohexanol is one of the most significant transformation in biomass conversion... |
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| SubjectTerms | Catalysis Catalysts Catalytic activity Cyclohexanol Hydrodeoxygenation Lignin lignin-derived phenols Phenols Raw materials Ruthenium Substitution reactions Zirconium dioxide |
| Title | Selective Hydrodeoxygenation of Lignin‐Derived Phenolic Monomers to Cyclohexanol over Tungstated Zirconia Supported Ruthenium Catalysts |
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