Morphology-design and semiconducting characteristics of zinc oxide nanostructures under microwave irradiation

Microwave irradiation (2.45 GHz) was used to synthesize nano-structured ZnO. The main precursors used were Zn(NO 3 ) 2 .6H 2 O and NaOH with molar ratio of Zn 2+ :OH − = 1:15. The powers for microwave heating were selected at 320 and 480 watts with 10 min synthesis time and 5s/15s on/off step. The c...

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Published inIntegrated ferroelectrics Vol. 177; no. 1; pp. 90 - 102
Main Authors Sooksaen, Pat, Chuankrerkkul, Nutthita
Format Journal Article
LanguageEnglish
Published Philadelphia Taylor & Francis 02.01.2017
Taylor & Francis Ltd
Subjects
band gap
Ferroelectrics
Heating
Irradiation
microwave
Microwaves
Nanostructure
Nanostructured ceramics
Nuclear power generation
Photodegradation
Synthesis
Zinc oxide
Zinc oxides
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Abstract Microwave irradiation (2.45 GHz) was used to synthesize nano-structured ZnO. The main precursors used were Zn(NO 3 ) 2 .6H 2 O and NaOH with molar ratio of Zn 2+ :OH − = 1:15. The powers for microwave heating were selected at 320 and 480 watts with 10 min synthesis time and 5s/15s on/off step. The charged particles vibrating in the electric field formed nuclei and grew in the temperature gradient in the solution leading to crystal growth in different directions. This study investigated the formation of nanostructured ZnO by microwave heating method using polyethylene glycols (MW = 1500 and MW = 4000), sugar and cassava starch as structure-directing agents. All the synthesized microwave conditions gave single phase of ZnO with wurtzite structure. The size of ZnO nanocrystals increased with increasing microwave power and the optical band gap energy values varied between 3.10 and 3.24 eV. Photocatalytic behavior of ZnO was studied through photodegradation of methylene blue. The highest photodegradation rate in this investigation was from PEG1500 modified nanostructured ZnO where they developed into fine rod-like particles.
AbstractList Microwave irradiation (2.45 GHz) was used to synthesize nano-structured ZnO. The main precursors used were Zn(NO sub(3)) sub(2).6H sub(2)O and NaOH with molar ratio of Zn super(2+):OH super(-) = 1:15. The powers for microwave heating were selected at 320 and 480 watts with 10 min synthesis time and 5s/15s on/off step. The charged particles vibrating in the electric field formed nuclei and grew in the temperature gradient in the solution leading to crystal growth in different directions. This study investigated the formation of nanostructured ZnO by microwave heating method using polyethylene glycols (MW = 1500 and MW = 4000), sugar and cassava starch as structure-directing agents. All the synthesized microwave conditions gave single phase of ZnO with wurtzite structure. The size of ZnO nanocrystals increased with increasing microwave power and the optical band gap energy values varied between 3.10 and 3.24 eV. Photocatalytic behavior of ZnO was studied through photodegradation of methylene blue. The highest photodegradation rate in this investigation was from PEG1500 modified nanostructured ZnO where they developed into fine rod-like particles.
Microwave irradiation (2.45 GHz) was used to synthesize nano-structured ZnO. The main precursors used were Zn(NO3)2.6H2O and NaOH with molar ratio of Zn2+:OH- = 1:15. The powers for microwave heating were selected at 320 and 480 watts with 10 min synthesis time and 5s/15s on/off step. The charged particles vibrating in the electric field formed nuclei and grew in the temperature gradient in the solution leading to crystal growth in different directions. This study investigated the formation of nanostructured ZnO by microwave heating method using polyethylene glycols (MW = 1500 and MW = 4000), sugar and cassava starch as structure-directing agents. All the synthesized microwave conditions gave single phase of ZnO with wurtzite structure. The size of ZnO nanocrystals increased with increasing microwave power and the optical band gap energy values varied between 3.10 and 3.24 eV. Photocatalytic behavior of ZnO was studied through photodegradation of methylene blue. The highest photodegradation rate in this investigation was from PEG1500 modified nanostructured ZnO where they developed into fine rod-like particles.
Microwave irradiation (2.45 GHz) was used to synthesize nano-structured ZnO. The main precursors used were Zn(NO 3 ) 2 .6H 2 O and NaOH with molar ratio of Zn 2+ :OH − = 1:15. The powers for microwave heating were selected at 320 and 480 watts with 10 min synthesis time and 5s/15s on/off step. The charged particles vibrating in the electric field formed nuclei and grew in the temperature gradient in the solution leading to crystal growth in different directions. This study investigated the formation of nanostructured ZnO by microwave heating method using polyethylene glycols (MW = 1500 and MW = 4000), sugar and cassava starch as structure-directing agents. All the synthesized microwave conditions gave single phase of ZnO with wurtzite structure. The size of ZnO nanocrystals increased with increasing microwave power and the optical band gap energy values varied between 3.10 and 3.24 eV. Photocatalytic behavior of ZnO was studied through photodegradation of methylene blue. The highest photodegradation rate in this investigation was from PEG1500 modified nanostructured ZnO where they developed into fine rod-like particles.
