Triheteropolyanions containing copper(II), manganese(II), or manganese(III)
Triheteropolyanions XZW 11O 40H 2 n− ( x = B, Zn, P, Si, Ge; Z = Cu II , Mn II , Mn III ), XZMo 11O 40H 2 n− ( X = P, Si, Ge; Z = Mn II, Cu II), and X 2′CuW 17O 62H 2 8− ( X′ = P, As) are reported. All anions are degraded slowly by base; acid attack on the Cu II and Mn II anions is rapid, but the ve...
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Published in | Journal of inorganic & nuclear chemistry Vol. 32; no. 12; pp. 3875 - 3890 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Elsevier B.V
01.01.1970
|
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Abstract | Triheteropolyanions
XZW
11O
40H
2
n−
(
x = B, Zn, P, Si, Ge;
Z = Cu
II
,
Mn
II
,
Mn
III
),
XZMo
11O
40H
2
n−
(
X = P, Si, Ge;
Z = Mn
II, Cu
II), and
X
2′CuW
17O
62H
2
8− (
X′ = P, As) are reported. All anions are degraded slowly by base; acid attack on the Cu
II and Mn
II anions is rapid, but the very stable free acids of the
XMn
III
W
11O
40H
2
n−
anions can be prepared. The molybdates are much less stable than the tungstates. The manganese complexes are high-spin; all salts are magnetically dilute. The Mn(II) complexes show metal-to-ligand charge-transfer bands in the near u.v. The Mn(III) 20,000 cm
−1 ligand-field bands show structure which cannot be satisfactorily explained. The Mn(III)/Mn(II) redox potentials range from +0·43 V to +0·88 V. |
---|---|
AbstractList | Triheteropolyanions
XZW
11O
40H
2
n−
(
x = B, Zn, P, Si, Ge;
Z = Cu
II
,
Mn
II
,
Mn
III
),
XZMo
11O
40H
2
n−
(
X = P, Si, Ge;
Z = Mn
II, Cu
II), and
X
2′CuW
17O
62H
2
8− (
X′ = P, As) are reported. All anions are degraded slowly by base; acid attack on the Cu
II and Mn
II anions is rapid, but the very stable free acids of the
XMn
III
W
11O
40H
2
n−
anions can be prepared. The molybdates are much less stable than the tungstates. The manganese complexes are high-spin; all salts are magnetically dilute. The Mn(II) complexes show metal-to-ligand charge-transfer bands in the near u.v. The Mn(III) 20,000 cm
−1 ligand-field bands show structure which cannot be satisfactorily explained. The Mn(III)/Mn(II) redox potentials range from +0·43 V to +0·88 V. |
Author | Tourné, Gilbert F. Tourné, Claude M. Malik, S.A. Weakley, T.J.R. |
Author_xml | – sequence: 1 givenname: Claude M. surname: Tourné fullname: Tourné, Claude M. – sequence: 2 givenname: Gilbert F. surname: Tourné fullname: Tourné, Gilbert F. – sequence: 3 givenname: S.A. surname: Malik fullname: Malik, S.A. – sequence: 4 givenname: T.J.R. surname: Weakley fullname: Weakley, T.J.R. |
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Cites_doi | 10.1021/ja00962a052 10.1021/ja00704a014 10.1016/0022-1902(70)80526-7 10.1002/zaac.19683580109 10.1002/zaac.18930040112 10.1039/j19670000442 10.1039/j19680002647 10.1039/jr9610003796 10.1021/ic50068a007 10.1016/0022-1902(67)80126-X 10.1016/0022-1902(66)80324-X 10.1039/j19690000301 10.1002/9780470166079.ch2 10.1002/zaac.19663470516 |
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Snippet | Triheteropolyanions
XZW
11O
40H
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x = B, Zn, P, Si, Ge;
Z = Cu
II
,
Mn
II
,
Mn
III
),
XZMo
11O
40H
2
n−
(
X = P, Si, Ge;
Z = Mn
II, Cu
II), and
X
2′CuW... |
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Title | Triheteropolyanions containing copper(II), manganese(II), or manganese(III) |
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