Saturated Ti-coordinated {001} facets-dependent photocatalytic water reduction over NH2-MIL-125(Ti) sheets: Observation and unraveling of facets effect

• Published in: Applied catalysis. B, Environmental Vol. 338; p. 123094
• Main Authors: Liu, Lifang, Du, Shiwen, Xiao, Yejun, Guo, Xiangyang, Jin, Shengye, Shao, Guosheng, Zhang, Fuxiang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 05.12.2023
• Subjects: Charge separation; Hydrogen; Metal–organic frameworks; Photocatalyst; Water splitting; Water splitting; Hydrogen; Photocatalyst; Metal–organic frameworks; Charge separation

Facets-dependent photocatalytic H2 evolution rates of inorganic semiconductors have been well recognized, but it remains unclear for metal-organic frameworks (MOFs). Herein, we controllably prepared a series of NH2-MIL-125(Ti) MOF sheets with different ratios of {001}/{111} facets exposure, on which...