Sub‐Nanometer Mono‐Layered Metal–Organic Frameworks Nanosheets for Simulated Flue Gas Photoreduction
The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono‐layered structure for advanced photo‐catalysis applications. Here, a kind of sub‐nanometer mono‐layered nanosheets (Co‐MOF MNSs) through the exfoliation of specifically designed...
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| Published in | Advanced materials (Weinheim) Vol. 36; no. 27; pp. e2403920 - n/a |
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| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
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01.07.2024
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| Abstract | The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono‐layered structure for advanced photo‐catalysis applications. Here, a kind of sub‐nanometer mono‐layered nanosheets (Co‐MOF MNSs) through the exfoliation of specifically designed Co3 cluster‐based metal–organic frameworks (MOFs) is reported. The sub‐nanometer thickness and inherent light‐sensitivity endow Co‐MOF MNSs with fully exposed Janus Co3 sites that can selectively photo‐reduce CO2 into formic acid under simulated flue gas. Notably, the production efficiency of formic acid by Co‐MOF MNSs (0.85 mmol g−1 h−1) is ≈13 times higher than that of the bulk counterpart (0.065 mmol g−1 h−1) under a simulated flue gas atmosphere, which is the highest in reported works up to date. Theoretical calculations prove that the exposed Janus Co3 sites with simultaneously available sites possess higher activity when compared with single Co site, validating the importance of mono‐layered nanosheet morphology. These results may facilitate the development of functional nanosheet materials for CO2 photo‐reduction in potential flue gas treatment.
A kind of sub‐nanometer mono‐layered nanosheets (Co‐MOF MNSs) is successfully prepared with remarkable performance in selective CO2 photo‐reduction into formic acid under simulated flue gas. |
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| AbstractList | The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono-layered structure for advanced photo-catalysis applications. Here, we report a kind of sub-nanometer mono-layered nanosheets (Co-MOF MNSs) through the exfoliation of a specifically designed Co
cluster-based metal-organic frameworks (MOFs). The sub-nanometer thickness and inherent light-sensitivity endow Co-MOF MNSs with fully exposed Janus Co
sites that can selectively photo-reduce CO
into formic acid under simulated flue gas. Notably, the production efficiency of formic acid by Co-MOF MNSs (0.85 mmol g
h
) is ∼13 times higher than that of bulk counterpart (0.065 mmol g
h
) under simulated flue gas atmosphere, which is highest in reported works up to date. Theoretical calculations prove that the exposed Janus Co
sites with simultaneously available sites possess higher activity when compared with single Co site, validating the importance of mono-layered nanosheet morphology. Our results might facilitate the development of functional nanosheet materials for CO
photo-reduction in potential flue gas treatment. This article is protected by copyright. All rights reserved. The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono‐layered structure for advanced photo‐catalysis applications. Here, a kind of sub‐nanometer mono‐layered nanosheets (Co‐MOF MNSs) through the exfoliation of specifically designed Co3 cluster‐based metal–organic frameworks (MOFs) is reported. The sub‐nanometer thickness and inherent light‐sensitivity endow Co‐MOF MNSs with fully exposed Janus Co3 sites that can selectively photo‐reduce CO2 into formic acid under simulated flue gas. Notably, the production efficiency of formic acid by Co‐MOF MNSs (0.85 mmol g−1 h−1) is ≈13 times higher than that of the bulk counterpart (0.065 mmol g−1 h−1) under a simulated flue gas atmosphere, which is the highest in reported works up to date. Theoretical calculations prove that the exposed Janus Co3 sites with simultaneously available sites possess higher activity when compared with single Co site, validating the importance of mono‐layered nanosheet morphology. These results may facilitate the development of functional nanosheet materials for CO2 photo‐reduction in potential flue gas treatment. A kind of sub‐nanometer mono‐layered nanosheets (Co‐MOF MNSs) is successfully prepared with remarkable performance in selective CO2 photo‐reduction into formic acid under simulated flue gas. The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono-layered structure for advanced photo-catalysis applications. Here, a kind of sub-nanometer mono-layered nanosheets (Co-MOF MNSs) through the exfoliation of specifically designed Co3 cluster-based metal-organic frameworks (MOFs) is reported. The sub-nanometer thickness and inherent light-sensitivity endow Co-MOF MNSs with fully exposed Janus Co3 sites that can selectively photo-reduce CO2 into formic acid under simulated flue gas. Notably, the production efficiency of formic acid by Co-MOF MNSs (0.85 mmol g-1 h-1) is ≈13 times higher than that of the bulk counterpart (0.065 mmol g-1 h-1) under a simulated flue gas atmosphere, which is the highest in reported works up to date. Theoretical calculations prove that the exposed Janus Co3 sites with simultaneously available sites possess higher activity when compared with single Co site, validating the importance of mono-layered nanosheet morphology. These