Designing nanostructured Si anodes for high energy lithium ion batteries

• Published in: Nano today Vol. 7; no. 5; pp. 414 - 429
• Main Authors: Wu, Hui, Cui, Yi
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.10.2012
• Subjects: Anodes; Electrochemistry; Lithium ion battery; Si nanostructures; Solid electrolyte interphase; Electrochemistry; Lithium ion battery; Solid electrolyte interphase; Si nanostructures; Anodes
• ISSN: 1748-0132; 1878-044X
• DOI: 10.1016/j.nantod.2012.08.004

Si electrode failure mechanisms: (a) Material pulverization. (b) Continuous SEI growth. (c) Morphology and volume change of the entire Si electrode. [Display omitted] ► We reviewed recent research progress on Si based high performance anode for lithium ion batteries. ► We reviewed the fundamental challenges associated with large volume change in Si anode. ► Nanostructured materials design can significantly improve the cycling life of Si anode. ► The nanoscale design principles can also be extended to other battery materials that undergo large volume changes. High energy lithium ion batteries are in demand for consumer electronics, electric-drive vehicles and grid-scale stationary energy storage. Si is of great interest since it has 10 times higher specific capacity than traditional carbon anodes. However, the poor cyclability due to the large volume change of Si upon insertion and extraction of lithium has been an impediment to its deployment. This review outlines three fundamental materials challenges associated with large volume change, and then shows how nanostructured materials design can successfully address these challenges. There have been three generations of nanostructure design, encompassing solid nanostructures such as nanowires, hollow nanostructures, and clamped hollow structures. The nanoscale design principles developed for Si can also be extended to other battery materials that undergo large volume changes.