Preparation of MCM-41 with high structural stability

MCM-41 molecular sieves with high structural stability and long-range order were synthesized using ethylamine (EA) as an additive instead of mineralizers such as NaOH and TPAOH. X-ray diffraction showed that the EA/CTAB (cetyltrimethylammonium bromide) ratio was the critical factor that determines t...

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Published inCeramics international Vol. 30; no. 6; pp. 817 - 822
Main Authors Lee, Hyoung-Ho, Ahn, Ji-Whan, Kim, Hwan
Format Journal Article
LanguageEnglish
Published Kidlington Elsevier Ltd 2004
Elsevier Science
Subjects
A. Sol–gel processes
B. Porosity
Chemistry
Colloidal state and disperse state
D. Silicate
Exact sciences and technology
General and physical chemistry
MCM-41
Porous materials
A. Sol–gel processes
B. Porosity
D. Silicate
MCM-41
Quaternary ammonium compound
High resolution
Transmission electron microscopy
Stability
Sol gel process
Preparation
Cationic surfactant
Porosity
Silicates
Small angle X ray scattering
Molecular sieve
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Abstract MCM-41 molecular sieves with high structural stability and long-range order were synthesized using ethylamine (EA) as an additive instead of mineralizers such as NaOH and TPAOH. X-ray diffraction showed that the EA/CTAB (cetyltrimethylammonium bromide) ratio was the critical factor that determines the degree of ordering in MCM-41, and an EA/CTAB ratio of 0.2 or 0.5 produced the highest long-range order. The samples had walls approximately 2 nm thick, which is the highest level ever reported. Therefore, they did not lose their structure entirely even after heat treatment at 1000 °C. Together with the effect of the EA/CTAB ratio, the textural mesoporosity, as confirmed from the N 2 adsorption–desorption isotherm analysis, suggests the EA participates in the templating process of the mesostructure.
AbstractList MCM-41 molecular sieves with high structural stability and long-range order were synthesised using ethylamine (EA) as an additive instead of mineralisers such as NaOH and TPAOH. XRD showed that the EA/CTAB (cetyltrimethylammonium bromide) ratio was the critical factor that determines the degree of ordering in MCM-41, and an EA/CTAB ratio of 0.2 or 0.5 produced the highest long-range order. The samples had walls approximately 2 nm thick, which is the highest level ever reported. Therefore, they did not lose their structure entirely even after heat treatment at 1000 C. Together with the effect of the EA/CTAB ratio, the textural mesoporosity, as confirmed from the N2 adsorption-desorption isotherm analysis, suggests the EA participates in the templating process of the mesostructure. 15 refs.
MCM-41 molecular sieves with high structural stability and long-range order were synthesized using ethylamine (EA) as an additive instead of mineralizers such as NaOH and TPAOH. X-ray diffraction showed that the EA/CTAB (cetyltrimethylammonium bromide) ratio was the critical factor that determines the degree of ordering in MCM-41, and an EA/CTAB ratio of 0.2 or 0.5 produced the highest long-range order. The samples had walls approximately 2 nm thick, which is the highest level ever reported. Therefore, they did not lose their structure entirely even after heat treatment at 1000 °C. Together with the effect of the EA/CTAB ratio, the textural mesoporosity, as confirmed from the N 2 adsorption–desorption isotherm analysis, suggests the EA participates in the templating process of the mesostructure.
Author Ahn, Ji-Whan
Lee, Hyoung-Ho
Kim, Hwan
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  email: hwan94@snu.ac.kr
  organization: School of Materials Science and Engineering, Seoul National University, Seoul 151-742, South Korea
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10.1021/cm950549a
10.1038/39549
10.1016/S1387-1811(99)00137-7
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Keywords A. Sol–gel processes
B. Porosity
D. Silicate
MCM-41
Quaternary ammonium compound
High resolution
Transmission electron microscopy
Stability
Sol gel process
Preparation
Cationic surfactant
Porosity
Silicates
Small angle X ray scattering
Molecular sieve
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Snippet MCM-41 molecular sieves with high structural stability and long-range order were synthesized using ethylamine (EA) as an additive instead of mineralizers such...
MCM-41 molecular sieves with high structural stability and long-range order were synthesised using ethylamine (EA) as an additive instead of mineralisers such...
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SubjectTerms A. Sol–gel processes
B. Porosity
Chemistry
Colloidal state and disperse state
D. Silicate
Exact sciences and technology
General and physical chemistry
MCM-41
Porous materials
Title Preparation of MCM-41 with high structural stability
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