Fourier-Transform Photocurrent Spectroscopy for a fast and highly sensitive spectral characterization of organic and hybrid solar cells
Two modes of Fourier-Transform Photocurrent Spectroscopy (FTPS) are presented for a fast and sensitive determination of photocurrent spectra of organic and dye sensitized solar cells. Furthermore, FTPS allows to spectrally resolve sub-bandgap absorption phenomena in P3HT, in organic P3HT:PCBM bulk h...
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Published in | Thin solid films Vol. 516; no. 20; pp. 7135 - 7138 |
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Main Authors | , , , , , , |
Format | Journal Article Conference Proceeding |
Language | English |
Published |
Lausanne
Elsevier B.V
30.08.2008
Elsevier Science |
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Abstract | Two modes of Fourier-Transform Photocurrent Spectroscopy (FTPS) are presented for a fast and sensitive determination of photocurrent spectra of organic and dye sensitized solar cells. Furthermore, FTPS allows to spectrally resolve sub-bandgap absorption phenomena in P3HT, in organic P3HT:PCBM bulk heterojunctions and in hybrid P3HT/TiO
2 solar cells. The sub-bandgap absorption in the P3HT:PCBM blend is dominated by a band due to the formation of a ground-state charge-transfer complex between the polymer and PCBM. In P3HT/TiO
2 junctions such a charge-transfer complex band is not observed. Long-lived light induced sub-bandgap states appear in pure P3HT and in P3HT/TiO
2 junctions after irradiation with
E
>
1.9 eV. |
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AbstractList | Two modes of Fourier-Transform Photocurrent Spectroscopy (FTPS) are presented for a fast and sensitive determination of photocurrent spectra of organic and dye sensitized solar cells. Furthermore, FTPS allows to spectrally resolve sub-bandgap absorption phenomena in P3HT, in organic P3HT:PCBM bulk heterojunctions and in hybrid P3HT/TiO
2 solar cells. The sub-bandgap absorption in the P3HT:PCBM blend is dominated by a band due to the formation of a ground-state charge-transfer complex between the polymer and PCBM. In P3HT/TiO
2 junctions such a charge-transfer complex band is not observed. Long-lived light induced sub-bandgap states appear in pure P3HT and in P3HT/TiO
2 junctions after irradiation with
E
>
1.9 eV. |
Author | Goris, L. Haenen, K. Haeldermans, I. Manca, J.V. Vandewal, K. Nesládek, M. Wagner, P. |
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Keywords | FTPS Optical spectroscopy Dye sensitized solar cells Organic solar cells Solar cells Radiation effects Fourier transform spectroscopy Organic dye Ground states Photoinduced effect Photocurrents Energy gap Heterojunctions Titanium oxide Photoconductivity Polymers Charge transfer |
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SubjectTerms | Applied sciences Condensed matter: electronic structure, electrical, magnetic, and optical properties Condensed matter: structure, mechanical and thermal properties Dye sensitized solar cells Electronic structure and electrical properties of surfaces, interfaces, thin films and low-dimensional structures Electronic transport phenomena in thin films and low-dimensional structures Energy Exact sciences and technology FTPS Natural energy Optical spectroscopy Organic solar cells Photoconduction and photovoltaic effects; photodielectric effects Photovoltaic conversion Physical radiation effects, radiation damage Physics Solar cells. Photoelectrochemical cells Solar energy Structure of solids and liquids; crystallography |
Title | Fourier-Transform Photocurrent Spectroscopy for a fast and highly sensitive spectral characterization of organic and hybrid solar cells |
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