Bimetallic Nanoalloy Catalysts for Green Energy Production: Advances in Synthesis Routes and Characterization Techniques

Bimetallic Nanoalloy catalysts have diverse uses in clean energy, sensing, catalysis, biomedicine, and energy storage, with some supported and unsupported catalysts. Conventional synthetic methods for producing bimetallic alloy nanoparticles often produce unalloyed and bulky particles that do not ex...

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Published inSmall (Weinheim an der Bergstrasse, Germany) Vol. 19; no. 43; pp. e2303031 - n/a
Main Authors Ashraf, Saima, Liu, Yanyan, Wei, Huijuan, Shen, Ruofan, Zhang, Huanhuan, Wu, Xianli, Mehdi, Sehrish, Liu, Tao, Li, Baojun
Format Journal Article
LanguageEnglish
Published Germany Wiley Subscription Services, Inc 01.10.2023
Subjects
Alloys
bimetallic nanoalloy
Bimetals
Catalysis
catalyst
Catalysts
Chemical reduction
Clean energy
Energy storage
High entropy alloys
hydrogen evolution reaction (HER)
Hydrogen evolution reactions
Nanoalloys
Nanoparticles
Nanotechnology
Oxidation
oxygen evolution reaction (OER)
Oxygen evolution reactions
oxygen reduction reaction (ORR)
Palladium
Production methods
Redox reactions
Renewable energy
Synthesis
hydrogen evolution reaction (HER)
nanoparticles
catalyst
oxygen evolution reaction (OER)
oxygen reduction reaction (ORR)
bimetallic nanoalloy
Online AccessGet full text
ISSN1613-6810
1613-6829
1613-6829
DOI10.1002/smll.202303031

