The first chiral early-late heterobimetallic complex — A titanium(IV)-palladium(II) complex based on salenophos

• Published in: Tetrahedron Vol. 52; no. 46; pp. 14599 - 14606
• Main Authors: Kless, Achim, Lefeber, Claudia, Spannenberg, Anke, Kempe, Rhett, Baumann, Wolfgang, Holz, Jens, Börner, Armin
• Format: Journal Article
• Language: English
• Published: OXFORD Elsevier Ltd 11.11.1996; Elsevier
• Subjects: Chemistry; Chemistry, Organic; Physical Sciences; Science & Technology; DESIGN; PHOSPHINE-LIGANDS; PYRIDINE; SUBSTITUENTS; SITES; HARD; CATALYSTS; MOLECULES

The synthesis of the chiral polyfunctional diphosphine salenophos 1 is described. The new ligand bearing hard and soft coordination sites chelates titanium(IV) as well as palladium(II) in a defined manner provided a certain order during the introduction of the two metals was kept. In this way the fi...