Dual‐Intermetallic Heterostructure on Hierarchical Nanoporous Metal for Highly Efficient Alkaline Hydrogen Electrocatalysis

Constructing well‐defined active multisites is an effective strategy to break linear scaling relationships to develop high‐efficiency catalysts toward multiple‐intermediate reactions. Here, dual‐intermetallic heterostructure composed of tungsten‐bridged Co3W and WNi4 intermetallic compounds seamless...

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Published inAdvanced materials (Weinheim) Vol. 36; no. 38; pp. e2406711 - n/a
Main Authors Shi, Hang, Dai, Tian‐Yi, Sun, Xin‐Ying, Zhou, Zhi‐Lan, Zeng, Shu‐Pei, Wang, Tong‐Hui, Han, Gao‐Feng, Wen, Zi, Fang, Qian‐Rong, Lang, Xing‐You, Jiang, Qing
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 01.09.2024
Subjects
Current density
Electrocatalysis
Electrocatalysts
Electrolytic cells
Fuel cells
Heterostructures
Hydrogen
hydrogen evolution reaction
Hydrogen evolution reactions
hydrogen oxidation reaction
Hydrogen production
Intermetallic compounds
intermetallic heterostructure
multisite electrocatalysts
nanoporous metal
Nickel
Oxidation
Platinum metals
Tungsten
intermetallic heterostructure
nanoporous metal
hydrogen oxidation reaction
multisite electrocatalysts
hydrogen evolution reaction
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Abstract Constructing well‐defined active multisites is an effective strategy to break linear scaling relationships to develop high‐efficiency catalysts toward multiple‐intermediate reactions. Here, dual‐intermetallic heterostructure composed of tungsten‐bridged Co3W and WNi4 intermetallic compounds seamlessly integrated on hierarchical nanoporous nickel skeleton is reported as a high‐performance nonprecious electrocatalyst for alkaline hydrogen evolution and oxidation reactions. By virtue of interfacial tungsten atoms configuring contiguous multisites with proper adsorptions of hydrogen and hydroxyl intermediates to accelerate water dissociation/combination and column‐nanostructured nickel skeleton facilitating electron and ion/molecule transportations, nanoporous nickel‐supported Co3W–WNi4 heterostructure exhibits exceptional hydrogen electrocatalysis in alkaline media, with outstanding durability and impressive catalytic activities for hydrogen oxidation reaction (geometric exchange current density of ≈6.62 mA cm−2) and hydrogen evolution reaction (current density of ≈1.45 A cm−2 at overpotential of 200 mV). Such atom‐ordered intermetallic heterostructure alternative to platinum group metals shows genuine potential for hydrogen production and utilization in hydroxide‐exchange‐membrane water electrolyzers and fuel cells. Dual‐intermetallic heterostructure composed of tungsten‐bridged Co3W and WNi4 intermetallic compounds seamlessly integrated on nanoporous Ni skeleton exhibits exceptional activities and durability for hydrogen evolution and oxidation reactions. Such dual‐intermetallic heterostructure enables interfacial atoms to configure multisites to accelerate water dissociation/combination, demonstrating the feasibility to construct well‐defined active multisites for multiple‐intermediate reactions based on intermetallic compounds.
AbstractList Constructing well‐defined active multisites is an effective strategy to break linear scaling relationships to develop high‐efficiency catalysts toward multiple‐intermediate reactions. Here, dual‐intermetallic heterostructure composed of tungsten‐bridged Co3W and WNi4 intermetallic compounds seamlessly integrated on hierarchical nanoporous nickel skeleton is reported as a high‐performance nonprecious electrocatalyst for alkaline hydrogen evolution and oxidation reactions. By virtue of interfacial tungsten atoms configuring contiguous multisites with proper adsorptions of hydrogen and hydroxyl intermediates to accelerate water dissociation/combination and column‐nanostructured nickel skeleton facilitating electron and ion/molecule transportations, nanoporous nickel‐supported Co3W–WNi4 heterostructure exhibits exceptional hydrogen electrocatalysis in alkaline media, with outstanding durability and impressive catalytic activities for hydrogen oxidation reaction (geometric exchange current density of ≈6.62 mA cm−2) and hydrogen evolution reaction (current density of ≈1.45 A cm−2 at overpotential of 200 mV). Such atom‐ordered intermetallic heterostructure alternative to platinum group metals shows genuine potential for hydrogen production and utilization in hydroxide‐exchange‐membrane water electrolyzers and fuel cells.
