Silver‐Templated γ‐Keggin Alkyltin‐Oxo Cluster: Electronic Structure and Optical Limiting Effect

• Published in: Angewandte Chemie International Edition Vol. 61; no. 27; pp. e202202853 - n/a
• Main Authors: Zhu, Yu, Wang, Zirui, Li, Dejing, Zhu, Yin‐Di, Li, Qiao‐Hong, Li, Dong‐Sheng, Zhang, Lei
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 04.07.2022
• Edition: International ed. in English
• Subjects: Clusters; Constraining; Electron transfer; Electronic Structure; Keggin Structures; Molecular orbitals; Noble metals; Nonlinear optics; Optical Limiting; Optical properties; Polyoxometallates; Silver; Tin-Oxo Clusters; Electronic Structure; Silver; Tin-Oxo Clusters; Keggin Structures; Optical Limiting

As one of the most representative polyoxometalate (POM) structures, Keggin clusters have attracted considerable attention. Nevertheless, the noble‐metal‐templated Keggin structure has not been reported to date. In this work, for the first time, a Ag atom was successfully incorporated to template the...