results may facilitate the development of functional nanosheet materials for CO2 photo-reduction in potential flue gas treatment.The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono-layered structure for advanced photo-catalysis applications. Here, a kind of sub-nanometer mono-layered nanosheets (Co-MOF MNSs) through the exfoliation of specifically designed Co3 cluster-based metal-organic frameworks (MOFs) is reported. The sub-nanometer thickness and inherent light-sensitivity endow Co-MOF MNSs with fully exposed Janus Co3 sites that can selectively photo-reduce CO2 into formic acid under simulated flue gas. Notably, the production efficiency of formic acid by Co-MOF MNSs (0.85 mmol g-1 h-1) is ≈13 times higher than that of the bulk counterpart (0.065 mmol g-1 h-1) under a simulated flue gas atmosphere, which is the highest in reported works up to date. Theoretical calculations prove that the exposed Janus Co3 sites with simultaneously available sites possess higher activity when compared with single Co site, validating the importance of mono-layered nanosheet morphology. These results may facilitate the development of functional nanosheet materials for CO2 photo-reduction in potential flue gas treatment. The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono‐layered structure for advanced photo‐catalysis applications. Here, a kind of sub‐nanometer mono‐layered nanosheets (Co‐MOF MNSs) through the exfoliation of specifically designed Co3 cluster‐based metal–organic frameworks (MOFs) is reported. The sub‐nanometer thickness and inherent light‐sensitivity endow Co‐MOF MNSs with fully exposed Janus Co3 sites that can selectively photo‐reduce CO2 into formic acid under simulated flue gas. Notably, the production efficiency of formic acid by Co‐MOF MNSs (0.85 mmol g−1 h−1) is ≈13 times higher than that of the bulk counterpart (0.065 mmol g−1 h−1) under a simulated flue gas atmosphere, which is the highest in reported works up to date. Theoretical calculations prove that the exposed Janus Co3 sites with simultaneously available sites possess higher activity when compared with single Co site, validating the importance of mono‐layered nanosheet morphology. These results may facilitate the development of functional nanosheet materials for CO2 photo‐reduction in potential flue gas treatment. The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono‐layered structure for advanced photo‐catalysis applications. Here, a kind of sub‐nanometer mono‐layered nanosheets (Co‐MOF MNSs) through the exfoliation of specifically designed Co 3 cluster‐based metal–organic frameworks (MOFs) is reported. The sub‐nanometer thickness and inherent light‐sensitivity endow Co‐MOF MNSs with fully exposed Janus Co 3 sites that can selectively photo‐reduce CO 2 into formic acid under simulated flue gas. Notably, the production efficiency of formic acid by Co‐MOF MNSs (0.85 mmol g −1 h −1 ) is ≈13 times higher than that of the bulk counterpart (0.065 mmol g −1 h −1 ) under a simulated flue gas atmosphere, which is the highest in reported works up to date. Theoretical calculations prove that the exposed Janus Co 3 sites with simultaneously available sites possess higher activity when compared with single Co site, validating the importance of mono‐layered nanosheet morphology. These results may facilitate the development of functional nanosheet materials for CO 2 photo‐reduction in potential flue gas treatment. |
| Author | Li, Qiang Chen, Yifa Rong, Yan He, Dong Xin, Zhifeng Wang, Qian Shen, Kejing Liu, Jing‐Jing |
| Author_xml | – sequence: 1 givenname: Dong surname: He fullname: He, Dong organization: Anhui University of Technology – sequence: 2 givenname: Qian surname: Wang fullname: Wang, Qian organization: Anhui University of Technology – sequence: 3 givenname: Yan surname: Rong fullname: Rong, Yan organization: Anhui University of Technology – sequence: 4 givenname: Zhifeng surname: Xin fullname: Xin, Zhifeng email: xinzf521@ahut.edu.cn organization: Anhui University of Technology – sequence: 5 givenname: Jing‐Jing surname: Liu fullname: Liu, Jing‐Jing organization: South China Normal University – sequence: 6 givenname: Qiang surname: Li fullname: Li, Qiang email: qiang.li@seu.edu.cn organization: Southeast University – sequence: 7 givenname: Kejing surname: Shen fullname: Shen, Kejing organization: Anhui University of Technology – sequence: 8 givenname: Yifa orcidid: 0000-0002-1718-6871 surname: Chen fullname: Chen, Yifa email: 20200698@m.scnu.edu.cn organization: South China Normal University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38635463$$D View this record in MEDLINE/PubMed |
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| Keywords | Mono‐layered nanosheet CO2 photo‐reduction Flue gas Formic acid |
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| Snippet | The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono‐layered structure for advanced... The dilemma between the thickness and accessible active site triggers the design of porous crystalline materials with mono-layered structure for advanced... |
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| SubjectTerms | Carbon dioxide CO2 photo‐reduction Flue gas Formic acid Metal-organic frameworks mono‐layered nanosheets Nanosheets Porous materials Thickness |
| Title | Sub‐Nanometer Mono‐Layered Metal–Organic Frameworks Nanosheets for Simulated Flue Gas Photoreduction |
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