Constructing well-defined active multisites is an effective strategy to break linear scaling relationships to develop high-efficiency catalysts toward multiple-intermediate reactions. Here, dual-intermetallic heterostructure composed of tungsten-bridged Co W and WNi intermetallic compounds seamlessly integrated on hierarchical nanoporous nickel skeleton is reported as a high-performance nonprecious electrocatalyst for alkaline hydrogen evolution and oxidation reactions. By virtue of interfacial tungsten atoms configuring contiguous multisites with proper adsorptions of hydrogen and hydroxyl intermediates to accelerate water dissociation/combination and column-nanostructured nickel skeleton facilitating electron and ion/molecule transportations, nanoporous nickel-supported Co W-WNi heterostructure exhibits exceptional hydrogen electrocatalysis in alkaline media, with outstanding durability and impressive catalytic activities for hydrogen oxidation reaction (geometric exchange current density of ≈6.62 mA cm ) and hydrogen evolution reaction (current density of ≈1.45 A cm at overpotential of 200 mV). Such atom-ordered intermetallic heterostructure alternative to platinum group metals shows genuine potential for hydrogen production and utilization in hydroxide-exchange-membrane water electrolyzers and fuel cells.
Constructing well-defined active multisites is an effective strategy to break linear scaling relationships to develop high-efficiency catalysts toward multiple-intermediate reactions. Here, dual-intermetallic heterostructure composed of tungsten-bridged Co3W and WNi4 intermetallic compounds seamlessly integrated on hierarchical nanoporous nickel skeleton is reported as a high-performance nonprecious electrocatalyst for alkaline hydrogen evolution and oxidation reactions. By virtue of interfacial tungsten atoms configuring contiguous multisites with proper adsorptions of hydrogen and hydroxyl intermediates to accelerate water dissociation/combination and column-nanostructured nickel skeleton facilitating electron and ion/molecule transportations, nanoporous nickel-supported Co3W-WNi4 heterostructure exhibits exceptional hydrogen electrocatalysis in alkaline media, with outstanding durability and impressive catalytic activities for hydrogen oxidation reaction (geometric exchange current density of ≈6.62 mA cm-2) and hydrogen evolution reaction (current density of ≈1.45 A cm-2 at overpotential of 200 mV). Such atom-ordered intermetallic heterostructure alternative to platinum group metals shows genuine potential for hydrogen production and utilization in hydroxide-exchange-membrane water electrolyzers and fuel cells.Constructing well-defined active multisites is an effective strategy to break linear scaling relationships to develop high-efficiency catalysts toward multiple-intermediate reactions. Here, dual-intermetallic heterostructure composed of tungsten-bridged Co3W and WNi4 intermetallic compounds seamlessly integrated on hierarchical nanoporous nickel skeleton is reported as a high-performance nonprecious electrocatalyst for alkaline hydrogen evolution and oxidation reactions. By virtue of interfacial tungsten atoms configuring contiguous multisites with proper adsorptions of hydrogen and hydroxyl intermediates to accelerate water dissociation/combination and column-nanostructured nickel skeleton facilitating electron and ion/molecule transportations, nanoporous nickel-supported Co3W-WNi4 heterostructure exhibits exceptional hydrogen electrocatalysis in alkaline media, with outstanding durability and impressive catalytic activities for hydrogen oxidation reaction (geometric exchange current density of ≈6.62 mA cm-2) and hydrogen evolution reaction (current density of ≈1.45 A cm-2 at overpotential of 200 mV). Such atom-ordered intermetallic heterostructure alternative to platinum group metals shows genuine potential for hydrogen production and utilization in hydroxide-exchange-membrane water electrolyzers and fuel cells.
