Chromatographic methods in determination of the soil-water partition coefficient

The soil-water partition coefficient normalized to the soil organic carbon content (K OC ) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water ma...

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Published inJournal of liquid chromatography & related technologies Vol. 39; no. 5-6; pp. 249 - 256
Main Authors Andric, Filip, S;egan, Sandra, Tesic, Zivoslav, Milojkovic-Opsenica, Dusanka
Format Journal Article
LanguageEnglish
Published Abingdon Taylor & Francis 02.04.2016
Taylor & Francis Ltd
Subjects
Assessments
Chromatography
Coefficients
Environmental assessment
High-performance liquid chromatography
Ions
Liquid chromatography
Markets
Moisture content
Organic carbon
Organic chemicals
Organic chemistry
Partitions
Soil (material)
soil thin-layer chromatography
Soil water
soil-column chromatography
soil-water partition coefficient (K
thin-layer chromatography
Wastewater management
Water management
Online AccessGet full text
ISSN1082-6076
1520-572X
DOI10.1080/10826076.2016.1163173

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Abstract The soil-water partition coefficient normalized to the soil organic carbon content (K OC ) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K OC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K OC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.
AbstractList The soil-water partition coefficient normalized to the soil organic carbon content (KOC) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of KOC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of KOC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.
The soil-water partition coefficient normalized to the soil organic carbon content (K sub(OC)) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K sub(OC) based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K sub(OC) values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.
The soil-water partition coefficient normalized to the soil organic carbon content (K OC ) is one of essential properties governing the fate of organic chemicals in the soil-water compartment. It is a parameter of utmost importance when it comes to the removal of toxic organics in the waste water management facilities or placing a new chemical on the market. Since direct determination of K OC based on tests involving soil-sorption measurements are expensive, time-consuming, tedious, and subject to different experimental difficulties and artifacts, different alternative methods have been developed for rapid indirect experimental determination and estimation of K OC values. In the scope of the present work, we provide critical and historical overview of development and application of the main chromatographic methods, both high-performance liquid chromatography and thin-layer chromatographic techniques for indirect experimental determination of the soil-water partition coefficient as well as mobility assessment of environmentally important compounds in the soil. Chromatographic methods proved to be promising in this field, which is clearly demonstrated by their implementation in official guidelines for testing the chemicals.
Author Andrić, Filip
Šegan, Sandra
Tešić, Živoslav
Milojković-Opsenica, Dušanka
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crossref_primary_10_3390_pharmaceutics15041172
crossref_primary_10_1080_10826076_2017_1298024
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Snippet The soil-water partition coefficient normalized to the soil organic carbon content (K OC ) is one of essential properties governing the fate of organic...
The soil-water partition coefficient normalized to the soil organic carbon content (KOC) is one of essential properties governing the fate of organic chemicals...
The soil-water partition coefficient normalized to the soil organic carbon content (K sub(OC)) is one of essential properties governing the fate of organic...
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SubjectTerms Assessments
Chromatography
Coefficients
Environmental assessment
High-performance liquid chromatography
Ions
Liquid chromatography
Markets
Moisture content
Organic carbon
Organic chemicals
Organic chemistry
Partitions
Soil (material)
soil thin-layer chromatography
Soil water
soil-column chromatography
soil-water partition coefficient (K
thin-layer chromatography
Wastewater management
Water management
Title Chromatographic methods in determination of the soil-water partition coefficient
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