Author Sooksaen, Pat
Chuankrerkkul, Nutthita
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Cites_doi 10.1016/j.jallcom.2011.11.118
10.1016/j.ceramint.2015.11.044
10.1016/j.scriptamat.2008.02.044
10.1016/j.ssc.2005.09.023
10.1016/j.matlet.2007.05.072
10.1016/j.ceramint.2009.07.027
10.1016/j.cej.2010.01.052
10.3762/bjnano.4.87
10.4236/aces.2011.11002
10.1016/j.matchemphys.2008.05.065
10.1016/j.jallcom.2011.03.157
10.1016/j.matlet.2007.05.004
10.1126/science.281.5379.969
10.1016/j.matchemphys.2010.09.038
10.1016/j.ultsonch.2009.10.017
10.1016/j.matlet.2008.10.008
10.1016/j.jallcom.2009.11.033
10.1016/j.powtec.2004.05.007
10.1016/j.colsurfa.2012.11.001
10.1016/j.ceramint.2013.02.076
10.1016/j.mseb.2008.05.014
10.1016/j.apt.2010.07.002
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References cit0011
cit0012
Zak A. K. (cit0014); 24
Cho S. (cit0010); 112
cit0019
cit0017
cit0018
cit0015
cit0016
cit0022
cit0001
cit0023
cit0021
Abdul Rahman I. (cit0026)
Kantan S. (cit0020); 3
cit0008
cit0009
cit0006
cit0007
cit0004
cit0005
cit0027
cit0002
BeMiller J. (cit0013)
cit0024
cit0003
cit0025
References_xml – ident: cit0017
  doi: 10.1016/j.jallcom.2011.11.118
– ident: cit0007
  doi: 10.1016/j.ceramint.2015.11.044
– ident: cit0009
  doi: 10.1016/j.scriptamat.2008.02.044
– ident: cit0006
  doi: 10.1016/j.ssc.2005.09.023
– ident: cit0003
  doi: 10.1016/j.matlet.2007.05.072
– ident: cit0005
  doi: 10.1016/j.ceramint.2009.07.027
– volume: 112
  start-page: 12769
  ident: cit0010
  publication-title: J Phys Chem.
  contributor:
    fullname: Cho S.
– volume: 24
  start-page: 618
  issue: 3
  ident: cit0014
  publication-title: Adv Powder Technol.
  contributor:
    fullname: Zak A. K.
– ident: cit0022
  doi: 10.1016/j.cej.2010.01.052
– volume: 3
  start-page: 350
  issue: 4
  ident: cit0020
  publication-title: Adv Mater Lett.
  contributor:
    fullname: Kantan S.
– ident: cit0021
  doi: 10.3762/bjnano.4.87
– ident: cit0027
  doi: 10.4236/aces.2011.11002
– ident: cit0001
  doi: 10.1016/j.matchemphys.2008.05.065
– ident: cit0024
  doi: 10.1016/j.jallcom.2011.03.157
– ident: cit0026
  publication-title: Journal of Nanotechnology.
  contributor:
    fullname: Abdul Rahman I.
– ident: cit0002
  doi: 10.1016/j.matlet.2007.05.004
– start-page: 149
  volume-title: Starch: Chemistry and Technology
  ident: cit0013
  contributor:
    fullname: BeMiller J.
– ident: cit0019
  doi: 10.1126/science.281.5379.969
– ident: cit0008
  doi: 10.1016/j.matchemphys.2010.09.038
– ident: cit0016
  doi: 10.1016/j.ultsonch.2009.10.017
– ident: cit0004
  doi: 10.1016/j.matlet.2008.10.008
– ident: cit0011
  doi: 10.1016/j.jallcom.2009.11.033
– ident: cit0012
  doi: 10.1016/j.powtec.2004.05.007
– ident: cit0015
  doi: 10.1016/j.colsurfa.2012.11.001
– ident: cit0025
  doi: 10.1016/j.ceramint.2013.02.076
– ident: cit0018
  doi: 10.1016/j.mseb.2008.05.014
– ident: cit0023
  doi: 10.1016/j.apt.2010.07.002
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Snippet Microwave irradiation (2.45 GHz) was used to synthesize nano-structured ZnO. The main precursors used were Zn(NO 3 ) 2 .6H 2 O and NaOH with molar ratio of Zn...
Microwave irradiation (2.45 GHz) was used to synthesize nano-structured ZnO. The main precursors used were Zn(NO3)2.6H2O and NaOH with molar ratio of Zn2+:OH-...
Microwave irradiation (2.45 GHz) was used to synthesize nano-structured ZnO. The main precursors used were Zn(NO sub(3)) sub(2).6H sub(2)O and NaOH with molar...
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SubjectTerms band gap
Ferroelectrics
Heating
Irradiation
microwave
Microwaves
Nanostructure
Nanostructured ceramics
Nuclear power generation
Photodegradation
Synthesis
Zinc oxide
Zinc oxides
Title Morphology-design and semiconducting characteristics of zinc oxide nanostructures under microwave irradiation
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