Post‐synthetic Rhodium (III) Complexes in Covalent Organic Frameworks for Photothermal Heterogeneous C−H Activation

• Published in: Angewandte Chemie International Edition Vol. 63; no. 14; pp. e202318180 - n/a
• Main Authors: Li, Teng, Zhang, Pei‐Lin, Dong, Long‐Zhang, Lan, Ya‐Qian
• Format: Journal Article
• Language: English
• Published: WEINHEIM Wiley 02.04.2024; Wiley Subscription Services, Inc
• Edition: International ed. in English
• Subjects: Catalysts; Chemical reactions; Chemistry; Chemistry, Multidisciplinary; C−H Activation; Heterogeneous; Hydrogen bonds; Photosensitivity; Photothermal Catalysis; Photothermal conversion; Physical Sciences; Porous materials; Post-synthetic COFs; Recyclability; Rh Complex; Rhodium; Room temperature; Science & Technology; Substrates; Temperature requirements; THIN-FILMS; Heterogeneous; SOLAR-CELLS; C-H Activation; PERFORMANCE; PEROVSKITE; Photothermal Catalysis; Post-synthetic COFs; EFFICIENT; Rh Complex; PBI2; LEAD; C−H Activation

Although photocatalytic C−H activation has been realized by using heterogeneous catalysts, most of them require high‐temperature conditions to provide the energy required for C−H bond breakage. The catalysts with photothermal conversion properties can catalyze this reaction efficiently at room tempe...