A Tailored Versatile and Efficient NHC‐Based NNC‐Pincer Manganese Catalyst for Hydrogenation of Polar Unsaturated Compounds

• Published in: Angewandte Chemie International Edition Vol. 62; no. 23; pp. e202301042 - n/a
• Main Authors: Wei, Zeyuan, Li, Hengxu, Wang, Yujie, Liu, Qiang
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 05.06.2023
• Edition: International ed. in English
• Subjects: Amides; Carbonates; Catalysts; Catalytic Hydrogenation; Energy levels; Esters; Hydrides; Hydrogenation; Ligand Design; Manganese; Manganese Catalysis; Metal Hydride; N-Heterocyclic Carbene; Phosphine; Phosphines; Steric hindrance; Urea; Metal Hydride; Manganese Catalysis; Ligand Design; Catalytic Hydrogenation; N-Heterocyclic Carbene

The reactivity of metal‐hydride complexes can be harnessed by the modification of ancillary ligands. With the aim of improving the hydride‐donor ability of the key Mn−H intermediate and reducing steric hindrance, we herein report the rational design of a versatile and efficient NHC‐based NNC‐pincer...