Achieving superb strength in single-phase FCC alloys via maximizing volume misfit

[Display omitted] •Single-phase binary FCC alloy with superb strength is designed through volume-misfit-maximization-strategy.•The targeted Ni80Mo20 exhibits a yield strength of ∼1.05 GPa while maintaining ∼40% elongation.•Unprecedented volume misfit brings a highest-ever Hall-Petch coefficient (103...

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Published inMaterials today (Kidlington, England) Vol. 63; pp. 108 - 119
Main Authors Li, Zhongtao, Ma, Shihua, Zhao, Shijun, Zhang, Weidong, Peng, Fei, Li, Qian, Yang, Tao, Wu, Chia-Yi, Wei, Daixiu, Chou, Yi-Chia, Liaw, Peter K., Gao, Yanfei, Wu, Zhenggang
Format Journal Article
LanguageEnglish
Published Elsevier Ltd 01.03.2023
Subjects
Grain-boundary strengthening
Mechanical properties
Single-phase face-centered cubic alloys
Solid-solution strengthening
Volume misfit
Mechanical properties
Grain-boundary strengthening
Solid-solution strengthening
Volume misfit
Single-phase face-centered cubic alloys
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Abstract [Display omitted] •Single-phase binary FCC alloy with superb strength is designed through volume-misfit-maximization-strategy.•The targeted Ni80Mo20 exhibits a yield strength of ∼1.05 GPa while maintaining ∼40% elongation.•Unprecedented volume misfit brings a highest-ever Hall-Petch coefficient (1034 MPa·μm1/2) and a pronounced solid solution strengthening (224 MPa).•Volume misfit is a good pertinent indicator of kHP.•Screw dislocations can control the strengthening in SP-FCC alloys. Single-phase face-centered cubic (SP-FCC) alloys normally possess low strength. Conventionally strengthening strategies inevitably cause significant ductility sacrifice. Here, a single-phase Ni-based FCC alloy with a superb yield strength of ∼1.05GPa and a good ductility of 37% is designed through maximizing the volume misfits. The misfit of the purposely targeted Ni80Mo20 alloy is severer than all existing FCC alloys, bringing the alloy a highest-ever Hall-Petch coefficient (kHP = 1034 MPa·μm1/2) and a pronounced solid solution strengthening (Δσss = 224 MPa). Current work yields two surprising and novel findings for SP-FCC alloys. First, volume misfit is a good pertinent indicator of kHP. Second, the conventional impression about the sole contribution of edge dislocations to strengthening in SP-FCC alloys may no longer hold; instead, screw dislocations can also kick in once the nonsphericity of the solute-induced stress field reaches a critical value. Altogether, this work paves a new avenue of pursuing ultimate strengthening without significant ductility sacrifice for SP-FCC alloys relying on the volume-misfit-maximization strategy.
AbstractList [Display omitted] •Single-phase binary FCC alloy with superb strength is designed through volume-misfit-maximization-strategy.•The targeted Ni80Mo20 exhibits a yield strength of ∼1.05 GPa while maintaining ∼40% elongation.•Unprecedented volume misfit brings a highest-ever Hall-Petch coefficient (1034 MPa·μm1/2) and a pronounced solid solution strengthening (224 MPa).•Volume misfit is a good pertinent indicator of kHP.•Screw dislocations can control the strengthening in SP-FCC alloys. Single-phase face-centered cubic (SP-FCC) alloys normally possess low strength. Conventionally strengthening strategies inevitably cause significant ductility sacrifice. Here, a single-phase Ni-based FCC alloy with a superb yield strength of ∼1.05GPa and a good ductility of 37% is designed through maximizing the volume misfits. The misfit of the purposely targeted Ni80Mo20 alloy is severer than all existing FCC alloys, bringing the alloy a highest-ever Hall-Petch coefficient (kHP = 1034 MPa·μm1/2) and a pronounced solid solution strengthening (Δσss = 224 MPa). Current work yields two surprising and novel findings for SP-FCC alloys. First, volume misfit is a good pertinent indicator of kHP. Second, the conventional impression about the sole contribution of edge dislocations to strengthening in SP-FCC alloys may no longer hold; instead, screw dislocations can also kick in once the nonsphericity of the solute-induced stress field reaches a critical value. Altogether, this work paves a new avenue of pursuing ultimate strengthening without significant ductility sacrifice for SP-FCC alloys relying on the volume-misfit-maximization strategy.
Author Yang, Tao
Ma, Shihua
Li, Zhongtao
Peng, Fei
Wu, Chia-Yi
Li, Qian
Chou, Yi-Chia
Zhang, Weidong
Liaw, Peter K.
Wu, Zhenggang
Wei, Daixiu
Zhao, Shijun
Gao, Yanfei
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  organization: Department of Electrophysics, National Yang Ming Chiao Tung University, Hsinchu 30010, Taiwan
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  surname: Wei
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  organization: Department of Materials Science and Engineering, The University of Tennessee, Knoxville, TN 37996-2100, USA
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  email: zwu9@hnu.edu.cn
  organization: College of Materials Science and Engineering, Hunan University, Changsha 410082, China
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Keywords Mechanical properties
Grain-boundary strengthening
Solid-solution strengthening
Volume misfit
Single-phase face-centered cubic alloys
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Snippet [Display omitted] •Single-phase binary FCC alloy with superb strength is designed through volume-misfit-maximization-strategy.•The targeted Ni80Mo20 exhibits a...
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SubjectTerms Grain-boundary strengthening
Mechanical properties
Single-phase face-centered cubic alloys
Solid-solution strengthening
Volume misfit
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Title Achieving superb strength in single-phase FCC alloys via maximizing volume misfit
URI https://dx.doi.org/10.1016/j.mattod.2023.02.012
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