Redox Properties of Cobalt Nitrides for NO Dissociation and Reduction

Redox reactions catalyzed by cobalt nitrides should be carried out below the critical temperature at which bulk oxidation of the nitrides occurs. Then, a catalytic redox cycle could be established by introducing a reducing agent into the system below this temperature so that the oxygen could be remo...

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Bibliographic Details
Published inCatalysis letters Vol. 130; no. 1-2; pp. 63 - 71
Main Authors Yao, Zhiwei, Zhu, Aimin, Au, C. T, Shi, Chuan
Format Journal Article
LanguageEnglish
Published Boston Boston : Springer US 01.06.2009
Springer US
Springer
Springer Nature B.V
Subjects
Catalysis
Chemical reactions
Chemistry
Chemistry and Materials Science
Cobalt
Critical temperature
Exact sciences and technology
General and physical chemistry
Industrial Chemistry/Chemical Engineering
Nitrides
Organometallic Chemistry
Oxidation
Physical Chemistry
Redox reactions
Reducing agents
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
NO dissociation
Reducing agent
Cobalt nitrides
Deactivation mechanism
Catalytic cycle
Critical property
Oxygen
Catalytic reaction
Deactivation
Mechanism
Chemical reduction
Heterogeneous catalysis
Oxidation
Dissociation
Critical temperature
Cobalt nitride
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Summary:Redox reactions catalyzed by cobalt nitrides should be carried out below the critical temperature at which bulk oxidation of the nitrides occurs. Then, a catalytic redox cycle could be established by introducing a reducing agent into the system below this temperature so that the oxygen could be removed prior to the occurrence of bulk oxidation.
Bibliography:http://dx.doi.org/10.1007/s10562-009-9881-6
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-009-9881-6