Preparation and properties of furan-based liquid crystal polymer
In this research, a furan-based liquid crystal polymer (FLCP) was synthesized through a one-pot chemical reaction. The effects of incorporating 2,5-furandicarboxylic acid (FDCA) into the polymer were characterized using a range of analytical techniques. The results demonstrated that the incorporatio...
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| Published in | Materials research express Vol. 12; no. 7; pp. 75302 - 75310 |
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| Main Author | |
| Format | Journal Article |
| Language | English |
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IOP Publishing
01.07.2025
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| Abstract | In this research, a furan-based liquid crystal polymer (FLCP) was synthesized through a one-pot chemical reaction. The effects of incorporating 2,5-furandicarboxylic acid (FDCA) into the polymer were characterized using a range of analytical techniques. The results demonstrated that the incorporation of FDCA effectively reduced the polymer’s water absorption rate. When FDCA was substituted for PTA up to a ratio of 50%, the thermal decomposition temperature of the polyester was found to be relatively stable with only a minor reduction. Moreover, the addition of FDCA led to an increase in the polyester’s viscosity and enhanced melt strength, which imply that the copolyesters have stronger deformation processing ability under the external force. This copolyester demonstrates favorable thermal stability, melt processing characteristics, mechanical performance, and hydrophobic behavior, suggesting substantial promise in medical and packaging applications. |
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| AbstractList | In this research, a furan-based liquid crystal polymer (FLCP) was synthesized through a one-pot chemical reaction. The effects of incorporating 2,5-furandicarboxylic acid (FDCA) into the polymer were characterized using a range of analytical techniques. The results demonstrated that the incorporation of FDCA effectively reduced the polymer’s water absorption rate. When FDCA was substituted for PTA up to a ratio of 50%, the thermal decomposition temperature of the polyester was found to be relatively stable with only a minor reduction. Moreover, the addition of FDCA led to an increase in the polyester’s viscosity and enhanced melt strength, which imply that the copolyesters have stronger deformation processing ability under the external force. This copolyester demonstrates favorable thermal stability, melt processing characteristics, mechanical performance, and hydrophobic behavior, suggesting substantial promise in medical and packaging applications. |
| Author | Wu, Yu |
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| Cites_doi | 10.1016/j.aiepr.2020.10.005 10.1039/c3py01717f 10.1039/b909377j 10.1016/j.eurpolymj.2018.10.014 10.3390/polym4020889 10.1007/s11164-012-0658-y 10.1016/j.polymer.2014.03.033 10.1002/app.54473 10.1021/ma500433e 10.1016/j.polymdegradstab.2018.12.008 10.1080/1385772X.2012.688325 10.1039/C5RA00242G 10.1021/ma3023298 10.1021/acs.macromol.5b00333 10.3390/ma11040522 10.1021/acssuschemeng.3c06878 10.1016/j.eurpolymj.2019.06.033 10.1016/S0927-796X(03)00035-4 10.3390/polym14030625 10.1016/j.tca.2014.04.008 10.1109/TMTT.2019.2892774 10.3390/polym15051088 10.1080/15421406.2015.1017295 10.1016/j.polymer.2014.10.065 10.1016/j.biomaterials.2010.07.006 10.1021/ma5000199 10.1016/j.eurpolymj.2022.111738 |
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| SubjectTerms | biobased polyester Chemical reactions Chemical synthesis FDCA liquid crystal Liquid crystal polymers Liquid crystals Mechanical properties preparation Thermal decomposition Thermal stability Water absorption |
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| Title | Preparation and properties of furan-based liquid crystal polymer |
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