Fine Pore‐Structure Engineering by Ligand Conformational Control of Naphthalene Diimide‐Based Semiconducting Porous Coordination Polymers for Efficient Chemiresistive Gas Sensing

• Published in: Angewandte Chemie International Edition Vol. 62; no. 2; pp. e202215234 - n/a
• Main Authors: Xue, Ziqian, Zheng, Jia‐Jia, Nishiyama, Yusuke, Yao, Ming‐Shui, Aoyama, Yoshitaka, Fan, Zeyu, Wang, Ping, Kajiwara, Takashi, Kubota, Yoshiki, Horike, Satoshi, Otake, Ken‐ichi, Kitagawa, Susumu
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 09.01.2023
• Edition: International ed. in English
• Subjects: 3D electron diffraction (3D ED); Charge transfer; Conductivity; Conformation; Coordination polymers; Diimide; Electron diffraction; Gas sensors; Ligands; Naphthalene; NDI; PCPs/MOFs; Polymers; Selectivity; Semiconductors; Sensors; Space charge; Stacking; 3D electron diffraction (3D ED); NDI; PCPs/MOFs; Sensors; Semiconductors

Exploring new porous coordination polymers (PCPs) that have tunable structure and conductivity is attractive but remains challenging. Herein, fine pore structure engineering by ligand conformation control of naphthalene diimide (NDI)‐based semiconducting PCPs with π stacking‐dependent conductivity t...