Constructing well‐defined active multisites is an effective strategy to break linear scaling relationships to develop high‐efficiency catalysts toward multiple‐intermediate reactions. Here, dual‐intermetallic heterostructure composed of tungsten‐bridged Co 3 W and WNi 4 intermetallic compounds seamlessly integrated on hierarchical nanoporous nickel skeleton is reported as a high‐performance nonprecious electrocatalyst for alkaline hydrogen evolution and oxidation reactions. By virtue of interfacial tungsten atoms configuring contiguous multisites with proper adsorptions of hydrogen and hydroxyl intermediates to accelerate water dissociation/combination and column‐nanostructured nickel skeleton facilitating electron and ion/molecule transportations, nanoporous nickel‐supported Co 3 W–WNi 4 heterostructure exhibits exceptional hydrogen electrocatalysis in alkaline media, with outstanding durability and impressive catalytic activities for hydrogen oxidation reaction (geometric exchange current density of ≈6.62 mA cm −2 ) and hydrogen evolution reaction (current density of ≈1.45 A cm −2 at overpotential of 200 mV). Such atom‐ordered intermetallic heterostructure alternative to platinum group metals shows genuine potential for hydrogen production and utilization in hydroxide‐exchange‐membrane water electrolyzers and fuel cells.
Constructing well‐defined active multisites is an effective strategy to break linear scaling relationships to develop high‐efficiency catalysts toward multiple‐intermediate reactions. Here, dual‐intermetallic heterostructure composed of tungsten‐bridged Co3W and WNi4 intermetallic compounds seamlessly integrated on hierarchical nanoporous nickel skeleton is reported as a high‐performance nonprecious electrocatalyst for alkaline hydrogen evolution and oxidation reactions. By virtue of interfacial tungsten atoms configuring contiguous multisites with proper adsorptions of hydrogen and hydroxyl intermediates to accelerate water dissociation/combination and column‐nanostructured nickel skeleton facilitating electron and ion/molecule transportations, nanoporous nickel‐supported Co3W–WNi4 heterostructure exhibits exceptional hydrogen electrocatalysis in alkaline media, with outstanding durability and impressive catalytic activities for hydrogen oxidation reaction (geometric exchange current density of ≈6.62 mA cm−2) and hydrogen evolution reaction (current density of ≈1.45 A cm−2 at overpotential of 200 mV). Such atom‐ordered intermetallic heterostructure alternative to platinum group metals shows genuine potential for hydrogen production and utilization in hydroxide‐exchange‐membrane water electrolyzers and fuel cells. Dual‐intermetallic heterostructure composed of tungsten‐bridged Co3W and WNi4 intermetallic compounds seamlessly integrated on nanoporous Ni skeleton exhibits exceptional activities and durability for hydrogen evolution and oxidation reactions. Such dual‐intermetallic heterostructure enables interfacial atoms to configure multisites to accelerate water dissociation/combination, demonstrating the feasibility to construct well‐defined active multisites for multiple‐intermediate reactions based on intermetallic compounds.
Author Wang, Tong‐Hui
Fang, Qian‐Rong
Han, Gao‐Feng
Lang, Xing‐You
Dai, Tian‐Yi
Shi, Hang
Sun, Xin‐Ying
Wen, Zi
Jiang, Qing
Zeng, Shu‐Pei
Zhou, Zhi‐Lan
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  fullname: Jiang, Qing
  email: jiangq@jlu.edu.cn
  organization: Jilin University
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Keywords intermetallic heterostructure
nanoporous metal
hydrogen oxidation reaction
multisite electrocatalysts
hydrogen evolution reaction
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Snippet Constructing well‐defined active multisites is an effective strategy to break linear scaling relationships to develop high‐efficiency catalysts toward...
Constructing well-defined active multisites is an effective strategy to break linear scaling relationships to develop high-efficiency catalysts toward...
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StartPage e2406711
SubjectTerms Current density
Electrocatalysis
Electrocatalysts
Electrolytic cells
Fuel cells
Heterostructures
Hydrogen
hydrogen evolution reaction
Hydrogen evolution reactions
hydrogen oxidation reaction
Hydrogen production
Intermetallic compounds
intermetallic heterostructure
multisite electrocatalysts
nanoporous metal
Nickel
Oxidation
Platinum metals
Tungsten
Title Dual‐Intermetallic Heterostructure on Hierarchical Nanoporous Metal for Highly Efficient Alkaline Hydrogen Electrocatalysis
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fadma.202406711
https://www.ncbi.nlm.nih.gov/pubmed/39046064
https://www.proquest.com/docview/3112450931
https://www.proquest.com/docview/3084028642
Volume 36
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