Construction of Benzoxazine‐linked One‐Dimensional Covalent Organic Frameworks Using the Mannich Reaction

• Published in: Angewandte Chemie International Edition Vol. 63; no. 33; pp. e202403473 - n/a
• Main Authors: Cheng, Cheng, Liu, Yikuan, Sheng, Guan, Jiang, Xinru, Kang, Xing, Jiang, Chao, Liu, Yan, Zhu, Yihan, Cui, Yong
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 12.08.2024; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Aldehydes; Alkylation; Asymmetric catalysis; Benzoxazine; Benzoxazines; Catalysts; Chemistry; Chemistry, Multidisciplinary; Condensation polymerization; Covalence; Covalent organic frameworks; Electrical properties; Electron microscopy; Mannich reaction; Materials synthesis; Optical properties; Organic chemistry; Physical Sciences; Polymers; Science & Technology; Stoichiometry; Benzoxazine; Covalent organic frameworks; TOPOLOGY; CATALYSIS; POLYMERS; DESIGN; NANOSHEETS; ADSORPTION; Asymmetric catalysis; Materials synthesis; SINGLE-CRYSTAL; Mannich reaction; CHEMISTRY; SEPARATION

Covalent polymerization of organic molecules into crystalline one‐dimensional (1D) polymers is effective for achieving desired thermal, optical, and electrical properties, yet it remains a persistent synthetic challenge for their inherent tendency to adopt amorphous or semicrystalline phases. Here w...