Oxidation of h-BN on strongly and weakly interacting metal surfaces

We used x-ray photoemission and absorption spectroscopies to study the influence of thermal molecular oxygen exposure on the h-BN/Co(0001) and h-BN/Au/Co(0001) systems. The spectral analysis was supported by density functional theory calculations. It is shown that oxygen can intercalate h-BN on Co(0...

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Published inNanotechnology Vol. 30; no. 23; p. 234004
Main Authors Shevelev, Viktor O, Bokai, Kirill A, Vilkov, Oleg Yu, Makarova, Anna A, Usachov, Dmitry Yu
Format Journal Article
LanguageEnglish
Published England IOP Publishing 07.06.2019
Subjects
h-BN
intercalation
oxidation
photoemission spectroscopy
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Abstract We used x-ray photoemission and absorption spectroscopies to study the influence of thermal molecular oxygen exposure on the h-BN/Co(0001) and h-BN/Au/Co(0001) systems. The spectral analysis was supported by density functional theory calculations. It is shown that oxygen can intercalate h-BN on Co(0001) and also be embedded into its lattice, replacing the nitrogen atoms. Upon substitution, the structures containing one (BN2O) and three (BO3) oxygen atoms in the boron atom environment are formed predominantly. In the case of gold-intercalated h-BN, only the (BN2O) structures are formed; the long-lasting oxygen exposures lead to etching of the h-BN layer.
AbstractList We used x-ray photoemission and absorption spectroscopies to study the influence of thermal molecular oxygen exposure on the h-BN/Co(0001) and h-BN/Au/Co(0001) systems. The spectral analysis was supported by density functional theory calculations. It is shown that oxygen can intercalate h-BN on Co(0001) and also be embedded into its lattice, replacing the nitrogen atoms. Upon substitution, the structures containing one (BN O) and three (BO ) oxygen atoms in the boron atom environment are formed predominantly. In the case of gold-intercalated h-BN, only the (BN O) structures are formed; the long-lasting oxygen exposures lead to etching of the h-BN layer.
We used x-ray photoemission and absorption spectroscopies to study the influence of thermal molecular oxygen exposure on the h-BN/Co(0001) and h-BN/Au/Co(0001) systems. The spectral analysis was supported by density functional theory calculations. It is shown that oxygen can intercalate h-BN on Co(0001) and also be embedded into its lattice, replacing the nitrogen atoms. Upon substitution, the structures containing one (BN2O) and three (BO3) oxygen atoms in the boron atom environment are formed predominantly. In the case of gold-intercalated h-BN, only the (BN2O) structures are formed; the long-lasting oxygen exposures lead to etching of the h-BN layer.
Author Shevelev, Viktor O
Bokai, Kirill A
Usachov, Dmitry Yu
Vilkov, Oleg Yu
Makarova, Anna A
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SubjectTerms h-BN
intercalation
oxidation
photoemission spectroscopy
Title Oxidation of h-BN on strongly and weakly interacting metal surfaces
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