Phase transformation of the brownmillerite SrCoO2.5 thin film through alkaline water electrolysis
A phase transformation from insulating brownmillerite SrCoO 2.5 to conducting perovskite SrCoO 3 through electrochemical oxidation has been demonstrated for thin films of SrCoOx on a SrTiO 3 (001) substrate. The cobalt-oxide film strongly favors the brownmillerite phase of SrCoO 2.5 instead of the p...
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Published in | Journal of the Korean Physical Society Vol. 64; no. 12; pp. 1845 - 1848 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
Seoul
The Korean Physical Society
01.06.2014
한국물리학회 |
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Abstract | A phase transformation from insulating brownmillerite SrCoO
2.5
to conducting perovskite SrCoO
3
through electrochemical oxidation has been demonstrated for thin films of SrCoOx on a SrTiO
3
(001) substrate. The cobalt-oxide film strongly favors the brownmillerite phase of SrCoO
2.5
instead of the perovskite phase of SrCoO
3
on a SrTiO
3
(001) substrate due to its low lattice mismatch. Therefore, the phase transformation has its own retention. The alkaline water electrolysis occurs between the copper cathode and the SrCoO
2.5
film anode. The H
+
ions are attracted to the cathode and generate H
2
gas. The OH
−
ions are attracted to the film’s surface and generate a rich amount of oxygen to fill the oxygen vacancy channel of brownmillerite SrCoO
2.5
. The phase transformation was verified from the change in the out-of-plane lattice constant and the change in the resistivity of the electrolyzed film. |
---|---|
AbstractList | A phase transformation from insulating brownmillerite SrCoO
2.5
to conducting perovskite SrCoO
3
through electrochemical oxidation has been demonstrated for thin films of SrCoOx on a SrTiO
3
(001) substrate. The cobalt-oxide film strongly favors the brownmillerite phase of SrCoO
2.5
instead of the perovskite phase of SrCoO
3
on a SrTiO
3
(001) substrate due to its low lattice mismatch. Therefore, the phase transformation has its own retention. The alkaline water electrolysis occurs between the copper cathode and the SrCoO
2.5
film anode. The H
+
ions are attracted to the cathode and generate H
2
gas. The OH
−
ions are attracted to the film’s surface and generate a rich amount of oxygen to fill the oxygen vacancy channel of brownmillerite SrCoO
2.5
. The phase transformation was verified from the change in the out-of-plane lattice constant and the change in the resistivity of the electrolyzed film. A phase transformation from insulating brownmillerite SrCoO2.5 to conducting perovskiteSrCoO3 through electrochemical oxidation has been demonstrated for thin films of SrCoOx on aSrTiO3 (001) substrate. The cobalt-oxide film strongly favors the brownmillerite phase of SrCoO2.5instead of the perovskite phase of SrCoO3 on a SrTiO3 (001) substrate due to its low lattice mismatch. Therefore, the phase transformation has its own retention. The alkaline water electrolysisoccurs between the copper cathode and the SrCoO2.5 film anode. The H+ ions are attracted tothe cathode and generate H2 gas. The OH− ions are attracted to the film’s surface and generatea rich amount of oxygen to fill the oxygen vacancy channel of brownmillerite SrCoO2.5. The phasetransformation was verified from the change in the out-of-plane lattice constant and the change inthe resistivity of the electrolyzed film. KCI Citation Count: 11 |
Author | Kim, Deok Hyeon Lee, Min Young Parwanta, Kadek Juliana Jung, Chang Uk Tambunan, Octolia Togibasa |
Author_xml | – sequence: 1 givenname: Octolia Togibasa surname: Tambunan fullname: Tambunan, Octolia Togibasa organization: Department of Physics, Hankuk University of Foreign Studies – sequence: 2 givenname: Min Young surname: Lee fullname: Lee, Min Young organization: Department of Physics, Hankuk University of Foreign Studies – sequence: 3 givenname: Deok Hyeon surname: Kim fullname: Kim, Deok Hyeon organization: Department of Physics, Hankuk University of Foreign Studies – sequence: 4 givenname: Kadek Juliana surname: Parwanta fullname: Parwanta, Kadek Juliana organization: Department of Physics, Hankuk University of Foreign Studies – sequence: 5 givenname: Chang Uk surname: Jung fullname: Jung, Chang Uk email: cu-jung@hufs.ac.kr organization: Department of Physics, Hankuk University of Foreign Studies |
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Cites_doi | 10.1021/ja063207m 10.1016/S0360-3199(97)00109-2 10.1016/S0957-4158(99)00066-5 10.1063/1.1695195 10.1038/430620a 10.1039/c2dt30317e 10.1002/adma.201300531 10.1038/ncomms1112 10.1103/PhysRevB.78.054404 10.1088/0953-8984/23/24/245601 10.1149/1.2086682 10.1038/nmat3736 10.1063/1.2375014 10.1021/cm950504+ 10.4283/JMAG.2008.13.2.061 |
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Keywords | Phase transformation Water electrolysis Brownmillerite SrCoO Thin film |
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Snippet | A phase transformation from insulating brownmillerite SrCoO
2.5
to conducting perovskite SrCoO
3
through electrochemical oxidation has been demonstrated for... A phase transformation from insulating brownmillerite SrCoO2.5 to conducting perovskiteSrCoO3 through electrochemical oxidation has been demonstrated for thin... |
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SubjectTerms | Mathematical and Computational Physics Particle and Nuclear Physics Physics Physics and Astronomy Theoretical 물리학 |
Title | Phase transformation of the brownmillerite SrCoO2.5 thin film through alkaline water electrolysis |
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