Asymmetric α‐Allylation of Glycinate with Switched Chemoselectivity Enabled by Customized Bifunctional Pyridoxal Catalysts - Ma, Jiguo; Gao, Bin; Song, Guanshui; Zhang, Ruixin; Wang, Qingfang; Ye, Zi; Chen, Wen‐Wen; Zhao, Baoguo (Angewandte Chemie International Edition, 2022)
Keywords: Acetates; Acetic acid; Allyl compounds; Allylic Substitution; Amides; Biomimetic Catalysis; Carbonyl Catalysis; Catalysis; Catalysts; Chemical reactions; Chemistry; Chemistry, Multidisciplinary; Esters; Glutamic acid; Intermediates; Organocatalysis; Physical Sciences; Pyridoxal; Science & Technology; Stereoisomerism; Stereoselectivity; Vitamin B6; Vitamin B-6; ACTIVATED ALLYLIC ACETATES; Allylic Substitution; CONJUGATE ADDITION-ELIMINATION; ALDEHYDE CATALYSIS; Organocatalysis; GLUTAMIC-ACID DERIVATIVES; ENANTIOSELECTIVE CONSTRUCTION; Carbonyl Catalysis; BIOMIMETIC TRANSAMINATION; DIPHOSPHINE LIGANDS; AMINO-ACIDS; SYNERGISTIC CU/PD CATALYSIS; BAYLIS-HILLMAN CARBONATES; Biomimetic Catalysis; Vitamin B6