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Abstract Bimetallic Nanoalloy catalysts have diverse uses in clean energy, sensing, catalysis, biomedicine, and energy storage, with some supported and unsupported catalysts. Conventional synthetic methods for producing bimetallic alloy nanoparticles often produce unalloyed and bulky particles that do not exhibit desired characteristics. Alloys, when prepared with advanced nanoscale methods, give higher surface area, activity, and selectivity than individual metals due to changes in their electronic properties and reduced size. This review demonstrates the synthesis methods and principles to produce and characterize highly dispersed, well‐alloyed bimetallic nanoalloy particles in relatively simple, effective, and generalized approaches and the overall existence of conventional synthetic methods with modifications to prepare bimetallic alloy catalysts. The basic concepts and mechanistic understanding are represented with purposely selected examples. Herein, the enthralling properties with widespread applications of nanoalloy catalysts in heterogeneous catalysis are also presented, especially for Hydrogen Evolution Reaction (HER), Oxidation Reduction Reaction (ORR), Oxygen Evolution Reaction (OER), and alcohol oxidation with a particular focus on Pt and Pd‐based bimetallic nanoalloys and their numerous fields of applications. The high entropy alloy is described as a complicated subject with an emphasis on laser‐based green synthesis of nanoparticles and, in conclusion, the forecasts and contemporary challenges for the controlled synthesis of nanoalloys are addressed. Bimetallic Nanoalloys catalysts are strikingly popular for green energy production and storage. Synthetic methods such as chemical reduction, vapor deposition, pyrolysis, laser ablation, etc., can improve the alloy catalytic activity for hydrogen evolution reactions, oxygen reduction reactions, oxygen evolution reactions, and alcohol oxidation reactions. In combination with transition and other metals, Nobel metals can create highly efficient electrocatalysts.
AbstractList Bimetallic Nanoalloy catalysts have diverse uses in clean energy, sensing, catalysis, biomedicine, and energy storage, with some supported and unsupported catalysts. Conventional synthetic methods for producing bimetallic alloy nanoparticles often produce unalloyed and bulky particles that do not exhibit desired characteristics. Alloys, when prepared with advanced nanoscale methods, give higher surface area, activity, and selectivity than individual metals due to changes in their electronic properties and reduced size. This review demonstrates the synthesis methods and principles to produce and characterize highly dispersed, well‐alloyed bimetallic nanoalloy particles in relatively simple, effective, and generalized approaches and the overall existence of conventional synthetic methods with modifications to prepare bimetallic alloy catalysts. The basic concepts and mechanistic understanding are represented with purposely selected examples. Herein, the enthralling properties with widespread applications of nanoalloy catalysts in heterogeneous catalysis are also presented, especially for Hydrogen Evolution Reaction (HER), Oxidation Reduction Reaction (ORR), Oxygen Evolution Reaction (OER), and alcohol oxidation with a particular focus on Pt and Pd‐based bimetallic nanoalloys and their numerous fields of applications. The high entropy alloy is described as a complicated subject with an emphasis on laser‐based green synthesis of nanoparticles and, in conclusion, the forecasts and contemporary challenges for the controlled synthesis of nanoalloys are addressed. Bimetallic Nanoalloys catalysts are strikingly popular for green energy production and storage. Synthetic methods such as chemical reduction, vapor deposition, pyrolysis, laser ablation, etc., can improve the alloy catalytic activity for hydrogen evolution reactions, oxygen reduction reactions, oxygen evolution reactions, and alcohol oxidation reactions. In combination with transition and other metals, Nobel metals can create highly efficient electrocatalysts.
Bimetallic Nanoalloy catalysts have diverse uses in clean energy, sensing, catalysis, biomedicine, and energy storage, with some supported and unsupported catalysts. Conventional synthetic methods for producing bimetallic alloy nanoparticles often produce unalloyed and bulky particles that do not exhibit desired characteristics. Alloys, when prepared with advanced nanoscale methods, give higher surface area, activity, and selectivity than individual metals due to changes in their electronic properties and reduced size. This review demonstrates the synthesis methods and principles to produce and characterize highly dispersed, well‐alloyed bimetallic nanoalloy particles in relatively simple, effective, and generalized approaches and the overall existence of conventional synthetic methods with modifications to prepare bimetallic alloy catalysts. The basic concepts and mechanistic understanding are represented with purposely selected examples. Herein, the enthralling properties with widespread applications of nanoalloy catalysts in heterogeneous catalysis are also presented, especially for Hydrogen Evolution Reaction (HER), Oxidation Reduction Reaction (ORR), Oxygen Evolution Reaction (OER), and alcohol oxidation with a particular focus on Pt and Pd‐based bimetallic nanoalloys and their numerous fields of applications. The high entropy alloy is described as a complicated subject with an emphasis on laser‐based green synthesis of nanoparticles and, in conclusion, the forecasts and contemporary challenges for the controlled synthesis of nanoalloys are addressed.
Bimetallic Nanoalloy catalysts have diverse uses in clean energy, sensing, catalysis, biomedicine, and energy storage, with some supported and unsupported catalysts. Conventional synthetic methods for producing bimetallic alloy nanoparticles often produce unalloyed and bulky particles that do not exhibit desired characteristics. Alloys, when prepared with advanced nanoscale methods, give higher surface area, activity, and selectivity than individual metals due to changes in their electronic properties and reduced size. This review demonstrates the synthesis methods and principles to produce and characterize highly dispersed, well-alloyed bimetallic nanoalloy particles in relatively simple, effective, and generalized approaches and the overall existence of conventional synthetic methods with modifications to prepare bimetallic alloy catalysts. The basic concepts and mechanistic understanding are represented with purposely selected examples. Herein, the enthralling properties with widespread applications of nanoalloy catalysts in heterogeneous catalysis are also presented, especially for Hydrogen Evolution Reaction (HER), Oxidation Reduction Reaction (ORR), Oxygen Evolution Reaction (OER), and alcohol oxidation with a particular focus on Pt and Pd-based bimetallic nanoalloys and their numerous fields of applications. The high entropy alloy is described as a complicated subject with an emphasis on laser-based green synthesis of nanoparticles and, in conclusion, the forecasts and contemporary challenges for the controlled synthesis of nanoalloys are addressed.Bimetallic Nanoalloy catalysts have diverse uses in clean energy, sensing, catalysis, biomedicine, and energy storage, with some supported and unsupported catalysts. Conventional synthetic methods for producing bimetallic alloy nanoparticles often produce unalloyed and bulky particles that do not exhibit desired characteristics. Alloys, when prepared with advanced nanoscale methods, give higher surface area, activity, and selectivity than individual metals due to changes in their electronic properties and reduced size. This review demonstrates the synthesis methods and principles to produce and characterize highly dispersed, well-alloyed bimetallic nanoalloy particles in relatively simple, effective, and generalized approaches and the overall existence of conventional synthetic methods with modifications to prepare bimetallic alloy catalysts. The basic concepts and mechanistic understanding are represented with purposely selected examples. Herein, the enthralling properties with widespread applications of nanoalloy catalysts in heterogeneous catalysis are also presented, especially for Hydrogen Evolution Reaction (HER), Oxidation Reduction Reaction (ORR), Oxygen Evolution Reaction (OER), and alcohol oxidation with a particular focus on Pt and Pd-based bimetallic nanoalloys and their numerous fields of applications. The high entropy alloy is described as a complicated subject with an emphasis on laser-based green synthesis of nanoparticles and, in conclusion, the forecasts and contemporary challenges for the controlled synthesis of nanoalloys are addressed.
Author Li, Baojun
Mehdi, Sehrish
Wei, Huijuan
Shen, Ruofan
Wu, Xianli
Ashraf, Saima
Liu, Yanyan
Liu, Tao
Zhang, Huanhuan
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  organization: Tsinghua University
BackLink https://www.ncbi.nlm.nih.gov/pubmed/37356067$$D View this record in MEDLINE/PubMed
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Keywords hydrogen evolution reaction (HER)
nanoparticles
catalyst
oxygen evolution reaction (OER)
oxygen reduction reaction (ORR)
bimetallic nanoalloy
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Snippet Bimetallic Nanoalloy catalysts have diverse uses in clean energy, sensing, catalysis, biomedicine, and energy storage, with some supported and unsupported...
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wiley
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StartPage e2303031
SubjectTerms Alloys
bimetallic nanoalloy
Bimetals
Catalysis
catalyst
Catalysts
Chemical reduction
Clean energy
Energy storage
High entropy alloys
hydrogen evolution reaction (HER)
Hydrogen evolution reactions
Nanoalloys
Nanoparticles
Nanotechnology
Oxidation
oxygen evolution reaction (OER)
Oxygen evolution reactions
oxygen reduction reaction (ORR)
Palladium
Production methods
Redox reactions
Renewable energy
Synthesis
Title Bimetallic Nanoalloy Catalysts for Green Energy Production: Advances in Synthesis Routes and Characterization Techniques
URI https://onlinelibrary.wiley.com/doi/abs/10.1002%2Fsmll.202303031
https://www.ncbi.nlm.nih.gov/pubmed/37356067
https://www.proquest.com/docview/2881086340
https://www.proquest.com/docview/2829704887
Volume 19
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